Category: 30670-30-5

Yi, Xin published the artcileLigands binding and molecular simulation: the potential investigation of a biosensor based on an insect odorant binding protein, Application In Synthesis of 30670-30-5, the publication is International Journal of Biological Sciences (2015), 11(1), 75-87, 13 pp., database is CAplus and MEDLINE.

Based on mimicking biol. olfaction, biosensors have been applied for the detection of various ligands in complex environment, which could represent one of the most promising research fields. In this study, the basic characters of one insect odorant binding protein (OBP) as a biosensor were explored. To explore the mol. recognition process, the tertiary structure of the protein was modeled and the protein-ligand interactions with 1,536,550 chems. were investigated by the mol. docking. The availability of large amount of recombinant SlitOBP1 overcame the difficulty to obtain biol. sensing material. After obtained the purified recombinant protein, the result of fluorescence binding assays proved the candidate protein has good affinities with the majority of the tested chems. With the aid of simulation docking, the key conserved amino acids within the binding site were identified and then mutated to alanine. After mutation, the protein-ligand binding characteristics were recorded, and the competitive binding assays were carried out to provide exptl. verification. The detailed information on its structure and affinities investigated in this study could allow the design of specific mutants with desired characteristics, which provides a solid base for tailoring OBP for biosensor and provides a role model for screening the other elements in olfactory system for different applications.

International Journal of Biological Sciences published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C15H10O2, Application In Synthesis of 30670-30-5.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Fu, Zheng-Jun published the artcileDual-layer membrane with hierarchical hydrophobicity and transport channels for nonpolar organic solvent nanofiltration, Product Details of C10H6F17N, the publication is AIChE Journal (2021), 67(4), e17138, database is CAplus.

Nonpolar solvent separation is widely used in petroleum, chem., food industries, but traditional separation methods consume intensive energy. State-of-art organic solvent nanofiltration membranes require complex modifications for nonpolar solvent transport. For the first time, we propose the concurrent modification of the surface, interface and support layer of dual-layer membranes with three additives (perfluorodecylamine, fluoro substituted aromatic amine, silica nanoparticles) in a one-step cocasting process. A delamination-free dual-layer membrane was obtained with a hierarchical hydrophobicity and transport channels. The novel designed structure elevated the pure n-hexane permeance (28.75 L m^-2 hr^-1 bar^-1) by 3 orders of magnitude with a high lecithin rejection (98.7%). This method of synergistically controlling the hierarchical structures and properties of dual-layer membranes can significantly shorten the preparation process of high-performance nonpolar solvent nanofiltration membranes.

AIChE Journal published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Product Details of C10H6F17N.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Jouani, Mohamed Azzedine published the artcileSynthesis of F-alkylated 5,6-dihydro-2-uracils, SDS of cas: 30670-30-5, the publication is Bulletin de la Societe Chimique de France (1996), 133(9), 839-842, database is CAplus.

A two-step synthesis of 3-fluoroalkylated dihydrouracils consists of reacting a 3-aminopropanoic acid derivative with 2-(fluoroalkyl)ethyl isocyanates and treating the resulting product with catalytic amounts of hydrochloric acid. The treatment of 3-[2-(fluoroalkyl)ethylamino]propanoic acid derivatives with benzoyl isocyanate followed by acid-catalyzed cyclization gives 1-fluoroalkylated dihydrouracils.

Bulletin de la Societe Chimique de France published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, SDS of cas: 30670-30-5.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Nasreddine, M. published the artcileNew and effective route to N-(2-F-alkyl ethyl) ¦Á-amino acids, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Synthetic Communications (1992), 22(11), 1547-54, database is CAplus.

A new and effective procedure is described for the synthesis of the title ¦Á-amino acids F₃C(CF₂)_nCH₂CH₂NHCHRCO₂H (I; n = 5, 7, R = H, Me, Et, Pr, Bu) which involves a solid-liquid phase transfer catalysis method. Thus, substitution of bromoalkanoates BrCHRCO₂Et with amines F₃C(CF₂)_nCH₂CH₂NH₂ in MeCN in the presence of K₂CO₃ and PhCH₂N⁺Et₃ Cl^– gave 76-96% of the corresponding amino esters, which were saponified to give 71-97% I.

Synthetic Communications published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Roman, L. published the artcileAn effective route to N,N-bis(2,3-epoxypropyl) 2-F-alkylethylamines, Quality Control of 30670-30-5, the publication is Synthetic Communications (1997), 27(18), 3125-3132, database is CAplus.

An effective procedure is described for the synthesis of N,N-Bis(epoxypropyl) 2-F-alkylethylamines I (R_F = C₄F₉, C₆F₁₃, C₈F₁₇) avoiding the formation of 2-F-alkylethylethenes usually occurring in the N-alkylation of 2-F-alkylethyl iodides by amines.

Synthetic Communications published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Quality Control of 30670-30-5.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Bollens, E. published the artcileSynthesis of long chain, perfluoroalkylethyl isothiocyanates, Name: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Journal of Fluorine Chemistry (1991), 53(1), 1-14, database is CAplus.

CF₃(CF₂)_nCH₂CH₂NCS (I, n = 3, 5, 7) were prepared in 69-73% yield by treating CF₃(CF₂)_nCH₂CH₂N₃ with CS₂ in the presence of PPh₃. I were also obtained in 65-76% yield by treating CF₃(CF₂)_nCH₂CH₂NH₂ with CS₂ in the presence of NaOH and ClCO₂Me or NaOCl.

Journal of Fluorine Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Name: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Trabelsi, H. published the artcileSynthesis of 2-F-alkylethylamines: optimization of the production of 2-F-alkylethyl azides and their reduction to the corresponding amines, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Journal of Fluorine Chemistry (1994), 69(1), 115-17, database is CAplus.

2-(Perfluoroalkyl)ethylamines are very important intermediates in organic fluorine chem. It is possible to combine the advantages of two techniques, i.e., phase-transfer catalysis and the use of water as a dispersing medium, in the reduction of 2-(perfluoroalkyl)ethyl azides, and hence simplify significantly the synthesis of such amines from 2-(perfluoroalkyl)ethyl iodides. Thus, CF₃(CF₂)_nCH₂CH₂R (I; R = iodo, n = 3, 5, 7) were converted to I (R = N₃) by a phase-transferred catalyzed reaction with NaN₃. Subsequent reduction of I (R = N₃) with N₂H₄/Raney Ni gave 70-80% I (R = NH₂).

Journal of Fluorine Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C5H10O2S, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Kalow, Julia A. published the artcileSynthesis of Miktoarm Branched Conjugated Copolymers by ROMPing In and Out, Formula: C10H6F17N, the publication is ACS Macro Letters (2015), 4(11), 1229-1233, database is CAplus and MEDLINE.

Architecture represents a promising yet underutilized control element in polymer design due to the challenging synthesis of compositionally varied branched copolymers. We report the one-pot synthesis of miktoarm branched polymers by ring-opening metathesis polymerization In this work, we graft to and from telechelic poly(3-hexylthiophene), which is end-capped by oxime click chem., using various norbornene monomers. The self-assembly of the resulting miktoarm H-shaped conjugated polymers is studied in solution and in the solid state. A dual stimuli-responsive miktoarm polymer is prepared that displays pH-switchable lower critical solution temperature and fluorescence.

ACS Macro Letters published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Formula: C10H6F17N.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Voggu, Rakesh published the artcileOne-step synthesis of high-purity fluorous-capped inorganic nanoparticles, Safety of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Dalton Transactions (2010), 39(26), 6021-6023, database is CAplus and MEDLINE.

Making use of the fact that perfluorohydrocarbon, and hydrocarbon solvents become miscible at high temperatures, highly pure inorganic nanoparticles capped with fluorous labels were generated in a 1-step synthesis. The procedure involves taking the reactants in a hydrocarbon + perfluorohydrocarbon mixture along with a fluorous reagent and carrying out the reaction at elevated temperatures On cooling the reaction mixture, fluorous-capped inorganic nanoparticles dispersed in the perfluorohydrocarbon were obtained.

Dalton Transactions published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C6H5BClNO4, Safety of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Schaetti, J. published the artcileTailoring the volatility and stability of oligopeptides, Related Products of catalysis-chemistry, the publication is Journal of Mass Spectrometry (2017), 52(8), 550-556, database is CAplus and MEDLINE.

Amino acids are essential building blocks of life, and fluorinated derivatives have gained interest in chem. and medicine. Modern mass spectrometry has enabled the study of oligo- and polypeptides as isolated entities in the gas phase, but predominantly as singly or even multiply charged species. While laser desorption of neutral peptides into adiabatically expanding supersonic noble gas jets is possible, UV-VIS spectroscopy, elec. or magnetic deflectometry as well as quantum interferometry would profit from the possibility to prepare thermally slow mol. beams. This has typically been precluded by the fragility of the peptide bond and the fact that a peptide would rather ‘fry’, i.e. denature and fragment than ‘fly’. Here, we explore how tailored perfluoroalkyl functionalization can reduce the intermol. binding and thus increase the volatility of peptides and compare it to previously explored methylation, acylation and amidation of peptides. We show that this strategy is essential and enables the formation of thermal beams of intact neutral tripeptides, whereas only fragments were observed for an extensively fluoroalkyl-decorated nonapeptide.

Journal of Mass Spectrometry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia