Category: 30670-30-5

Sasso, Barbara published the artcileSynthesis of ¦Ø-End Group Functionalized Poly(methyl methacrylate)s via RAFT Polymerization, Product Details of C10H6F17N, the publication is Macromolecules (Washington, DC, United States) (2010), 43(18), 7453-7464, database is CAplus.

“Living” poly(Me methacrylate) (PMMA), prepared by the RAFT technique, reacted with maleic anhydride to give succinic anhydride-terminated PMMA (SA-PMMA) in very high yield. The ¦Ø-terminal anhydride residues react in high yields with primary alcs., primary amines and aromatic amines. As examples, SA-PMMA reacted with 1H,1H,2H,2H-perfluorodecylamine to give a polymer containing 5.78% of fluorine; with Disperse Orange 3 to give a dye-labeled PMMA; with 9-hydroxymethylanthracene to give a fluorescently labeled PMMA; with norephedrine to give a polymer with a biol. active end group; and with 4,4′-diaminophenymethane to give amine-ended PMMA. The latter reacted smoothly with fluorescein isocyanate to give a fluorescently labeled PMMA. In these examples the fraction of polymer chains functionalized were in the range 75-95%. Allowing for the fact the starting PMMAs were up to 96% “living”, these loadings correspond to functionalization yields, for the anhydride addition plus the reaction with the nucleophiles, of 81-99%.

Macromolecules (Washington, DC, United States) published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Product Details of C10H6F17N.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Petkevich, S. K. published the artcileSynthesis of Fluorine-Containing Derivatives of 5-Arylisoxazoles and 4,5-Dichlorothiazole, Related Products of catalysis-chemistry, the publication is Russian Journal of General Chemistry (2018), 88(2), 234-240, database is CAplus.

Alkylation of fluorophenols and phenolic aldehydes with 5-phenyl(p-tolyl)-3-chloromethylisoxazole under the Williamson reaction conditions afforded the corresponding ethers. Condensation of the resulting phenolic aldehyde derivatives and 5-phenyl(p-tolyl)isoxazole-3-carbaldehydes with p-fluoroaniline resulted in fluorine-containing azomethines. Acylation of fluorinated amines with 5-(p-tolyl)isoxazole- and 4,5- dichloroisothiazole-3-carbonyl chlorides gave rise to fluorinated amides bearing isoxazole and isothiazole fragments, representatives of which showed a synergistic effect in compositions with insecticides.

Russian Journal of General Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

De Bruycker, Kevin published the artcileCovalent Fluorination Strategies for the Surface Modification of Polydienes, Synthetic Route of 30670-30-5, the publication is Macromolecular Rapid Communications (2017), 38(11), n/a, database is CAplus and MEDLINE.

Nonreactive additives are widely applied to enhance polymer properties but can leach out of the material over time. In this work, two essentially different fluorinated additives bearing a triazolinedione moiety are synthesized and grafted on several polydiene backbones (acrylonitrile-butadiene-styrene, styrene-butadiene, and styrene-isoprene-styrene (SIS) copolymers), either by dip-coating or by reaction in solution The resulting polymers are analyzed by contact angle goniometry, size exclusion chromatog., and NMR, IR, and XPS. Independent of the modification procedure, the fluorophilic perfluoroalkyl additive is found at the material surface, thereby yielding a more hydrophobic surface. For SIS thermoplastic elastomers, for example, contact angles up to 125¡ã can be obtained.

Macromolecular Rapid Communications published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Synthetic Route of 30670-30-5.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Guittard, Frederic published the artcileSynthesis and behavior at the air-water interface of fluorinated nonionic surfactants containing two methylated polyoxyethylene moieties, Related Products of catalysis-chemistry, the publication is Journal of Colloid and Interface Science (1996), 177(1), 101-05, database is CAplus and MEDLINE.

The nonionic surfactants of the type polyoxyethylated, monomethylated, and containing a fluorinated tail were synthesized from 2-(F-alkyl)ethylamines. These compounds have two polyethoxylated tails with a perfectly defined number of oxyethylene motifs. Compared with their bipodal homologs within the F-alkylated series, these new structures were easily obtained from com. raw materials which are the 2-(F-alkyl)ethyliodides. The evaluation of their behavior at the air-water interface has been studied from measurements of surface tension vs. variation of concentration This clearly shows the variation of the critical micelle concentration (c.m.c.) from 1.0.10^-5 to 2.5.10^-3 mol.liter^-1 and of the surface area per surfactant mol. vs. studied structure. The N,N-dipolyethoxylene methoxyether of 2-(F-alkyl)ethylamines so realized exhibit noteworthy properties as nonionic fluorinated surfactants.

Journal of Colloid and Interface Science published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Xiao, Ke published the artcileSimultaneous achievement of refractory pollutant removal and energy production in saline wastewater treatment, Safety of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Chemical Engineering Journal (Amsterdam, Netherlands) (2019), 845-853, database is CAplus.

A novel solar-wastewater-energy recovery system was presented to simultaneously remove refractory organic pollutants from saline wastewater and produce energy. To accomplish this goal, a two-chamber cell was fabricated. The anode chamber integrating photo-oxidation and flocculation was developed by using a TiO₂ nanotube array (TNA) and Al foil. A dopamine modified carbon felt (DPA/CF) electrode was located in the cathode chamber to produce H₂O₂ by the two-electron reduction of O₂ with electrons generated on the anodes. Under sunlight irradiation, the TNA photoanode initiated the degradation of perfluorodecylamine (PFDA) as typical refractory pollutant and selectively transformed its organic nitrogen to N₂ and NO₃^– with yields of 87% and 12%, resp. Compared with PFDA removal efficiency using single flocculation, the efficiency was improved by more than 5 times (ca. 96.6%) in the combined process of photo-oxidation and flocculation. H₂O₂ production was also achieved using the DPA/CF cathode, obtaining a high concentration of 5.0 mM. Furthermore, this study revealed that the reversible reaction between dehydrogenation and hydrogenation on polydopamine accomplished the catalytic reduction of O₂ to H₂O₂. The present study proposes a new approach involving energy recovery in saline wastewater treatment for an energy-sustainable society.

Chemical Engineering Journal (Amsterdam, Netherlands) published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C12H25Br, Safety of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Valles-Miret, Mariona published the artcileA generic small-molecule microarray immobilization strategy, Recommanded Product: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, the publication is Tetrahedron Letters (2011), 52(50), 6819-6822, database is CAplus.

Small-mol. microarrays are often limited by the requirement for each compound undergoing immobilization to contain a common functional group or by the need to prepare glass slides containing photo-reactive groups. Herein, the authors present a generic strategy that allows any compound library to be immobilized. This was achieved by printing a fluorous-tagged photo-reactive 3-aryl-3-trifluoromethyldiazirine, which undergoes nonselective insertion into compounds following UV-activation, onto fluorous-functionalized glass slides. The arrays could be reused following aqueous stripping and re-assessment of the compounds with the same protein or another target of interest.

Tetrahedron Letters published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C11H10O, Recommanded Product: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Godeau, Guilhem published the artcileOne-pot Staudinger Ureation reaction to develop superhydrophobic/oleophobic surfaces with urea linkers, SDS of cas: 30670-30-5, the publication is Materials & Design (2017), 116-122, database is CAplus.

In this work, we report for the first time the use of the one-pot Staudinger ureation to link an azido monomer to a perfluorinated amine by taking advantage of a variation of the Staudinger reaction using CO₂ as an electrophile to form an isocyanate in-situ. The formed isocyanate directly reacts with various perfluorinated amines to form the corresponding urea. This chem. pathway is successfully used to prepare new perfluorinated monomers. The monomers were then electrodeposited to form structured surfaces with different wetting properties. Various properties were obtained such as: parahydrophobicity, super hydrophobicity, oleophilicity and strong oleophobicity. This study shows the important influence of the perfluorinated chain on both polymerization and surface properties. This work also illustrates the efficiency of the one-pot Staudinger ureation for new urea monomer elaboration.

Materials & Design published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, SDS of cas: 30670-30-5.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Nivet, J. B. published the artcileSynthesis and bioacceptability of fluorinated surfactants derived from F-alkylated tertiary amines, COA of Formula: C10H6F17N, the publication is European Journal of Medicinal Chemistry (1992), 27(9), 891-8, database is CAplus.

Two methods for synthesizing tertiary F-alkylated amines are reported. The more general method allows the access in 56-87% yields to various N,N-dialkyl F-alkyl amines. These amines are key intermediates leading in 52-96% yields to several families of surfactants, including zwitterionic and cationic derivatives and amine oxides, potentially useful in the formulation of fluorocarbon emulsions for diagnostic and therapeutic uses. The toxicity of the new surfactants and the influence of the polar head were assessed: the long chain compounds C₈F₁₇(CH₂)₃N⁺Me₂(CH₂)_mCO₂^– (8; m = 3, 4, 5); C₈F₁₇(CH₂)₃N⁺R₃ X^– (9; R = Me, X = Cl; R = Et, X = Br) and C₈F₁₇(CH₂)₃NMe₂O were found to be toxic for cell cultures and the zwitterionic compounds, e.g., 8, have a LD₅₀ <250 mg·kg bw^-1 in mice. The hemolysis test highlights the influence of the polar head: the zwitterionic compounds were found to be non-hemolytic even at remarkably high concentrations (100 g L^-1 for 8), whereas the cationic compounds 9 are highly hemolytic even at very low concentrations (0.05 g L^-1).

European Journal of Medicinal Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, COA of Formula: C10H6F17N.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Enjalbert, Delphine published the artcileSynthesis of new double-chain cationic and amphoteric F-alkylated amphiphiles derived from N-alkyl N-methyl N-[2-(F-alkyl)ethyl]amines, Related Products of catalysis-chemistry, the publication is Tenside, Surfactants, Detergents (1998), 35(4), 248-253, database is CAplus.

N-alkyl N-Me N-[2-(fluoroalkyl)] amines were prepared and quaternized by Et bromoacetate, propane-1,3-sultone, hydrogen peroxide, and α,ω-dibromoalkanes to give the resp. carboxybetaines, sulfobetaines, amine oxides, and bis-ammonium double-chain F-alkylated surfactants.

Tenside, Surfactants, Detergents published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C10H6F17N, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Sismondi, A. published the artcileSynthesis of novel intermediate fluoroalkyl precursors to highly fluorinated cationic surfactants, Category: catalysis-chemistry, the publication is Journal of Fluorine Chemistry (1992), 59(1), 127-32, database is CAplus.

The syntheses of F-alkyl compounds such as R_FC₂H₄ZCOCH₂Br (R_F = C₄F₉, C₆F₁₃, C₈F₁₇; Z = S, O, NH) by the reaction of bromoacetyl bromide with an F-alkyl compound such as R_FC₂H₄ZH are reported. These compounds show high reactivity with nucleophilic substrates, e.g., Et₃N. They are intended for use as precursors of surfactants or as precursors of monomers for the elaboration of artificial vesicles.

Journal of Fluorine Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C13H10O3, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia