Category: 13822-56-5

Ye, Xinming published the artcileEngineering two nitrogen-containing polyhedral oligomeric silsesquioxanes (N-POSSs) to enhance the fire safety of epoxy resin endowed with superior thermal stability, Recommanded Product: 3-(Trimethoxysilyl)propan-1-amine, the publication is Polymer Degradation and Stability (2022), 109946, database is CAplus.

Despite remarkable advances in developing flame retardants and smoke suppressants for epoxy resin (EP), engineering nitrogen-containing polyhedral oligomeric silsesquioxane (N-POSS) to impart superior fire safety properties to EP has remained an intractable challenge. In this work, two nitrogen-containing polyhedral oligomeric silsesquioxanes (N-POSSs), namely, aminoethyl-aminopropyl-hepta-Ph polyhedral oligomeric silsesquioxane (AEAP-POSS) and aminopropyl-hepta-Ph polyhedral oligomeric silsesquioxane (AP-POSS), were synthesized through the “corner-capping” reaction. The mol. structures of N-POSSs were fully characterized by FTIR, ¹H NMR, ²⁹Si NMR and MALDI-TOF MS, and the synthesized AEAP-POSS and AP-POSS were introduced into EP to solve the shortcomings of flammability. TGA results showed that the incorporation of 4 wt% N-POSS nanoparticles distinctly improved the char residue at 800¡ãC, which significantly enhanced the thermal stability of the EP composites. When 4 wt% of AP-POSS was introduced into EP, reductions in the peak of heat release rate (p-HRR), fire growth index (FGI), peak of smoke production rate (p-SPR), and the peak of CO production rate (p-COP) reached to 60.6%, 70.2%, 52.3% and 60.4%, resp. Subsequently, TG-FTIR and XPS were utilized to investigate the flame retardancy and smoke suppression mechanism. Our work presented a considerable advancement for the facile fabrication of flame retardants based on nitrogen-containing polyhedral oligomeric silsesquioxane compounds

Polymer Degradation and Stability published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C7H10BNO4S, Recommanded Product: 3-(Trimethoxysilyl)propan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Lorusso, Emanuela published the artcileInvestigation of aminolysis routes on PET fabrics using different amine-based materials, Application of 3-(Trimethoxysilyl)propan-1-amine, the publication is Nano Select (2022), 3(3), 594-607, database is CAplus.

In this study, functionalization of PET fabrics with amino groups was achieved by aminolysis. Aminolysis routes were explored using different amine-based materials including ethylenediamine (EDA), triaminotriethylamine (TAEA) and (3-aminopropyl)trimethoxysilane (APTMS), (3-trimethoxy-silylpropyl)diethylentriamine (TRIAMO) in addition to amino-functionalized silica nanoparticles as amino-silane based reagents. The samples were deeply characterized by SEM, AFM, and XPS. Abrasion and tensile tests were carried out to evaluate the mech. properties of the modified fabrics. Results showed that aminolysis conducted with EDA and TAEA as amino based reagents lower the performances of PET, while dense coatings can be deposited on the fibers by amino silane-based reagents that act as protective layers. APTMS modified PET presented improved abrasion resistance compared to the native PET. The antibacterial activity of the PET surfaces functionalized with the different amino groups was also evaluated using the gram-neg. bacterium A. fischeri antibacterial assay. The results showed improved antibacterial performances of the native textile treated with APTMS and TAEA based reagents.

Nano Select published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C6H17NO3Si, Application of 3-(Trimethoxysilyl)propan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Ashouri, Fatemeh published the artcileFabrication, characterization and structure activity relationship of Co and Mn encapsulated on magnetic nanocomposite and its application in one-pot tandem synthesis of various tetrazoles and vitamin K₃, Quality Control of 13822-56-5, the publication is Chemical Papers (2022), 76(6), 3581-3605, database is CAplus.

Considering the importance of vitamin K₃ in com. pet foods, veterinary medicines, poultry, and some swine feed and also tetrazole derivatives in drugstore, medicine, chem., petroleum, and military industry, design efficient catalytic systems are desirable. Herein, four magnetic nanocomposites (MNCs) of cobalt and manganese using metformin, 3-aminopropyltrimethoxysilane (L1) and 2-aminoethyl-3-aminopropyltrimethoxysilane (L2) were designed and constructed as an efficient and controllable catalytic system. The synthesized nanocomposites fully characterized by FT-IR, AAS, ICP-OES, BET, CHN elemental anal., SEM, TEM, DLS, EDX, TGA, VSM, and XPS spectroscopy. The well-prepared magnetically recoverable nanocomposites were used in the synthesis of a wide derivatives of ¦Á-hydrazino tetrazoles (¦Á-HyT), ferrocenyltetrazoles (FcT), arylaminotetrazoles (ArAT) and also vitamin K₃. Besides, the effect of operating parameters, such as the amount of catalyst, nature of solvent, temperature and reaction time, metal nature, chain length and hydrophobicity properties of linkers, was studied in the catalytic efficiency of synthesized nanocatalysts. The best catalytic results were obtained in the following order: FS-L2-Met@Co(II) > FS-L2-Met@Mn(II) > FS-L1-Met@Co(II) > FS-L1-Met@Mn(II) due to their structural characteristics. In addition to high TOF, these magnetic nanocomposites are superior in easy, inexpensive, and com. preparation, keeping the structural and magnetic characteristics, easy magnetically separation from the reaction medium, short reaction time, mild reaction condition, easy work-up, and reusability without any metal leaching in six runs.

Chemical Papers published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C6H17NO3Si, Quality Control of 13822-56-5.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Wang, Yilin published the artcileCatalytic membrane nano reactor with Cu/ZnO in situ immobilized in membrane pores for methanol dehydrogenation to formaldehyde, Category: catalysis-chemistry, the publication is Journal of Membrane Science (2022), 120014, database is CAplus.

A catalytic membrane nano reactor (CMNR) with deep-permeation nanocomposite structure (DPNS) was fabricated by flowing synthesis for methanol dehydrogenation to formaldehyde. In this structure, Cu/ZnO nanoparticles are in situ immobilized in the pores of Ti membrane substrate with thickness 1 mm, pore size 10¦Ìm, and porosity 45%. The characterization by XRD, TGA, XPS, SEM and TEM indicates that the Cu/ZnO nanoparticles with mean size of 82 nm was successfully embedded into the membrane pores, and well distributed along the thickness direction of the membrane. The ICP measurement results demonstrate that the immobilization amount of 20 mg of Cu/ZnO nanoparticles per g of Ti membrane substrate can be obtained. The prepared Cu/ZnO/Ti CMNR was built in the technol. apparatus for catalytic dehydrogenation of methanol. For one sheet of membrane setting up, the conversion efficiency of methanol 7.5%, the mass specific activity 183 mmol_MeOH¡¤h^-1¡¤g^-1_cat, the pressure drop 2.7 kPa with gas permeating the membrane was measured, under mass ratio of Cu to ZnO 0.05 in the membrane, reaction temperature 360¡ã, the gas flux 8 m³.m^-2.h^-1 through the membrane. The selectivity of formaldehyde is ¡Ü 98% and increases with increasing reaction temperature, the highest mass specific activity of 318 mmol_MeOH.h^-1.g^-1_cat can be achieved with mass ratio of Cu to ZnO 0.12 at 360¡ã. For three sheets of CMNRs setting up in serials, > 18% of conversion efficiency has been achieved with gas pressure drop 6.8 kPa. If 70 sheets of CMNRs are packed in serials to build a reactor with 70 mm thickness, which will produce the gas pressure drop 162 kPa, the conversion efficiency of 99% would be expected according to a simple simulation based on the exptl. measurement.

Journal of Membrane Science published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C10H15ClO3S, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Huang, Rui published the artcileHighly stretchable polyurethane coating based on functionalized cerium oxide nanoparticles for anti-corrosive/UV protection, Formula: C6H17NO3Si, the publication is Journal of Applied Polymer Science (2022), 139(15), 51927, database is CAplus.

To prolong the active life of carbon steel in corrosive environment, it is an effective way to use inorganic nano-pigments in polyurethane (PU) coatings. In this work, the CeO₂ nanoparticles are modified by APTMS (labeled as mCeNPs), and the organic-inorganic nanocomposite coating is prepared The morphol. and structure of PU/mCeNPs composites are characterized by field emission SEM, transmission electron microscopy, and Fourier transform IR spectroscopy. The mech. and UV resistance properties of compound material are studied by UV spectroscopy and universal tensile testing machine. The corrosion resistance of PU/mCeNPs coatings are investigated by Tafel polarization technique and electrochem. impedance spectroscopy. The results show that the PU composite coating with mCeNPs additive had high long-term corrosion resistance. Under the optimum conditions, when mCeNPs accounted for 5% of PU, the nanocomposite coatings show excellent UV resistance, excellent mech. properties, and long-term corrosion resistance due to the characteristics of ceria and its good dispersion in PU.

Journal of Applied Polymer Science published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C6H17NO3Si, Formula: C6H17NO3Si.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Wei, Yudi published the artcileDetailing molecular interactions of ionic liquids with charged SiO₂ surfaces: A systematic AFM study, COA of Formula: C6H17NO3Si, the publication is Journal of Molecular Liquids (2022), 118506, database is CAplus.

It is crucial to understand the behavior and interfacial interactions as well as properties of ionic liquids (ILs) at electrode surfaces on the mol. level for developing IL-based electrochem. energy storage devices including supercapacitors and batteries. In this work, a colloid probe at. force microscopy (CP-AFM) -based exptl. approach is presented to determine the mol. interaction forces between ILs and differently charged SiO₂ microspheres. The effects of structural variations in ILs and the nature surface charges of SiO₂ on the mol. interaction force are systematically studied. The surface charges of SiO₂ were achieved by grafting quaternary ammonium and -COOH, -NH₂ groups. The determined mol. interaction force is found to be strongly dependent on the surface charge, in which, the force enhances at a more neg. charged surface. Furthermore, the ILs with longer alkyl chains on cations exhibit stronger mol. interaction forces with the charged SiO₂. These reported exptl. results on the mol. level provide new insights for model development and mol. simulations of ILs interacting with charged surfaces and guide the design of ILs-based supercapacitor and battery systems.

Journal of Molecular Liquids published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C9H7NO2, COA of Formula: C6H17NO3Si.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Yang, Pu published the artcileChiral Nanostructured Bimetallic Au-Ag Films for Enantiomeric Discrimination, Related Products of catalysis-chemistry, the publication is Advanced Materials Interfaces (2022), 9(19), 2200369, database is CAplus.

Herein, the chiral nanostructured bimetallic Au-Ag films (CNAAFs) with both photomagnetic-chiral anisotropy to enantiomers (PM-ChA_C-E) and surface-enhanced Raman scattering-chiral anisotropy to enantiomers (SERS-ChA_C-E) for efficient enantiomeric discrimination are reported. The CNAAFs are synthesized by electrodeposition on n-type Si (n-Si) substrates with the assistance of N-acetyl-L/D-cysteine (S/R-NAC) as symmetry-breaking agents, which are consisted of polycrystalline Boerdijk-Coxeter-Bernal (BCB) tetrahelical structured Au-Ag alloy nanowires grown on n-Si substrates perpendicularly. The anisotropic factors of PM-ChA_C-E (g_PM-ChA) and SERS-ChA_C-E (g_SERS-ChA) of CNAAFs in the range of 0.68-1.12 and 1.45-1.89 are obtained, resp. Considering the increase of magnetic fields and SERS intensities with enantiomeric excess (ee) values of adsorbed enantiomers on the CNAAFs are higher than that of pure chiral nanostructure Au films, the enhancement of PM-ChAC-E and SERS-ChAC-E effects of CNAAFs can be attributed to the enhanced selective spin polarization coupling between CNAAFs and enantiomers. It is predicted to be due to the strong surface plasmon resonance generated by the active electrons of Ag under laser irradiation

Advanced Materials Interfaces published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C6H12O2, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Pu, Xiaoying published the artcileSelective capture of mercury(II) in aqueous media using nanoporous diatomite modified by allyl thiourea, Category: catalysis-chemistry, the publication is Journal of Materials Science (2022), 57(20), 9246-9264, database is CAplus.

We herein aim to construct a novel sorbent (DT-S) possessing adsorption selectivity to mercury(II) in aqueous media. Silanized purified diatomite (DT-N) was first synthesized by grafting 3-aminopropyltrimethoxysilane (APS) onto purified diatomite (DT). Nanoporous DT-S was then constructed through successively grafting epichlorohydrin (ECH) and allyl thiourea (AT) onto DT-N. FTIR, elemental anal. (EA), Brunauer-Emmett-Teller (BET), XRD, SEM, and pH at the zero point of charge (pH_zpc) results demonstrated that DT-S had ample -OH, -NH₂, and C=S, sp. surface area of 5.52 m²/g, small pore diameter (16.10 nm), porous structures, and pH_zpc of 5.80, favorable for Hg(II) capture. Optimal adsorption parameters were determined through batch tests. Capture behavior was interpreted preferably by pseudo-second-order kinetic and Liu isothermal equations. DT-S¡ä capture features, e.g., monolayer, spontaneity, chemisorption, and endothermic reaction, were evidenced by the data obtained. DT-S had 56.30 mg/g of maximum adsorption capacity for Hg(II), exceeded some sorbents available. Competitive adsorption tests displayed remarkably selective ability to capture Hg(II) (> 80.01%). FTIR and XRD analyses validated a possible capture mechanism, i.e., chelation reactions took place between mercury ions and nitrogen, oxygen, or sulfur atom in solid-liquid interface. Altogether, DT-S with high removal efficiency, capture selectivity, and excellent reusability is expected to be new sorbent applied to Hg(II)-contaminated water purification

Journal of Materials Science published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C6H17NO3Si, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Eremina, Olga E. published the artcileExpanding the multiplexing capabilities of Raman imaging to reveal highly specific molecular expression and enable spatial profiling, SDS of cas: 13822-56-5, the publication is ACS Nano (2022), 16(7), 10341-10353, database is CAplus and MEDLINE.

Profiling the heterogeneous landscape of cell types and biomols. is rapidly being adopted to address current imperative research questions. Precision medicine seeks advancements in mol. spatial profiling techniques with highly multiplexed imaging capabilities and subcellular resolution, which remains an extremely complex task. Surface-enhanced Raman spectroscopy (SERS) imaging offers promise through the utilization of nanoparticle-based contrast agents that exhibit narrow spectral features and mol. specificity. The current renaissance of gold nanoparticle technol. makes Raman scattering intensities competitive with traditional fluorescence methods while offering the added benefit of unsurpassed multiplexing capabilities. Here, we present an expanded library of individually distinct SERS nanoparticles to arm researchers and clinicians. Our nanoparticles consist of a 6?0 nm gold core, a Raman reporter mol., and a final inert silica coating. Using d. functional theory, we have selected Raman reporters that meet the key criterion of high spectral uniqueness to facilitate unmixing of up to 26 components in a single imaging pixel in vitro and in vivo. We also demonstrated the utility of our SERS nanoparticles for targeting cultured cells and profiling cancerous human tissue sections for highly multiplexed optical imaging. This study showcases the far-reaching capabilities of SERS-based Raman imaging in mol. profiling to improve personalized medicine and overcome the major challenges of functional and structural diversity in proteomic imaging.

ACS Nano published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C6H17NO3Si, SDS of cas: 13822-56-5.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Jibril, Liban published the artcilePolymer-Mediated Particle Coarsening within Hollow Silica Shell Nanoreactors, Synthetic Route of 13822-56-5, the publication is Chemistry of Materials (2022), 34(11), 5094-5102, database is CAplus.

Inspired by the scanning probe block copolymer lithog. process, hollow silica shells were loaded with polymer-metal ink mixtures and investigated as solution-based nanoreactors for the synthesis of gold nanoparticles. The incorporation of poly(ethylene oxide) (PEO) into these hollow silica nanoreactors (approx. 40 nm in size) and the use of a two-step reductive annealing process (first at 200¡ãC and then at 600¡ãC) results in a high yield (76%) of larger (?6 nm) single nanoparticles; when the polymer is not used, smaller (?3 nm) particles dominate, and the yield of single particles is only 6%. It was determined that particle coarsening mostly occurs in the temperature range where the polymer is present and not degraded (i.e., <400¡ãC for PEO), as indicted by correlative in situ scanning/transmission electron microscopy in a reductive gas-phase environment. Thus, polymer incorporation in this nanoreactor system, which is amenable to scale up, drives the complete conversion of nanoreactor contents without excessive metal loss, highlighting the impact of nanoreactor composition and structural design on particle synthesis.

Chemistry of Materials published new progress about 13822-56-5. 13822-56-5 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is 3-(Trimethoxysilyl)propan-1-amine, and the molecular formula is C6H17NO3Si, Synthetic Route of 13822-56-5.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia