Category: 30670-30-5

Platen, Tobias published the artcileSynthesis and Antibody Binding of Highly Fluorinated Amphiphilic MUC1 Glycopeptide Antigens, Recommanded Product: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is European Journal of Organic Chemistry (2011), 2011(20-21), 3878-3887, S3878/1-S3878/24, database is CAplus.

The anal. of humoral immune responses is of great importance for basic and clin. research. Mapping the structural requirements of epitope recognition with modified tumor-associated carbohydrate antigens allows both the development of biomarkers and the design of synthetic anticancer vaccines. For this purpose, double-tailed hydrocarbon/fluorocarbon membrane anchors have been prepared and conjugated to a T_N dipeptide. Furthermore, a novel hydrophobic MUC1 tandem repeat glycopeptide antigen was fully assembled on a solid support and its specific binding to different mouse anti-MUC1 antibodies was demonstrated through ELISA, QCM, and SPR measurements. Such functional fluorous MUC1 antigens are of great interest for specific glycan (micro-)array formats and allow a detailed analyses of serum antibodies obtained from immunization studies. In addition, the intriguing characteristics of fluorous surfactants, for example, their strong self-association tendency, might stimulate the use of novel fluorous-tagged antigen conjugates in the development of multivalent micellar glycopeptide vaccines.

European Journal of Organic Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Recommanded Product: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Svoboda, Jiri published the artcileThiourea-enhanced flavin photooxidation of benzyl alcohol, Safety of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Chemistry – A European Journal (2008), 14(6), 1854-1865, database is CAplus and MEDLINE.

Upon irradiation, flavin oxidizes 4-methoxybenzyl alc. to the corresponding aldehyde using aerial O₂ as the terminal oxidant. We have observed that this reaction is significantly accelerated by the presence of thiourea. A series of thiourea-functionalized flavins has been prepared from flavin isothiocyanates and their photocatalytic efficiencies have been monitored by NMR. The alc. photooxidation proceeds rapidly and cleanly with high turnover numbers of up to 580, exceeding previously reported performances. A likely mechanistic rationale for the more than 30-fold acceleration of the photo-redox reaction by thiourea has been derived from spectroscopic, electrochem., and kinetic studies. Thus, thiourea acts as an electron-transfer mediator for the initial photooxidation of 4-methoxybenzyl alc. by the excited flavins. This mechanism has similarities to electron-relay mechanisms in flavoenzymes, for which cysteine sulfenic acid intermediates are proposed. The observation that thiourea mediates flavin photo-redox processes is valuable for the design of more sophisticated photocatalysts based on Nature’s best redox chromophore.

Chemistry – A European Journal published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H10O6, Safety of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Firestone, Raymond A. published the artcileSelective delivery of cytotoxic compounds to cells by the LDL pathway, HPLC of Formula: 30670-30-5, the publication is Journal of Medicinal Chemistry (1984), 27(8), 1037-43, database is CAplus and MEDLINE.

Cytotoxic compounds were prepared for reconstitution with LDL (low-d. lipoproteins) to be delivered to cancer cells that internalize LDL, and evaluated by measuring the toxicity of reconstituted LDL toward test cells, SV-589 (SV-40 transformed human fibroblasts) bearing LDL receptors. Selectivity was determined by comparison, either with mutant cells with few LDL receptors, or with reconstituted methylated LDL (not recognized by LDL receptors) or normal cells. N-[[[4-(3¦Â–(Oleoyloxy)androst-5-en-17¦Â-yl]pentyl]oxy]carbonyl]-N,N-bis(2-chloroethyl)amine (I) [90343-98-9] reconstituted well and was delivered exclusively via the LDL pathway in amounts capable of killing 100% cells.

Journal of Medicinal Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, HPLC of Formula: 30670-30-5.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Firestone, Raymond A. published the artcileLysosomotropic agents. 4. Carbobenzoxyglycylphenylalanyl, a new protease-sensitive masking group for introduction into cells, Safety of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Journal of Medicinal Chemistry (1982), 25(5), 539-44, database is CAplus and MEDLINE.

Bioactive primary and secondary amines, when acylated with the Z-Gly-Phe group, were transported into pinocytic cells, such as macrophages, P-815 mastocytoma, SV-40 3T3, and leukemia 1210, much faster than the parent compounds Amines, such as lysomotropic detergents (which are cytotoxic compounds, designed as anticancer agents, acting by selectively rupturing the membranes of liposomes) and nitrogen mustard, which are deactivated by acylation, are unmasked by enzymic action intracellularly, probably in lysosomes because an acidic pH maximum in activity exists which acts only on the L isomer. The added polarity and mol. weight brought about by acylation prevents the amines’ normally facile entry into cells by simple diffusion, restricting it to an active-transport mechanism.

Journal of Medicinal Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Safety of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Szonyi, F. published the artcileNew methods of preparation of 2-(perfluoroalkyl)ethylamines, Related Products of catalysis-chemistry, the publication is Journal of Fluorine Chemistry (1991), 55(1), 85-92, database is CAplus.

(Perfluoroalkyl)ethyl azides R_fCH₂CH₂N₃ (R_f = perfluoroethyl, -butyl, –n-hexyl, or –n-octyl) were reduced to the corresponding amines by 4 methods, i.e., Ph₃P/NH₄OH, N₂H₄.H₂O/Raney Ni, NaBH₄ under phase-transfer conditions, or Zn/AcOH.

Journal of Fluorine Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C11H15NO2, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Porcherie, Olivier published the artcileDirect syntheses using a fluorinated surfactant of silicas containing organofluorinated groups, Formula: C10H6F17N, the publication is New Journal of Chemistry (2005), 29(4), 538-543, database is CAplus.

Direct syntheses of silicas containing organofluorinated groups have been achieved by co-condensation of tetraethylorthosilicate (TEOS) and a organofluorinated triethoxysilane, R_F(CH₂)₂Si(OEt)₃ [R_F = CF₃(CF₂)₅ or CF₃], in the presence of either the neutral fluorinated surfactant n-CF₃(CF₂)₇(CH₂)₂NH₂ or the cationic one, n-CF₃(CF₂)₇(CH₂)₂NMe₃⁺I^–. Microporous silica with a wormhole structure containing the C₈ fluorinated chain was obtained in the presence of the nonionic surfactant. It was shown that the use of fluorinated surfactants allows the incorporation of an amount of (fluorinated) chains located in the channel pores that is superior to that obtained by using a hydrogenated surfactant. The cationic surfactant used under acidic conditions allowed the incorporation of only a low amount of the C₈ fluorinated chain, leading to a poorly structured material. In contrast, a mesoporous silica containing the CF₃(CH₂)₂ group and showing a hexagonal arrangement was obtained under the same exptl. conditions.

New Journal of Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Formula: C10H6F17N.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Cosgun, Sedat published the artcileEfficient synthesis of new perfluorinated or hybrid amphiphilic surfactants, HPLC of Formula: 30670-30-5, the publication is Journal of Fluorine Chemistry (2004), 125(1), 55-61, database is CAplus.

A very simple pathway for the preparation of amphiphilic analogs of natural bioactive peptidoamines such as carnosine (¦Â-alanylhistidine) or carcinine (¦Â-alanylhistamine) is presented. The strategy makes it possible to synthesize original bialkyl chain or trialkyl chain perfluorinated surfactants with or without perhydrogenated chains.

Journal of Fluorine Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, HPLC of Formula: 30670-30-5.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Abrahami, Renata A. published the artcileA de novo synthetic route to 1,2,3,4-tetrahydroisoquinoline derivatives, Recommanded Product: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Synlett (2018), 29(15), 2066-2070, database is CAplus.

A novel synthetic approach was developed for the construction of the 1,2,3,4-tetrahydroisoquinoline framework, e.g. I (R¹ = Et, CHF₂CH₂, CF₃CH₂, CF₃CHMe, PhCH₂, etc.; R² = H, Br), possessing varied functions. The synthetic strategy is based on oxidative ring opening of the corresponding indandiols, e.g. II, followed by double reductive amination of the dicarbonyl intermediates with various primary alkyl- or fluoroalkylamines R¹NH₂.

Synlett published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Recommanded Product: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Ramos Chagas, Gabriela published the artcileSuperhydrophobic and fluorescent properties of fluorinated polypyrene surfaces using various polar linkers prepared via electropolymerization, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Reactive & Functional Polymers (2019), 65-76, database is CAplus.

Superhydrophobic and fluorescent polypyrene surfaces were synthesized by an electropolymerization process. Six different linkers (ester, thioester, amide, carbamate, thiocarbamate and urea) are used to introduce fluorinated chains (lengths of 4, 6 and 8 carbons) onto pyrene moiety. The electropolymerized surfaces were analyzed by their morphol., surface chem., wettability and fluorescence. The linkers and the length of the fluorinated chain influence on both surface chem. and morphol. confirmed by XPS and SEM anal., resp. Superhydrophobic surfaces were obtained for ester, thioester, carbamate and thiocarbamate series while high hydrophobic surfaces for amide and urea series. Here, we show the possibility to control the surface hydrophobicity, oleophobicity and liquid adhesion with both the linker and the fluorinated chain length. For example, N-H groups seem to induce a decrease in the static contact angle (¦È_w) and in the surface structuration due to their polarity generating smoother surfaces (as for amide and urea series) and yielding to a red-shift in the emission spectra (showed for amide, carbamate, thiocarbamate and urea). The emission of all the polypyrene films is red-shifted compared to the pyrene monomers (excimer emission) and in the green region independently of the side chain. Here, we show that the nature of the heteroatom that connects the pyrene moiety to the fluorinated chain also does great impact on the surface morphol., wetting and fluorescence properties.

Reactive & Functional Polymers published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Tristany, Mar published the artcileSelf-assembled platinum nanoparticles into heavily fluorinated templates: Reactive gas effect on the morphology, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is New Journal of Chemistry (2009), 33(7), 1529-1534, database is CAplus.

The synthesis of platinum(0) nanoparticles by decomposition of Pt₂(dba)₃ under a dihydrogen or CO atm. and in the presence of heavily fluorinated stabilizers is described. Several techniques were used for the characterization of the obtained nanomaterials (TEM, HREM, WAXS and SEM-FEG) that organize into spherical or elongated superstructures made of small individual nanoparticles (?2.5 nm).

New Journal of Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C16H12O, Application of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia