Category: 4141-48-4

Toste, F. Dean published the artcileFunctional group diversity by ruthenium-catalyzed olefin cross-metathesis, Application of Allyldiphenylphosphine oxide, the publication is Pure and Applied Chemistry (2002), 74(1), 7-10, database is CAplus.

Ruthenium-catalyzed olefin cross-metathesis tolerates a wide range of functional groups, including phosphine-boranes, sulfides, amines, phenols, and oxazolines. The catalyst discussed here was [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium. The high functional group tolerance allows for the use of an olefin as a linchpin for the synthesis of a variety of bi-, tri-, and tetradentate chiral ligands with a high degree of functional group diversity. A lecture presented at the 11th annual IUPAC International Symposium on Organometallic Chem. Directed Toward Organic Synthesis (OMCOS-11), Taipei, Taiwan July 22-26, 2001.

Pure and Applied Chemistry published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C10H11NO4, Application of Allyldiphenylphosphine oxide.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Baechler, Raymond D. published the artcileContrasting thermal reactions of allylic sulfilimines and phosphinimines, Category: catalysis-chemistry, the publication is Tetrahedron Letters (1988), 29(42), 5353-4, database is CAplus.

Allylic sulfilimines and phosphinimines undergo spontaneous but contrasting rearrangements at low temperatures Whereas PhN:SPhCH₂CH:CH₂ is converted to isomeric sulfenamide PhN(SPh)CH₂CH:CH₂ by (2,3)-sigmatropic rearrangement, structurally analogous phosphinimine PhN:PPh₂CH₂CH:CH₂ undergoes an unusually facile double bond shift to form PhN:PPh₂CH:CHMe with an isomeric vinylic structure.

Tetrahedron Letters published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Schulz, Michael D. published the artcileCopper(I) halides inhibit olefin isomerized by-products from phosphine-based Grubbs’ metathesis catalysts in polar protic solvents, Synthetic Route of 4141-48-4, the publication is Transition Metal Chemistry (Dordrecht, Netherlands) (2014), 39(7), 763-767, database is CAplus.

Copper(I) halides were employed as ‘phosphine sponges’ to sequester phosphor-ylides when using phosphine-based Grubb’s metathesis catalysis in polar protic solvents and under heat. These cuprous halides were hypothesized to significantly slow the formation of the ruthenium hydride olefin isomerization catalyst. Their use was demonstrated in both cross metathesis and ring-closing metathesis.

Transition Metal Chemistry (Dordrecht, Netherlands) published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C38H24F4O4P2, Synthetic Route of 4141-48-4.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia