Category: 6972-05-0

Pandeya, S. N. published the artcileSynthesis, anticonvulsant and analgesic activity of 1,2,4-dithiazoline derivatives, Recommanded Product: 1,1-Dimethylthiourea, the publication is Indian Journal of Pharmaceutical Sciences (1982), 44(2), 31-3, database is CAplus.

Iminodithiazolines I (R = 4-EtOC₆H₄NH, Me₂N; R¹ = Ph, 4-MeC₆H₄, PhCH₂, Me) were prepared by S-benzylating RCSNH₂, treating RC(:NH)SCH₂Ph with R¹NCS, and oxidative cyclization of R¹NHCSN:CRSCH₂Ph with Br₂. I (R = 4-MeC₆H₄, R¹ = CH₂Ph) was obtained as a by-product. At 10 mg/kg i.p. I (R = 4-EtOC₆H₄NH, R¹ = Ph, 4-MeC₆H₄; R = NMe₂, R¹ = 4-MeC₆H₄; R = 4-MeC₆H₄, R¹ = CH₂Ph) had 40-80% anticonvulsant activity in maximum electroshock test. I (R = 4-EtOC₆H₄NH, R¹ = 4-MeC₆H₄, PhCH₂; R = 4-MeC₆H₄, R¹ = CH₂Ph) had analgesic activity at 10 mg/kg i.p. in rats.

Indian Journal of Pharmaceutical Sciences published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, Recommanded Product: 1,1-Dimethylthiourea.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Aziz, I. published the artcileSynthesis, Characterization, DNA Interaction Study, Antibacterial and Anticancer Activities of New Palladium(II) Phosphine Complexes, Category: catalysis-chemistry, the publication is Russian Journal of General Chemistry (2018), 88(3), 551-559, database is CAplus.

Palladium(II) complexes with N,N-dimethylthiourea and phosphines [tri-p-tolylphosphine (Tptp), benzyl(diphenyl)phosphine (Bdp), cyclohexyl(diphenyl)phosphine (Cdp)] were synthesized by the direct reaction of K₂[(PdCl₄)] with the corresponding phosphines and then with N,N-dimethylthiourea at a molar ratio of 1:2:2, resp. The general formula of these complexes is [Pd(L1)₂(L₂)₂]Cl₂, where L1 = N,N-dimethylthiourea (Dmtu), L2 = Tptp, Bdp, Cdp. The complexes were characterized by elemental analyses, multinuclear NMR (¹H, ¹³C, ³¹P), and FTIR. The complex with cyclohexyl(diphenyl)phosphine was also characterized by single crystal x-ray anal. The spectral and crystallog. data suggest monodentate coordination of dimethylthiourea through the S atom and of the phosphine ligand through the P atom and distorted square planar environment of Pd(II). The synthesized complexes were screened for DNA binding, antibacterial, cytotoxic, and antitumor activities. The complexes show interaction with DNA via intercalative mode. The complexes show good activity against both gram pos. and gram neg. bacteria as compared to that of a standard drug, Imipenem. Their antitumor activity against MCF7 tumor cell line is comparable with doxorubicin. MTT assay was used to study the cytotoxicity of the studied compounds

Russian Journal of General Chemistry published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Kawamatsu, Yutaka published the artcile2-Amino-4-phenylthiazole derivatives as anti-atherogenic agents, Formula: C3H8N2S, the publication is European Journal of Medicinal Chemistry (1981), 16(4), 355-62, database is CAplus.

Thiazoles I [R = (un)substituted benzyloxy, Ph, PhO, 4-ClC₆H₄O, PhCH₂, PhCH₂CH₂O, 4-ClC₆H₄CO₂, 4-ClC₆H₄CONHCH₂CH₂, 4-ClC₆H₄CH₂NH, 4-ClC₆H₄CH₂S, 3-pyridylmethoxy, 2-thienylmethoxy, cyclohexylmethoxy, 1-methyl-1-cyclohexylmethoxy, Me₃CCH₂O, Me(CH₂)₁₄CH₂O; R¹ = H, Me; R² = H, CHO, acyl, Me, MeSO₂, 4-MeC₆H₄SO₂, allyl, cyclohexyl, Ph; R¹R² = (CH₂)₅] were prepared E.g. refluxing 4-ClC₆H₄CH₂OC₆H₄COCH₂Cl-4 with thiourea and NaOAc in H₂O/EtOH gave 77.5% I (R = 4-ClC₆H₄CH₂O, R¹ = R² = H). I.HCl (R = 4-FC₆H₄CH₂O, R¹ = R² = H) showed pronounced antiatherogenic activity in rats.

European Journal of Medicinal Chemistry published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, Formula: C3H8N2S.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Yonemoto, Katsumi published the artcileReaction of 1,4,2-dithiazolium salts with amino compounds, Quality Control of 6972-05-0, the publication is Bulletin of the Chemical Society of Japan (1988), 61(11), 4043-9, database is CAplus.

Systematic studies on the behavior of 1,4,2-dithiazolium cations I (R = Et, R¹ = Ph, 4-ClC₆H₄, 4-MeC₆H₄, 4-MeOC₆H₄; NR² = NMe₂, NPhMe, morpholino, R¹ = Ph) toward various amino compounds (ammonia, aliphatic and aromatic amines, hydrazine, semicarbazide, thiosemicarbazide derivatives, etc.) were performed. The reaction pathway could be classified into three types, depending on three possible fission modes of the initially formed adduct. The main products were 5-imino-1,4,2-dithiazole, thiourea, and 1,3,4-thiadiazole derivatives, through the three different pathways, resp. In order to clarify the factors controlling the reaction courses, the reactions of I with p-substituted aniline derivatives were carried out under systematically varying conditions. The strength of bases and the polarity of solvents had clear influence on the reactivity. The reaction mechanism is also discussed.

Bulletin of the Chemical Society of Japan published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C7H7IN2O, Quality Control of 6972-05-0.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Rotti, P. B. published the artcileEffect of thiourea and substituted thioureas on electrocrystallization of copper, Formula: C3H8N2S, the publication is Bulletin of Electrochemistry (1987), 3(4), 305-11, database is CAplus.

The presence of traces of thiourea (TU), N,N-dimethylthiourea (DMTU) and phenylthiourea (PTU) in highly purified acid CuSO₄ bath affects the morphol. of Cu electrodeposits and the cathodic polarization on Cu single crystal (100), (110) and (111) planes, in a range of c.d. 2-20 mA/cm². At low c.d. on (100) plane these addition agents bring about a transition from layer type of deposit to ridge type and to pyramidal type of deposit which finally transformed to polycrystalline At high c.ds., layers, truncated pyramids and blocks obtained in pure solution transformed to ridges and pyramidal type which got transformed to polycrystalline deposit. The cathodic overpotentials in the presence of these addition agents were always lower compared to those observed in pure acid CuSO₄ bath, but the trend in the variation of overpotential with time remained the same. The morphol. and overpotential changes observed during electroplating of Cu depend on the concentration of addition agents and the c.d. The cathodic Tafel slope of 120 + 5 mV obtained in pure bath changed slightly in the presence of these addition agents.

Bulletin of Electrochemistry published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, Formula: C3H8N2S.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Subramanyam, N. C. published the artcileThiourea and substituted thioureas as corrosion inhibitors for aluminum in sodium nitrite solution, Name: 1,1-Dimethylthiourea, the publication is Corrosion Science (1993), 34(4), 563-71, database is CAplus.

The effect of sulfur-containing organic compounds such as thiourea (TU), Ph thiourea (PTU), di-Ph thiourea (DPTU), allyl thiourea (ATU), p-tolyl thiourea (p-TTU) and N,N-di-Me thiourea (DMTU) on the corrosion of aluminum in sodium nitrite solution at 303 K was investigated using weight loss and polarization techniques. A significant decrease in the corrosion rate of aluminum was observed by the presence of traces of these compounds The corrosion rate was a function of the nature, concentration of the inhibitor, and temperature of the medium. The degree of surface coverage calculated from the results was used to evaluate the free energy of adsorption of the inhibitors. All the inhibitors follow the Frumkin adsorption isotherm. The mechanism of inhibitor action has been discussed on the basis of adsorption and mol. polarizability of the inhibitor. These compounds act as cathodic inhibitors. The neg. values of free energy of adsorption and high degree of protection also confirm the strong interaction of these compounds on the corroding aluminum surface.

Corrosion Science published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C17H29BO2, Name: 1,1-Dimethylthiourea.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Etefagh, R. published the artcileEffect of Zn doping on optical properties and photoconductivity of SnS₂ nanocrystalline thin films, SDS of cas: 6972-05-0, the publication is Bulletin of Materials Science (2013), 36(3), 411-416, database is CAplus.

Zn-doped SnS₂ thin films have been deposited simply by spray pyrolysis technique. The doping level was changed from [Zn/Sn] = 0 to 7.5 at%. The films were characterized by x-ray diffraction, STM, energy dispersive x-ray anal. (EDX), photoluminescence, and UV-vis spectroscopy. XRD patterns of the films with different zinc contents show that all samples have polycrystalline structure with Berndtite dominant phase and preferred orientation of (001) growth plane. Zn insertion causes a significant decrease in grain size. Optical bandgap of the films were calculated for different dopant concentrations and they lie in the region of 2.3-2.7 eV. Surprisingly, regardless of doping level, the luminescent properties of films are related to the fundamental bandgap energy and deep levels inside the bandgap. Photoconductivity of the films were measured under visible light. Sensitivity to the light increases by zinc incorporation, which was a large amount for SnS₂:Zn of 7.5%.

Bulletin of Materials Science published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, SDS of cas: 6972-05-0.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Vignesh, Rajendran Babhu published the artcileCorrosion protection behaviour of sol-gel derived N,N-dimethylthiourea doped 3-glycidoxypropyltrimethoxysilane on aluminium, Recommanded Product: 1,1-Dimethylthiourea, the publication is Progress in Organic Coatings (2014), 77(1), 136-141, database is CAplus.

The present work describes the anticorrosion features of inhibitor doped sol-gel coating on Al metal. Sol-gel coatings were prepared by using 3-glycidoxypropyltrimethoxysilane (GPTMS) as parent precursor. In order to improve the corrosion resistance property of coating, N,N-dimethylthiourea was added into the sol-gel matrix. The corrosion inhibitor doped sol-gel coating on metal was characterized by Fourier transform IR anal. (FTIR) and scanning electron microscope (SEM). Inhibition effect of N,N-dimethylthiourea doped GPTMS coating on Al substrates in 1% NaCl solution was investigated using electrochem. impedance (EIS) and polarization studies. EIS results showed that the corrosion resistance of sol-gel coating significantly improved upon addition of N,N-dimethylthiourea. The study had outlined the nuances of doping an organic inhibitor to enhance the protection ability of sol-gel coating on Al metal.

Progress in Organic Coatings published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C8H10S, Recommanded Product: 1,1-Dimethylthiourea.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Friedrichsen, Willy published the artcileReactions of mesoionic five-membered heterocycles with o-quinonoid compounds. IV. Mono- and tricyclic 1,3-thiazolium-4-olates, 1,3-dithiolylium-4-olates, Related Products of catalysis-chemistry, the publication is Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie (1981), 36B(5), 609-21, database is CAplus.

Monocyclic 1,3-thiazolium-4-olates I (R = H, NO₂; R¹ = Ph, p-ClC₆H₄) react with o-quinonoid compounds to give [¦Ð4 + ¦Ð4]cycloadducts II and III; tricyclic 1,3-thiazolium-4-olates IV (X = CH:CH, S) similarly yield compounds V (Z = O, PhSO₂N), which can formally be derived from a ketene tautomer. 1,3-Dithiolylium-4-olates are borderline cases; both [¦Ð4 + ¦Ð2], e.g., VI, and [¦Ð4 + ¦Ð4]adducts VII were obtained.

Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Bream, John B. published the artcileSeven-membered heterocycles. 25. Synthesis of 1- and 5-aryl-2,4-benzothiazepines, Application In Synthesis of 6972-05-0, the publication is Helvetica Chimica Acta (1977), 60(8), 2872-80, database is CAplus.

Benzothiazepines I (R = H, Me, R¹ = H, 7-Cl, R² = H) and II [R¹ = R² = H, R³ = R⁴ = Me, R³R⁴ = (CH₂)_2-4; R¹ = 8-Cl, R² = H, R³R⁴ = (CH₂)₃; R¹ = H, R² = Me, F, R³R⁴ = (CH₂)₃] were prepared by treating the xylyl dibromides III with thioureas and cyclizing with base. The intermediate IV gave V. Benzothiazepines VI (R⁵ = H, 7-Cl, 8-Cl; R⁶ = H, Me, CH₂CH₂Ph; R⁷ = H, Me) and VII [R⁵ = same; R⁸ = H, Me, R⁹ = Me; R⁸R⁹ = (CH₂)_2-3] were obtained by cyclizing VIII.

Helvetica Chimica Acta published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, Application In Synthesis of 6972-05-0.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia