Category: 1206-46-8

Petrov, V. A. published the artcileReaction of (pentafluorophenyl)trimethylsilane with perfluorinated internal azaalkenes in the presence of cesium fluoride, Name: Trimethyl(perfluorophenyl)silane, the publication is Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya (1990), 923-4, database is CAplus.

CF₃(CF₂)_mN:CF(CF₂)_nCF₃ (m = 1, n = 0; m = 3, n = 2) reacted with C₆F₅SiMe₃ in the presence of CsF to give 63 and 56% yields, resp., of CF₃(CF₂)_mN:C(C₆F₅)(CF₂)_nCF₃.

Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Name: Trimethyl(perfluorophenyl)silane.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Dilman, Alexander D. published the artcileTrifluoromethylation of N-Benzoylhydrazones, Quality Control of 1206-46-8, the publication is Journal of Organic Chemistry (2008), 73(14), 5643-5646, database is CAplus and MEDLINE.

A method for the nucleophilic trifluoromethylation of N-benzoylhydrazones using Me₃SiCF₃/AcONa leading to hydrazides, e.g., I (R = H, MeO, NO₂), has been described. The C=N bond of the hydrazones is activated by difluoroboron group, which is introduced by means of boron trifluoride and allylsilane.

Journal of Organic Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Quality Control of 1206-46-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Dilman, Alexander D. published the artcileTrifluoromethylation of Salicyl Aldimines, Name: Trimethyl(perfluorophenyl)silane, the publication is Journal of Organic Chemistry (2007), 72(22), 8604-8607, database is CAplus and MEDLINE.

A method for the nucleophilic trifluoromethylation of salicyl aldimines, which do not contain an activating group at the nitrogen atom, has been described. The reaction proceeds through the initial generation of an intramol. boron complex followed by interaction with Me₃SiCF₃ activated by sodium acetate. Thus, BF₃.OEt₂ was added dropwise to a solution of imine I and EtN(i-Pr)₂ in CH₂Cl₂. After stirring for 2 h at room temperature, the solvent was evaporated in a vacuum followed by successive addition of DMF, Me₃SiCF₃, and AcONa to give up to 86% trifluoromethylated product II.

Journal of Organic Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Name: Trimethyl(perfluorophenyl)silane.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Bardin, V. V. published the artcilePolyfluorophenylation of halosilanes, -germanes and -stannanes, Quality Control of 1206-46-8, the publication is Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya (1989), 2153-4, database is CAplus.

Reaction of R₃MX (R = Me, Et; M = Si, Ge, Sn; X = Cl, Br) with 4-R¹C₆F₄Br (R¹ = F, PrO, CF₃) in pentane containing P(NEt₂)₃ gave 4-R¹C₆F₄MR₃. Thus, reaction of C₆F₅Br with Me₃MCl (M = Si, Ge, Sn) gave 50-66% C₆F₅MMe₃.

Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Quality Control of 1206-46-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Bardin, V. V. published the artcileReactions of (triethylgermyl)pentafluorobenzene and perfluorotetraphenylgermane with nucleophiles, COA of Formula: C9H9F5Si, the publication is Zhurnal Obshchei Khimii (1990), 60(8), 1820-6, database is CAplus.

Oxygen- or nitrogen-containing nucleophiles attack the Ge atom in Et₃GeC₆F₅, while sulfur-, carbon-, and hydrogen-containing nucleophiles attack the C-4 atom of the C₆F₅ group. (C₆F₅)₄Ge undergoes C_aryl-Ge bond cleavage in reactions with O– and S-nucleophiles, while reactions with C-nucleophiles give complex mixtures of products from cleavage and defluorination. Piperidine reacts with (C₆F₅)₄Ge by substitution of an F atom, apparently due to steric screening of Ge.

Zhurnal Obshchei Khimii published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, COA of Formula: C9H9F5Si.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia