Category: 1237588-12-3

Borjian, Sogol’s team published research in Organometallics in 33 | CAS: 1237588-12-3

Organometallics published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C30H42NOP, Recommanded Product: 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine.

Borjian, Sogol published the artcileNMR Studies of the Species Present in Cross-Coupling Catalysis Systems Involving Pd(η3-1-Ph-C3H4)(η5-C5H5) and [Pd(η3-1-Ph-C3H4)Cl]2 Activated by PBut3, XPhos, and Mor-Dalphos: Nonexistence of Pd(XPhos)n and Pd(Mor-Dalphos)n (n = 1, 2) at Moderate Temperatures, Recommanded Product: 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, the publication is Organometallics (2014), 33(15), 3936-3940, database is CAplus.

The compounds Pd(η3-1-Ph-C3H4)(η5-C5H5) (I), Pd2(dba)3 (II), Pd(OAc)2 (III), and [Pd(η3-1-Ph-C3H4)Cl]2 (IV) are frequently used as catalyst precursors for a variety of cross-coupling processes, including Suzuki-Miyaura, Heck-Mizoroki, Sonogashira, and Buchwald-Hartwig reactions. The NMR spectroscopy the solution chem. of I and IV with PBut3, XPhos, and Mor-Dalphos, noting similarities and differences in the resp. abilities of these precursor-ligand combinations to generate Pd(0) catalyst systems. Inter alia that steric requirements prevent Xphos and Mor-Dalphos from forming 2:1 Pd(0) complexes and, surprisingly, that 1:1 Pd(0) complexes of Xphos and Mor-Dalphos are unstable with respect to dissociation to free ligand and Pd metal were found. These two ligands and, by implication, other sterically demanding phosphine ligands do not form Pd(0) compounds

Organometallics published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C30H42NOP, Recommanded Product: 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Crawford, Sarah M.’s team published research in European Journal of Organic Chemistry in 2012 | CAS: 1237588-12-3

European Journal of Organic Chemistry published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C30H42NOP, Quality Control of 1237588-12-3.

Crawford, Sarah M. published the artcilePalladium-catalyzed mono-α-arylation of carbonyl-containing compounds with aryl halides using DalPhos ligands, Quality Control of 1237588-12-3, the publication is European Journal of Organic Chemistry (2012), 2012(30), 6042-6050, database is CAplus.

The extension and optimization of the [Pd(cinnamyl)Cl]2/DalPhos catalyst system, previously found effective for the α-monoarylation of acetone, to the α-monoarylation of a variety of carbonyl compounds with aryl halides and heteroaryl halides was reported. Aryl Me ketones, heteroaryl Me ketones, propiophenones, malonates, and methoxyacetone can be α-arylated under relatively mild conditions and in good yields. The limitations of the ligand/catalyst system towards other classes of carbonyl compounds are reported also.

European Journal of Organic Chemistry published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C30H42NOP, Quality Control of 1237588-12-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia