Category: 1949-41-3

Martinetto, Yohan’s team published research in Molecules in 26 | CAS: 1949-41-3

Molecules published new progress about 1949-41-3. 1949-41-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene, name is 2-Methyl-4-phenylbutanoic acid, and the molecular formula is C11H14O2, HPLC of Formula: 1949-41-3.

Martinetto, Yohan published the artcileSynthesis, physical properties and application of a series of new polyoxometalate-based ionic liquids, HPLC of Formula: 1949-41-3, the publication is Molecules (2021), 26(2), 496, database is CAplus and MEDLINE.

This paper deals with the preparation and the characterization of four new ionic liquids resulting from the pairing of various polyoxotungstates or polyoxomolybdates with the cation trihexyltetradecylphosphonium. The phys. properties measured by different techniques evidence that the viscosity and the rheol. behaviors of such POM-based ionic liquids, POM-ILs, strongly depend on the nature of the POM, especially its charge. Playing on the nature of the POM, we can indeed obtain Newtonian liquids or some much more viscous materials exhibiting characteristics of resins or pseudo-plastics. In a second part of this study, the potentialities of using such materials both as solvent and catalyst for the oxidation of a series of alcs. are presented as proof of concept. This part highlights great differences in strength and selectivity as a function of the POM-IL used. Furthermore, a very simple way to recycle the catalyst is also presented.

Molecules published new progress about 1949-41-3. 1949-41-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene, name is 2-Methyl-4-phenylbutanoic acid, and the molecular formula is C11H14O2, HPLC of Formula: 1949-41-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Kuo, Ying Che’s team published research in Chemical & Pharmaceutical Bulletin in 30 | CAS: 1949-41-3

Chemical & Pharmaceutical Bulletin published new progress about 1949-41-3. 1949-41-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene, name is 2-Methyl-4-phenylbutanoic acid, and the molecular formula is C11H14O2, Application In Synthesis of 1949-41-3.

Kuo, Ying Che published the artcileNew methods and reagents in organic synthesis. 26. Reductive desulfonylation of α-sulfonylacetates, Application In Synthesis of 1949-41-3, the publication is Chemical & Pharmaceutical Bulletin (1982), 30(8), 2787-92, database is CAplus.

α-Acyl-α-benzylsulfonyldiazomethanes RCOC(:N2)SO2CH2Ph (R = Ph, PhCH2CH2, Me2CH, cyclohexyl) have been converted to RCH(CO2H)SO2CH2Ph (I, same R) by Wolff rearrangement. Reductive removal of the benzylsulfonyl group of I (R = PhCH2CH2, Me2CH, cyclohexyl) can be achieved by Na-EtOH in THF. HO2CCRMeSO2CH2Ph (same R), prepared from benzyl α-benzylsulfonyl-α-substituted acetates, were also benzylsulfonylated under similar reductive conditions. The overall process, in combination with the Arndt-Eistert synthesis of α-sulfonylacetates from acyl chlorides and benzylsulfonyldiazomethane, provides a new, safe method for the homologation of carboxylic acids.

Chemical & Pharmaceutical Bulletin published new progress about 1949-41-3. 1949-41-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene, name is 2-Methyl-4-phenylbutanoic acid, and the molecular formula is C11H14O2, Application In Synthesis of 1949-41-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia