Category: 23897-16-7

Platten, Andrew W. J.’s team published research in ChemCatChem in 14 | CAS: 23897-16-7

ChemCatChem published new progress about 23897-16-7. 23897-16-7 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Dimesitylphosphine oxide, and the molecular formula is C18H23OP, Safety of Dimesitylphosphine oxide.

Platten, Andrew W. J. published the artcileHydrophosphinylation of Styrenes Catalyzed by Well-Defined s-Block Bimetallics, Safety of Dimesitylphosphine oxide, the publication is ChemCatChem (2022), 14(5), e202101853, database is CAplus.

Advancing the applications of s-block heterobimetallic complexes in catalysis, authors report the use of potassium magnesiate (PMDETA)2K2Mg(CH2SiMe3)4 [PMDETA = N,N,N’,N’,N”-pentamethyldiethylenetriamine] for the catalytic hydrophosphinylation of styrenes under mild conditions. Exploiting chem. cooperation, this bimetallic approach offers greater catalytic activity and chemoselectivity than the single-metal components KCH2SiMe3 and Mg(CH2SiMe3)2. Stoichiometric studies between (PMDETA)2K2Mg(CH2SiMe3)4 and Ph2P(O)H help to elucidate the constitution of the active catalytic species, and illustrate the influence of donors on the potassium cation coordination, and how this may impact catalytic activity. Mechanistic investigations support that the rate determining step is the insertion of the olefinic substrate.

ChemCatChem published new progress about 23897-16-7. 23897-16-7 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Dimesitylphosphine oxide, and the molecular formula is C18H23OP, Safety of Dimesitylphosphine oxide.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Molitor, Sebastian’s team published research in Journal of the American Chemical Society in 136 | CAS: 23897-16-7

Journal of the American Chemical Society published new progress about 23897-16-7. 23897-16-7 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Dimesitylphosphine oxide, and the molecular formula is C18H23OP, HPLC of Formula: 23897-16-7.

Molitor, Sebastian published the artcileSelective Dehydrocoupling of Phosphines by Lithium Chloride Carbenoids, HPLC of Formula: 23897-16-7, the publication is Journal of the American Chemical Society (2014), 136(44), 15517-15520, database is CAplus and MEDLINE.

The development of a simple, transition-metal-free approach for the formation of phosphorus-phosphorus bonds through dehydrocoupling of phosphines is presented. The reaction is mediated by electronically stabilized lithium chloride carbenoids and affords a variety of different diphosphines under mild reaction conditions. The developed protocol is simple and highly efficient and allows the isolation of novel functionalized diphosphines in high yields.

Journal of the American Chemical Society published new progress about 23897-16-7. 23897-16-7 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Dimesitylphosphine oxide, and the molecular formula is C18H23OP, HPLC of Formula: 23897-16-7.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia