Category: 19117-31-8

Davis, Franklin A. published the artcileChemistry of the sulfur-nitrogen bond. 12. Metal-assisted synthesis of sulfenamide derivatives from aliphatic and aromatic disulfides, Application In Synthesis of 19117-31-8, the publication is Journal of Organic Chemistry (1977), 42(6), 967-72, database is CAplus.

R1SNR2 (R, R1 = alkyl, aryl) (?25) were prepared by treating R12S2 with excess R2NH in MeOH or AcOEt in the presence of AgNO3, AgOAc, or HgCl2. Recovery of Ag was 65-75%. 3,4-Cl2C6H3SNH2 and 3-O2NC6H4SNH2 were obtained by reaction of the corresponding disulfides with NH3 in the presence of AgNO3. Similar treatment of Ph2S2 or (4-ClC6H4)2S2 gave (PhS)2NH and (4-ClCl6H4S)2NH, resp. AgNO3-assisted reaction of aliphatic disulfides with NH3 and PhCHO, PhCOMe, or 2-HOC6H4CHO afforded the resp. R1SN:CR2 in low yield.

Journal of Organic Chemistry published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, Application In Synthesis of 19117-31-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Hankin, Danielle M. published the artcileA new type of sulfenamido ligand. Crystal structure of W(NBu^t)₂(¦Ç²-PhSNBu^t)₂, Computed Properties of 19117-31-8, the publication is Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1995), 1059-60, database is CAplus.

The interaction of Li₂W(NBu^t)₄ with PhSCl gave W(NBu^t)₂(¦Ç²-PhSNBu^t)₂ the structure of which was determined by x-ray diffraction. Reaction of Li(PhSNBu^t) with transition-metal halides gave a range of other compounds with the ¦Ç²-N,S ligand.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, Computed Properties of 19117-31-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Hankin, Danielle M. published the artcile¦Ç²-Sulfenamido and -selenamido complexes of titanium, zirconium, molybdenum and tungsten, Synthetic Route of 19117-31-8, the publication is Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1996), 1309-21, database is CAplus.

The interaction of TiCl₄ with LiN(Bu^t)SR (R = Ph or C₆H₂Me₃-2,4,6) gave the sulfenamido complexes TiCl₂(¦Ç²-Bu^tNSR)₂. Interaction of ZrCl₄ with 3 equiv of LiN(Bu^t)SPh produced ZrCl(¦Ç²-Bu^tNSPh)₃ while ZrCl₄(tht)₂ (tht = tetrahydrothiophene) with 5 equiv gave the homoleptic Zr(¦Ç²-Bu^tNSPh)₄. From ZrCl₂(¦Ç⁵-C₅H₅)₂ only ZrCl(¦Ç⁵-C₅H₅)₂(¦Ç²-Bu^tNSPh) was obtained. Using as starting materials MO₂Cl₂(dme) (dme = 1,2-dimethoxyethane, M = Mo or W), MoCl₂(NBu^t)₂ and WCl₂(NBu^t)₂(py)₂, interactions with LiNBu^tSPh gave ¦Ç²-sulfenamido compounds such as MoO₂(¦Ç²-Bu^tNSPh)₂. The Se analog of the W compound, i.e. W(NBu^t)₂(¦Ç²-Bu^tNSePh)₂ was made by interaction of Li₂W(NBu^t)₄ with PhSeBr. Where study was possible, NMR spectra over a temperature range indicate that invertomers and isomers occur. Six compounds were structurally characterized by x-ray diffraction. In all case the sulfenamido ligands are ¦Ç² bonded and the geometry about the N atoms is planar.

Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, Synthetic Route of 19117-31-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Armitage, D. A. published the artcileSulfur(II)-nitrogen bond. III. Synthesis of the sulfur(II)-nitrogen from sulfenates, Formula: C10H15NS, the publication is Journal of the Chemical Society [Section] C: Organic (1971), 3867-9, database is CAplus.

PhSOMe reacted with primary and secondary amines (e.g. MeNH2, Pr2NH) to give sulfenamides (e.g., PhSNHMe, PhSNPr2), and with Me3SiNMe2, Me3SiNEt2, and Me3SiNSO to give PhSNMe2, Ph-SNEt2, and PhSNSO, resp.; with Me3SiNHEt or Me3SiNHPr a mixture of PhSNHEt or PhSNHPr and PhSNEtSiMe3 or PhSNPrSiMe3 was obtained. PhSOMe reacted with MeN(SiMe3)2 to give PhSNMeSiMe3 and with PhSNHMe to give (PhS)2NMe. N2H4 reduced PhSOMe to Ph2S2.

Journal of the Chemical Society [Section] C: Organic published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, Formula: C10H15NS.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Greer, Alexander published the artcileExperimental and ab Initio Computational Evidence for New Peroxidic Intermediates (Iminopersulfinic Acids). Substituent Effects in the Photooxidations of Sulfenic Acid Derivatives, SDS of cas: 19117-31-8, the publication is Journal of the American Chemical Society (1997), 119(19), 4380-4387, database is CAplus.

A detailed ab initio study of the structures and energetics of the persulfoxides and thiadioxiranes derived from sulfenic acid derivatives (RSX) is reported. The persulfoxides adopt structures in which the O-O bond bisects the RSX angle while the thiadioxiranes prefer a distorted trigonal bipyramidal geometry. The thiadioxiranes are more stable in every case than their persulfoxide isomer. The exothermicities of the interconversions of the persulfoxide to the thiadioxirane increase in the substituent (X) order CH₃ < NH₂ < Cl < OCH₃ < SCH₃ < F from a low of 3 kcal/mol to a high of 31 kcal/mol. The activation barriers, on the other hand, decrease in the substituent order Cl > CH₃ ¡Ö NH₂ > OCH₃ ¡Ö SCH₃ > F from 27 to 10 kcal/mol. Only those persulfoxides which do not have a hydrogen on a heteroatom X exist in well-defined min. on the potential energy surface. Attempted minimization with tight convergence criteria of persulfoxides with heteroatom X-H bonds resulted in collapse via ene-like reactions to give hydroperoxy sulfonium ylides. In the case where X-H is N-H, the resulting hydroperoxysulfonium ylide (iminopersulfinic acid) adopts a hydrogen-bonded structure reminiscent of peracids. Exptl. evidence for the formation of these new peroxides was obtained by photooxidations of N-methyl-, N-n-butyl-, and N-tert-butylbenzenesulfenamides.

Journal of the American Chemical Society published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, SDS of cas: 19117-31-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Clennan, Edward L. published the artcileExperimental and computational evidence for the formation of iminopersulfinic acids, COA of Formula: C10H15NS, the publication is Journal of Organic Chemistry (1998), 63(10), 3397-3402, database is CAplus.

An exptl. and computational study of the reactions of singlet O₂ with N-substituted sulfenamides is reported. Intermediates capable of epoxidizing norbornene were observed during the photooxidations of PhSNHR (R = Me, Bu, CMe₃). These results are used to argue for the formation of iminopersulfinic acids. The structural integrity of 2 iminopersulfinic acids was supported by their successful location at the MP2/6-31G^* level of theory. Furthermore, the inability to locate computationally significant persulfinimide precursors suggests that the iminopersulfinic acids form by ene-like reactions involving near-simultaneous addition of singlet O₂ to S and H abstraction.

Journal of Organic Chemistry published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, COA of Formula: C10H15NS.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Datta, Mrityunjoy published the artcileFast and efficient synthesis of sulfinamides by the oxidation of sulfenamides using potassium fluoride and m-chloroperoxybenzoic acid, Computed Properties of 19117-31-8, the publication is Synthetic Communications (2012), 42(12), 1760-1769, database is CAplus.

A procedure for the synthesis of N-alkyl-, N-cycloalkyl-, N,N-dialkyl-, and N-arylarenesulfinamides from the corresponding sulfenamides using KF/m-chloroperoxybenzoic acid in CH₃CN-H₂O was described. High efficiency (fast reactions, ease of manipulation, and good yields) and absence of over-oxidation are the major advantageous features of this protocol.

Synthetic Communications published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, Computed Properties of 19117-31-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Tymann, Dina Christina published the artcilePhotochemical Approach to the Cyclohepta[b]indole Scaffold by Annulative Two-Carbon Ring-Expansion, Product Details of C10H15NS, the publication is Chemistry – A European Journal (2020), 26(52), 11974-11978, database is CAplus and MEDLINE.

The implementation of the concept of a photochem. elicited two-carbon homologation of a π-donor-π-acceptor substituted chromophore by triple-bond insertion was reported. Implementing a Ph connector between the slide-in module and the chromophore enabled the synthesis of cyclohepta[b]indole-type building blocks by a metal-free annulative one-pot two-carbon ring expansion of the five-membered chromophore. Post-irradiative structural elaboration provided founding members of the indolo[2,3-d]tropone family of compounds Control experiments in combination with computational chem. on this multibond reorganization process founded the basis for a mechanistic hypothesis.

Chemistry – A European Journal published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C15H14O3, Product Details of C10H15NS.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Tanaka, Tetsuaki published the artcileA new sulfenylation reagent, 3-phenylsulfenyl-2-(N-cyanoimino)thiazolidine, and its optically active version, COA of Formula: C10H15NS, the publication is Synlett (2000), 33-36, database is CAplus.

A new sulfenylation reagent, 3-(phenylthio)-2-(N-cyanoimino)thiazolidine (I), was developed, which is readily available and stable upon storage. Compound I easily reacts with amines or thiols to give the corresponding sulfenamides or asym. disulfides in excellent yields. The α-sulfenylation of carbonyl compounds with I proceeds smoothly. Furthermore, the optically active 4-diphenylmethyl derivative of I was synthesized as an asym. sulfenylation reagent, which realized 96% ee upon α-sulfenylation of a cyclic β-keto ester.

Synlett published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C6H12O2, COA of Formula: C10H15NS.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Miura, Yozo published the artcileESR studies of N-(arylthio)-tert-butylaminyls. Part VI, Quality Control of 19117-31-8, the publication is Bulletin of the Chemical Society of Japan (1977), 50(7), 1855-7, database is CAplus.

Me3CN•SC6H4R-p (I; R = H, F, Cl, Br, NO2) are easily generated by the photolysis of Me3CNHSC6H4R-p. ESR spectra of I were split into a 1:1:1 triplet by the interaction with the N nucleus, and each peak of the triplet was further split by the ring protons. The radicals are not sensitive to atm. O.

Bulletin of the Chemical Society of Japan published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, Quality Control of 19117-31-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia