Category: 14707-75-6

Galik, V. published the artcileNitrogen compounds of adamantane. VI. 1,3,5-Triazaadamantane and its derivatives, COA of Formula: C7H14N4, the publication is Collection of Czechoslovak Chemical Communications (1975), 40(2), 442-7, database is CAplus.

1,3,5-Triazaadamantane I was prepared from 7-nitro-1,3,5-triazaadamantane by reduction with Zn dust in alc. NaOH, conversion of the obtained 7-amino-1,3,5-triazaadamantane (II) to 7-bromo- or 7-chloro-1,3,5-triazaadamantane and dehalogenation with Zn dust in alc. NaOH. Refluxing II with 7 aldehydes in C6H6 afforded III (R = Pr, Ph, 4-Me2NC6H4, 4-ClC6H4, 4-MeOC6H4, 4-pyridyl, and 3-pyridyl). Hydrogenation of III on Pt in EtOH gave the corresponding 7-alkylamino-1,3,5-triazaadamantanes.

Collection of Czechoslovak Chemical Communications published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, COA of Formula: C7H14N4.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Benevolenskaya, G. V. published the artcileCatalytic activity of azaadamantanes in the Claus reaction in the further purification of exhaust gases of a sulfur production apparatus, Category: catalysis-chemistry, the publication is Podgotovka i Pererabotka Gaza i Gazovogo Kondensata (1978), 13-17, database is CAplus.

The catalytic activity was studied of azaadamantanes in the manufacture of elementary S from SO₂-containing waste gases by the Claus process at 125-30¡ã. The highest conversion rates were attained with 7-amino-1,3,5-triazaadamantane (I), I benzoate, and I stearate in a polyethylene glycol PEG-400 medium. The conversion was practically complete when the catalyst concentration was ¡Ý1%. Little of the catalyst was consumed since they were inert to SO₂ and suitable at any H₂S/SO₂ ratio.

Podgotovka i Pererabotka Gaza i Gazovogo Kondensata published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Benevolenskaya, G. V. published the artcileCatalytic effect of azaadamantanes on the Claus reaction in additional cleaning of waste gases from sulfur production units, Recommanded Product: 1,3,5-Triazaadamantan-7-amine, the publication is Nauchno-Tekhnicheskii Obzor, Seriya: Podgotovka i Pererabotka Gaza i Gazovogo Kondensata (1978), 13-17, database is CAplus.

In order to apply azaadamantane derivatives in an adsorption-catalytic process for addnl. cleaning of waste gases from S production plants, their catalytic properties were investigated. In a reactor formed by a porous filter of diameter 18 mm containing 10³ cm of catalyst solution, a gas mixture consisting of 3% of H₂S and SO₂ in N was introduced with volume rate 31/h at 130¡ã. As an index of catalytic activity, the degree of H₂S transformation was used. The dependence of this index on the flow rate and time were measured. The high catalytic activity of 7-amino-1,3,5-triazaadamantane [14707-75-6] with low volume rate, due to its excellent phys. properties and no interaction with SO₂, makes it possible to use this substance as a material in the process of addnl. cleaning of waste gases from S production plants.

Nauchno-Tekhnicheskii Obzor, Seriya: Podgotovka i Pererabotka Gaza i Gazovogo Kondensata published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Recommanded Product: 1,3,5-Triazaadamantan-7-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Trska, Petr published the artcileCarbon-13 chemical shifts of aza- and triazaadamantane derivatives, Name: 1,3,5-Triazaadamantan-7-amine, the publication is Organic Magnetic Resonance (1984), 22(5), 352-5, database is CAplus.

¹³C NMR chem. shifts for 1-azaadamantane, twelve N-substituted 1-azaadamantanes, 1,3,5-triazaadamantane (I) and for nine derivatives of I were recorded.

Organic Magnetic Resonance published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H6Cl2O, Name: 1,3,5-Triazaadamantan-7-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Trska, Petr published the artcileSubstituent effects on the carbon-13 NMR chemical shifts of aza- and triazaadamantanes, Application of 1,3,5-Triazaadamantan-7-amine, the publication is Sbornik Vysoke Skoly Chemicko-Technologicke v Praze, H: Analyticka Chemie (1984), 29-40, database is CAplus.

¹³C NMR chem. shifts were studied for 13 N-substituted 1-aza- and 11 1,3,5-triazaadamantane derivatives The effects of substitution at the N for the former and at C-7 for the latter compounds were examined The ¦Á-C atoms in azaadamantanes were influenced in the same manner as the ¦Â-carbons in 1-substituted adamantanes. Similar results were obtained for 7-substituted triazaadamantanes. The substituent-chem.-shift (SCS) contributions for the 1-azaadamantane derivatives did not correlate simply with the electron densities obtained by the EHT method. Factor anal. was applied to 9 1-azaadamantanes, and the charges at the ¦Á, ¦Â and ¦Ã C atoms were established to be the decisive factors. Based on these data, the chem. shifts for a compound in this series were calculated with reasonable accuracy using the SCS matrix of the remaining 8 compounds

Sbornik Vysoke Skoly Chemicko-Technologicke v Praze, H: Analyticka Chemie published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C5H11NO2S, Application of 1,3,5-Triazaadamantan-7-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Vichkanova, S. A. published the artcileAntiviral activity of some 1,3,5-triazaadamantane derivatives, Computed Properties of 14707-75-6, the publication is Farmakologiya i Toksikologiya (Moscow) (1974), 37(1), 76-80, database is CAplus.

All 11 derivatives of 1,3,5-triazaadamantane (I) [281-31-2] tested inhibited the growth of Newcastle disease virus in vitro, with 7-bromo-1,3,5-triazaadamantane [51706-46-8] and 7-amino-1,3,5-triazaadamantane-HCl [51706-47-9] the most effective. 7-Nitro-1,3,5-triazaadamantane [14612-28-3] exerted antimicrobial activity against influenza A2 virus in vitro and 7-nitro-1,3,5-triazaadamantane-HCl [51706-48-0] inhibited 4 herpes virus strains in chick fibroblast cultures. None of the I derivatives were active against Aujeszky virus.

Farmakologiya i Toksikologiya (Moscow) published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C18H17NO8, Computed Properties of 14707-75-6.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Safar, M. published the artcileNitrogen compounds of adamantane. VII. New preparation of 7-nitro-1,3,5-triazaadamantane and derivatives by hydrogenation and ozonization, Product Details of C7H14N4, the publication is Collection of Czechoslovak Chemical Communications (1975), 40(7), 2179-82, database is CAplus.

Reflux of hexamethylenetetramine, 80% aqueous EtOH, 98-100% HCO2H, and MeNO2 gave 65% I (R = NO2) which was hydrogenated (over PtO2 or Pd/C in EtOH) to I (R = NH2) or (over Pd/C in H2O) to I (R = NHOH). Quaternization of I (R = NO2) with MeI or EtI gave 7-nitro-1,3-diaza-5-alkylazoniaadamantane iodide (alkyl = Me, Et). Reaction of I (R = NO2) with O3 in H2O or 30% H2O2 in AcOH gave the corresponding N-oxide. I (R = NHCH2CN and NHCH2CH2NH2) were also prepared

Collection of Czechoslovak Chemical Communications published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Product Details of C7H14N4.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Safar, M. published the artcileNitrogen compounds of adamantane. VIII. Chromatographic separation of azaadamantanes and their derivatives in a gas liquid system, Synthetic Route of 14707-75-6, the publication is Collection of Czechoslovak Chemical Communications (1975), 40(11), 3334-8, database is CAplus.

Gas chromatog. separation of 1-azaadamantane (I), 1,3-diazaadamantane (II), 1,3,5-triazaadamantane (III), 1,3,5,7-tetraazaadamantane (IV), and their derivatives was investigated. Elution data for I, II, III, IV, 7-substituted-1,3,5-triazaadamantanes (substituents = Cl, Br, NO2, NH2, MeNH, Me2N), adamantane, 1-bromo- and 1-aminoadamantane, and eicosane, rel. elution volumes of 7-amino-1,3,5-triazaadamantane aldimines, and homomorphic factors for I, II, III, and IV were determined A flame ionization detector and N carrier gas at 50 ml/min were used. Stainless steel columns (6 mm ¡Á 1.2 m) packed with 3 types of fillings were used: type A:12.3 g Chromaton N-AW-DMCS (particle size 0.16-0.20 mm) containing 5% (weight) SE-30 at 125 and 220¡ã, type B: 10.9 g Chromaton N-AW-HMDS (particle size 0.16-0.20 mm) with 10% (weight) OS-124 (Lachema, Brno) at 190¡ã; and type C: 9.7 g Chromaton N (particle size 0.20-0.25 mm) with 5% (weight) polyethylene glycol (mol. weight 1500) and 1% KOH at 160¡ã. Chromatog. behavior of the substances with respect to their structure and interaction with the stationary phase is discussed.

Collection of Czechoslovak Chemical Communications published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Synthetic Route of 14707-75-6.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Kafka, Zdenek published the artcileNitrogen compounds of adamantane. Part XII. Study of reactivity of some 1,3,5-triazaadamantane derivatives, COA of Formula: C7H14N4, the publication is Collection of Czechoslovak Chemical Communications (1978), 43(1), 151-5, database is CAplus.

The reactivities of 7-nitro-1,3,5-triazaadamantane (I) and 7-amino-1,3,5-triazaadamantane (II), prepared by hydrogenation of I.HCl or I.HBr over PtO₂, were studied. Boiling II with HC(OEt)₃ in AcOH or with aqueous HCO₂H gave as the main product 7-(dimethylamino)-1,3,5-triazaadamantane, whereas analogous treatment of I yielded 3-methyl-5-nitro-1,3,7-triazabicyclo[3.3.1]nonane (III). Hydrogenation of III gave 3-methyl-5-amino-1,3,7-triazabicyclo[3.3.1]nonane.

Collection of Czechoslovak Chemical Communications published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, COA of Formula: C7H14N4.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Kafka, Zdenek published the artcileNitrogeneous compounds of adamantane. XI. Paper chromatography and thin-layer chromatography of some derivatives of 1,3,5-triazaadamantane, Application In Synthesis of 14707-75-6, the publication is Sbornik Vysoke Skoly Chemicko-Technologicke v Praze, D: Technologie Paliv (1977), 119-26, database is CAplus.

1,3,5-Triazaadamantane (I), nitro and amino derivatives of I, and their quaternary salts were separated by paper chramatog. (Whatman number 1, 20¡ã, descending) and thin-layer chromatog. on silica gel and Al2O3 (ascending). RF values are given for I, 7-nitro-1,3,5-triazabicyclononane (II), II N-oxide, 3,7-diacetyl-5-nitro-1,3,7-triazaadamantane (III), III N-oxide, 7-amino-1,3,5-triazaadamantane (IV), IV nicotinate, IV isonicotinate, IV adipate, IV glutarate, 7-nitro-1,3-diaza-5-methylazoniaadamantane iodide, 7-nitro-1,3-diaza-5-ethylazoniaadamantane iodide, 7-amino-1,3-diaza-5-methylazoniaadamantane iodide, 7-amino-1,3-diaza-5-ethylazoniaadamantane iodide, and N,N’-bis(1,3,5-triaza-7-adamantyl) urea for 13 binary and ternary solvent systems used in paper chromatog. The quaternary salts and bicyclononane derivatives were separated with HCl or AcOH containing systems.

Sbornik Vysoke Skoly Chemicko-Technologicke v Praze, D: Technologie Paliv published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C7H14N4, Application In Synthesis of 14707-75-6.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia