Category: 10517-44-9

Gozdowska, M. published the artcileSynthesis and in vitro anticancer activity of conjugates of MDP with amino-acridine/acridone derivatives, Recommanded Product: Propane-1,3-diamine dihydrochloride, the publication is Polish Journal of Chemistry (1997), 71(6), 767-773, database is CAplus.

A series of MDP (muramyl dipeptide) analogs modified at the C-terminus of MDP mol. by the formation of an amide bond between the carboxylic group of isoglutamine and the amine function of the resp. derivative of acridine or acridone were synthesized as potential anticancer agents.

Polish Journal of Chemistry published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, Recommanded Product: Propane-1,3-diamine dihydrochloride.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Rapsomanikis, Spyridon published the artcileMethylation of lead(II) and methyllead(IV) compounds in water by a trans-dimethylcobalt(III) complex, Recommanded Product: Propane-1,3-diamine dihydrochloride, the publication is Inorganica Chimica Acta (1984), 89(3), 179-83, database is CAplus.

The Me cobalamin model and carbanion donor [CoLMe₂]ClO₄ (I) was prepared by the reaction of H₂N(CH₂)₃NH₂, MeCOCOMe, and Co(OAc)₂ to give [CoLCl₂]ClO₄, which was methylated with MeI to give I. I methylated Pb²⁺(aq) to give 0.12% PbMe₄ and 14.2% CH₄; in the Pb^2-I-MnO₂-MeI system, only Pb⁺² and I were necessary for PbMe₄ formation. I also methylated low concentrations of aqueous Me₂PbCl₂ and Me₃PbCl giving 12-22% CH₄ and 33.3-65.0% PbMe₄. Thus aqueous Pb⁺² and partially methylated Pb compounds were methylated by a Me cobalamin model to give toxic, air-transportable PbMe₄ in environmentely significant yields.

Inorganica Chimica Acta published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, Recommanded Product: Propane-1,3-diamine dihydrochloride.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Meschke, C. published the artcileComplexes of cucurbituril with mono- and diammonium ions in aqueous formic acid studied by calorimetric titrns, Related Products of catalysis-chemistry, the publication is Thermochimica Acta (1997), 297(1-2), 43-48, database is CAplus.

The thermodn. data of the complexation reaction between the ligand cucurbituril and different alkylmonoamine and alkyldiamine hydrochlorides have been studied in aqueous formic acid. The stability constants, the reaction enthalpies and the reaction entropies are obtained from calorimetric titrations At both rims of the cavity of cucurbituril the carbonyl groups interact with ions by ion-dipole interactions. If ammonium ions with longer alkyl chains enter the hydrophobic cavity of cucurbituril hydrophobic interactions participate in the complex formation. The hydrophobic contribution to the reaction enthalpy is calculated for the alkyl monoammonium ions. In 50% (volume/volume) formic acid the enthalpies of the hydrophobic interactions contribute more to the exptl. reaction enthalpy that the ion-dipole interactions.

Thermochimica Acta published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Ocak, Mirac published the artcileThermodynamic data for the formation of 1:1 and 2:1 complexes of ¦Á,¦Ø-diamino dihydrochlorides with 18-crown-6 in aqueous solution, Quality Control of 10517-44-9, the publication is Journal of Solution Chemistry (2008), 37(5), 595-601, database is CAplus.

Calorimetric titrations are used to study the interactions between the crown ether 18-crown-6 and several ¦Á,¦Ø-diamino dihydrochlorides in aqueous solution These complexes are formed by ion-dipole interactions between the pos. charged nitrogen atoms and the oxygen donor atoms of the crown ether. Depending on the exptl. conditions, the formation of 1:1 or 2:1 complexes (ligand:diamines) can be studied. The solvation of the ligand and the amines are responsible for the observed thermodn. values. The number of water mols. released during the reaction were calculated from the determined reaction entropies. Formation of 1:1 complexes distorts the solvation shell around the mols. As a result, the number of solvent mols. released during the formation of the 2:1 complexes is slightly smaller than the number released from formation of the 1:1 complex. No exptl. evidence is observed for the formation of 1:1 complexes between one crown ether and two protonated amino groups.

Journal of Solution Chemistry published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, Quality Control of 10517-44-9.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Meikle, Peter J. published the artcilePreparation of polysaccharide-enzyme conjugates for competitive binding assays, Application In Synthesis of 10517-44-9, the publication is Glycoconjugate Journal (1990), 7(3), 207-18, database is CAplus.

A variety of bacterial O-polysaccharides were covalently linked to enzymes and it was demonstrated with three discrete monoclonal antibodies that enzyme-glycoconjugates function as convenient labeled antigens in direct enzyme immunoassays, particularly competitive assays that quantify bacterial O-antigens. Two strategies, each involving reductive amination, were used to couple O-polysaccharides to enzymes, while retaining high enzymic activity. Reduction of the Schiff base formed between 1,3-diaminopropane and the terminal reducing ketodeoxyoctanoic acid (KDO) residue present in the majority of the lipopolysaccharide (LPS) core domains, following mild acid removal of Lipid A, offered the most direct route to mono-aminated polysaccharide. Alternatively, mild periodate oxidation of KDO and heptose residues generated multiple aldehyde targets for Schiff base formation, without affecting the O-antigenic determinant. Hetero- and homobifunctional coupling reagents, sulfosuccinimidyl-4-(N-maleimidomethyl)-cyclohexane-1-carboxylate and disuccinimidyl suberate, activated polysaccharide for coupling to enzymes at amino and sulphydryl sites and produced conjugates that retained at least 95% of the original enzymic activity. The most suitable enzyme conjugates, especially for competitive inhibition EIA were those bearing one polysaccharide chain, and these were easily prepared from horse-radish peroxidase. Although the extent of conjugation of activated polysaccharide to ¦Â-galactosidase and alk. phosphatase could be controlled by reaction stoichiometry, the use of these enzymes were a less effective utilization of valuable antigen and enzyme.

Glycoconjugate Journal published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, Application In Synthesis of 10517-44-9.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Padmanabhan, S. published the artcileRelative affinities of divalent polyamines and of their N-methylated analogs for helical DNA determined by sodium-23 NMR, HPLC of Formula: 10517-44-9, the publication is Biochemistry (1991), 30(30), 7550-9, database is CAplus and MEDLINE.

Interactions of divalent polyamines with double-helical DNA in aqueous solution are investigated by monitoring the decrease in ²³Na NMR relaxation rates as NaDNA is titrated with H₃N⁺-(CH₂)_m^-+NH₃, where m = 3, 4, 5, or 6. Analogous measurements are made for the same homologous series of methylated polyamines (methonium ions). The dependence of the ²³Na relaxation rates on the amount of added divalent cation (M²⁺) is analyzed quant. in terms of a two-state model. The sodium ions are assumed to be in rapid exchange between a bound state, where they are close enough to DNA so that it affects their relaxation rate, and a free state in bulk solution, where their relaxation rate is the same as in solutions containing no DNA. The distribution of Na⁺ and M²⁺ between these states is described quant. in terms of an ion-exchange parameter: D_Mú·(p_B^M)(1 – p_B^Na)ⁿ/(p_B^Na)ⁿ(1 = p_B^M), where p_B^Na and p_B^M are the fractions of Na⁺ and M²⁺ that are close enough to DNA to be considered bound (by the NMR criterion), and n is the number of sodium ions displaced from DNA by the binding of one M²⁺ ion. For each of the polyamines and methonium ions investigated here, equations derived from this two-state model yield acceptable fittings of the titration curves if r_Na^o, the number of sodium ions bound per DNA phosphate when no competing cations are present, is assigned a value between 0.6 and 1.00. Within this range, changing the value assigned to r_Na^o does change the best-fitted values of D_M determined for the polyamines (D_H) and for the methonium ions (D_Me) but does not alter the following conclusions about the trends in these parameters. (1) For polyamines and methonium ions of the same m, D_H exceeds D_Me by factors that are significantly larger for m = 3 and 4 than for m = 5 and 6. (2) D_H For m = 3 and 4 is larger than D_H for m = 5 and 6. (3) D_Me For m = 3 and 4 is smaller than D_Me for m = 5 and 6.

Biochemistry published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, HPLC of Formula: 10517-44-9.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Brisson, Josee published the artcileNew refinement of the crystal structure of 1,3-diaminopropane dihydrochloride, Computed Properties of 10517-44-9, the publication is Journal of Crystallographic and Spectroscopic Research (1982), 12(1), 39-43, database is CAplus.

The title compound is orthorhombic, space group Pbcn, with a 8.567(3), b 9.341(2), and c 9.444(9) ?; d.(exptl.) = 1.30 and d.(calculated) = 1.29 for Z = 4. The structure, which had previously been solved and refined to R = 0.196 by S. Hirokawa et al. (1968), was refined to R = 0.034. At. parameters, bond angles and distances are given.

Journal of Crystallographic and Spectroscopic Research published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, Computed Properties of 10517-44-9.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

El Hajj, A. published the artcileNew process of preparation of pyrazolidine: synthesis, extraction and flow-sheet, Related Products of catalysis-chemistry, the publication is MATEC Web of Conferences (2013), 01045, database is CAplus.

A new process for the preparation of the pyrazolidine (PYRZ), by intramol. Raschig way was developed. Synthesis and extraction are described. The formation of pyrazolidine is carried out in two successive steps. The first involves the oxidation of 1,3-diaminopropane (DAP) by sodium hypochlorite and formation of N-chloro-1,3-diaminopropane. The second step consists of a cyclization of N-chloro-1,3-diaminopropane leading to pyrazolidine. For the extraction the authors determined 3 isothermal sections (289, 313, and 323 K) of the solid-liquid-liquid isobaric ternary system H2O-DAP-NaOH by isoplethic thermal anal. and acid-base titration The second stage involves a selective precipitation of the two compounds in form of a salt by addition of hydrochloric acid.

MATEC Web of Conferences published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Schneider, Hans Joerg published the artcileInteraction of acyclic and cyclic peralkylammonium compounds and DNA, Safety of Propane-1,3-diamine dihydrochloride, the publication is Angewandte Chemie (1992), 104(9), 1244-6 (See also Angew. Chem., Int. Ed. Engl., 1992, 31(9), 1207-9), database is CAplus.

Electrostatic binding of calf thymus B-DNA by amines was studied with regard to amine structure in the binding mechanism. Free energies of binding by various amines were compared. DNA binding response to amine protonation and alkyl chain length and flexibility were considered. Acyclic and macrocyclic polyammonium derivatives were used as models, and biol. polyamines were discussed.

Angewandte Chemie published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, Safety of Propane-1,3-diamine dihydrochloride.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Kay, John E. published the artcileDirect effects of 1,3-diaminopropane on reticulocyte lysate protein synthesis, SDS of cas: 10517-44-9, the publication is FEBS Letters (1980), 121(2), 309-12, database is CAplus and MEDLINE.

1,3-Diaminopropane-2HCl (I) [10517-44-9] inhibited protein synthesis by reticulocyte lysates in the presence of 2 mM Mg²⁺. This was apparently a simple cation effect, since I itself supported protein synthesis by the system in the absence of normal divalent cations. The inhibitory action of I was not due to an antagonistic effect toward spermidine, a natural polyamine associated with protein synthesis, because the inhibition was not diminished when the lyzate was supplemented with large amounts of spermidine-HCl [334-50-9]. Direct inhibition of protein synthesis by I would include, among other effects, a reduction in the concentration of enzymes required for polyamine synthesis. This raises questions as to the specificity of I as an inhibitor of polyamine formation.

FEBS Letters published new progress about 10517-44-9. 10517-44-9 belongs to catalysis-chemistry, auxiliary class Salt,Amine,Aliphatic hydrocarbon chain, name is Propane-1,3-diamine dihydrochloride, and the molecular formula is C3H12Cl2N2, SDS of cas: 10517-44-9.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia