Category: 14707-75-6

Nielson, Arnold T. published the artcileSynthesis of 7-(N-alkylamino)- and 7-(N,N-dialkylamino)-1,3,5-triazaadamantanes, COA of Formula: C7H14N4, the publication is Journal of Heterocyclic Chemistry (1975), 12(1), 161-4, database is CAplus.

Alkylaminotriazaadamantanes (I, R1 = Et, Pr, Bu, pentyl, hexyl, Me2CHCH2, EtMeCHCHMeCH2) were prepared in 92-9% yields by reductive alkylation of I (R1 = H) with R1CHO. II were prepared in 90-100% yields by reductive methylation of I with HCHO. HCHO also reacted with I (R1 = H) to give II (R1 = Me). Reductive alkylation of I (R1 = H) with OHC(CH2)3CHO gave 26% I (NHR1 = 1-piperidyl).

Journal of Heterocyclic Chemistry published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, COA of Formula: C7H14N4.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Hodge, E. B. published the artcile7-Nitro-1,3,5-triazaadamantane and derivatives. Reactions of azaadamantanes with anhydrides, COA of Formula: C7H14N4, the publication is Journal of Organic Chemistry (1972), 37(2), 320-1, database is CAplus.

A new method of preparation and a number of reactions of 7-nitro-1,3,5-triazaadamantane (I) are given. The reactions of I with anhydrides leads to 3,7-diacyl-5-nitro-1,3,7-triazabicyclo[3.3.1]nonanes. This same reactions was studied with hexamethylenetetramine, which, with propionic anhydride, gave 1,3,5,7-tetrapropionyloctahydro-tetrazocine.

Journal of Organic Chemistry published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, COA of Formula: C7H14N4.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Gijsman, Pieter published the artcileNew synergists for hindered amine light stabilizers, COA of Formula: C7H14N4, the publication is Polymer (2002), 43(5), 1573-1579, database is CAplus.

The development of hindered amine light stabilizers (HALS) in the seventies led to a tremendous increase in the outdoor use of polyolefins. Although since that time a great deal of insight has been gained into the UV-degradation mechanism of polyolefins and the mechanism of action of HALS, no new UV-stabilization chem. has been discovered. The most recent thoughts about the UV-degradation mechanism of polyolefins (initiation of photooxidation by polymer oxygen charge transfer complexes (CTCs)) and new insights into the mechanism of action of HALS stabilizers (quenching of these CTCs) are explored as a basis for designing new UV-stabilizers. A mechanism is proposed that explains the action of HALS as a quencher. Based on this mechanism several other possible quenchers (bridged amines) have been suggested. These bridged amines are active as UV-stabilizers in films and plaques and they show a synergism with HALS stabilizers. These new stabilizers are the most effective when they are present at concentrations higher than 0.1% and at higher concentrations of HALS. In such cases the addition of these synergists to a HALS stabilized system can lead to an improvement of a factor of 2-3.

Polymer published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, COA of Formula: C7H14N4.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Edwards, Afarin published the artcileNitration of 7-substituted 1,3,5-triaza-adamantanes, Application of 1,3,5-Triazaadamantan-7-amine, the publication is Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) (1977), 1989-92, database is CAplus.

Nitrations of the triazaadamantanes I (R = NO₂, NH₂, Br, NHAc, N:CHC₆H₄OMe-4) with various nitrating mixtures are described. E.g., reaction of I (R = NO₂) with HNO₃-NH₄NO₃ (NAN) gave the diazacyclohexane derivative II (R = NO₂, R¹ = CH₂N⁺H₃NO₃^–) whereas treatment with HNO₃-H₂SO₄ (NS) gave the bicyclic product III. Similar treatment of I (R = NH₂, Br) with NAN or NS, I (R = NHAc) with NAN, and I (R = N:CHC₆H₄OMe-4) with fuming HNO₃ gave II [R = NHNO₂, Br, R¹ = CH₂N⁺H₃NO₃^–; RR¹ = CH₂N(NO)₂CH₂NAc, CH₂N(NO₂)CH₂NH, resp.]. The mechanism which is postulated for the nitration reactions is similar to that suggested by W. (1976) for the nitration of hexamine with HNO₃.

Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Application of 1,3,5-Triazaadamantan-7-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Edwards, A. published the artcileNMR studies on some 1,3,5-triazaadamantane derivatives, Related Products of catalysis-chemistry, the publication is Organic Magnetic Resonance (1978), 11(2), 103-5, database is CAplus.

The ¹H and ¹³C NMR spectra of 11 1,3,5-triazaadamantane derivatives are reported. Ring protonation decreases the screening in the ¹H NMR spectrum and increases that in the corresponding ¹³C NMR spectrum. Triaryl-substituted compounds exist as a single isomer with diequatorial and monoaxial substituents.

Organic Magnetic Resonance published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Gridunov, I. T. published the artcileStudy of the effect of adamantane derivatives in nitrile rubber vulcanizates, Related Products of catalysis-chemistry, the publication is Trudy Instituta – Moskovskii Institut Tonkoi Khimicheskoi Tekhnologii imeni M. V. Lomonosova (1975), 5(1), 97-9, database is CAplus.

The vulcanization of SKN 26 rubber in the presence of 0.6-1.4% 7-nitro-1,3,5-triazaadamantane (I) [14612-28-3], 7-amino-1,3,5-triazaadamantane (II) [14707-75-6] or 7-dimethylamino-1,3,5-triazaadamantane (III) [32476-16-7] at 150-80¡ã showed that I, II, and III were vulcanization accelerators having a large induction period. The vulcanizates had good physicomech. properties when SKN 26 rubber was vulcanized in the presence of I at 180¡ã for 50 min.

Trudy Instituta – Moskovskii Institut Tonkoi Khimicheskoi Tekhnologii imeni M. V. Lomonosova published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Gridunov, I. T. published the artcileEffect of 7-amino-1,3,5-triazaadamantane on the crosslinking of butadiene-acrylonitrile rubber, Recommanded Product: 1,3,5-Triazaadamantan-7-amine, the publication is Kauchuk i Rezina (1977), 19-20, database is CAplus.

7-Amino-1,3,5-triazaadamantane (I) [14707-75-6], prepared in a 2-step process via 7-nitro-1,3,5-triazaadamantane preparation and reduction, was an effective vulcanization accelerator for nitrile rubber SKN-26. Rubber compositions containing an optimal amount of 1 phr I gave vulcanizates having improved physicomech. properties in comparison to those obtained using a standard accelerator (2-MBT). In addition I can be used at higher vulcanization temperatures (¡Ü180¡ã) than the 2-MBT.

Kauchuk i Rezina published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Recommanded Product: 1,3,5-Triazaadamantan-7-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Ignat’eva, S. N. published the artcile[[N-(1,3,5-Triazaadamant-7-yl)amino]alkyl]phosphine oxides, Safety of 1,3,5-Triazaadamantan-7-amine, the publication is Zhurnal Obshchei Khimii (1996), 66(11), 1800-1801, database is CAplus.

Treating RCH:NR’ (R = 4-EtOC₆H₄, 4-Me₂NC₆H₄, 3,4-methylenedioxyphenyl; R’ = 1,3,5-triazaadamant-7-yl throughout this abstract) with Ph₂PH in C₆H₆ gave the corresponding R’NHCHRP(O)Ph₂.

Zhurnal Obshchei Khimii published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Safety of 1,3,5-Triazaadamantan-7-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Zubairov, M. M. published the artcileCharacterization of chlorine-free biocidal agents based on nontoxic or slightly toxic azaadamantane compounds, SDS of cas: 14707-75-6, the publication is Russian Journal of Physical Chemistry B (2015), 9(3), 471-480, database is CAplus.

The bactericidal properties of a series of 20 chlorine-free biocidal agents based on monoaza-, diaza-, triaza-, and tetraazaadamantanes and their homo and dihomo analogs were studied. Based on the exptl. results, the most active compound 1,3,6,8-tetraazatricyclo[4.4.1.1^3.8]dodecane was chosen in order to study its biocidal activity and pharmacol. and toxicol. characteristics. Disinfection conditions for the viral and bacterial causative agents of taxonomic groups of different etiol. were determined It was found that the above compound is characterized by high bactericidal, viricidal, mycocidal, and sporicidal activities, and it is a promising agent for the development of an industrial process for the production of a safe chlorine-free disinfectant.

Russian Journal of Physical Chemistry B published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C5H6BNO2, SDS of cas: 14707-75-6.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Kafka, Z. published the artcileNitrogen compounds of adamantane. IV. Paper chromatography of azaadamantane derivatives, Computed Properties of 14707-75-6, the publication is Collection of Czechoslovak Chemical Communications (1974), 39(11), 3268-71, database is CAplus.

The separation of 1-azaadamantane (I) and its quaternary salts, 1,3-diazaadamantane (II) and its tetrasubstituted derivatives, and 1,3,5-triazaadamantane (III) and its derivatives was studied by descending chromatog. on Whatman number 1 paper at 20¡ã. The Rf values in various solvents are tabulated. Good separation of I and its quaternary salts was achieved by using a solvent system containing HCl and an alc. with a branched chain, e.g. iso-PrOH or 2-methyl-1-propanol. For the separation of II and its derivatives, HCl was replaced by HOAc; but the best results were obtained by using 20:1:4 EtOH-NH4OH(25%)-H2O. For the separation of III and its derivatives a neutral solvent system, i.e. alcs.-H2O was used. For the detection of I and II and their derivatives, Dragendorff’s reagent was used. To detect III and its derivatives, which do not contain either a primary or a secondary amino group, a solution of 4-dimethylaminobenzaldehyde in EtOH and HCl was used. The quaternary salts of I and derivatives of III were applied as aqueous solutions; derivatives of II were dissolved in HOAc or in EtOH-HCl.

Collection of Czechoslovak Chemical Communications published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Computed Properties of 14707-75-6.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia