Category: 5411-14-3

Thuery, Pierre published the artcileUranyl-Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid, the publication is Crystal Growth & Design (2011), 11(1), 347-355, database is CAplus.

Six novel complexes formed under hydrothermal conditions by uranyl ions with three ligands comprising a rigid phenyl- or cyclohexyl-containing platform, and two to four acetate arms were obtained. trigonal nodes. 1,3,5-Benzenetriacetic acid (H₃BTA) yielded [NMe₄][UO₂(BTA)]¡¤H₂O (1), in which the structure-directing counterion induces a two-dimensional, bilayer-type structure different from that previously reported, with both the tris-chelating ligand and the metal ion as. Two complexes were obtained with 1,2-phenylenedioxydiacetic acid (H₂PDDA), [UO₂(PDDA)(H₂O)] (2) and [H₂DABCO][(UO₂)₂(PDDA)₃]¡¤1.5H₂O (3). Complex 2 is a simple, ribbon-like, 1-dimensional polymer, while 3 is a nanotubular assembly built around the H-bonded, structure-directing counterions. Three complexes were obtained with trans-1,2-diaminocyclohexane-N,N,N’,N’-tetraacetic acid (H₄DCTA), a polyaminopolycarboxylic acid, with different bases, [UO₂(H₂DCTA)(H₂O)₂]¡¤H₂O (4), [UO₂(H₂DCTA)(H₂O)]¡¤1.5H₂O (5), and [UO₂Na(HDCTA)(H₂O)] (6). The N atoms are not coordinated, both of them (4) or only one (5 and 6) being protonated, and the carboxylic/ate groups are monodentate, except for one chelating in 6 and one nonbonding in 4. These differences in bonding result in various assemblies, 1-dimensional in 4 and two-dimensional in 5 and 6. The layers in 5 are strongly corrugated, with the cyclohexyl groups pointing on either side, and their packing displays oval-shaped channels, while the layers in 6 are planar, with the cyclohexyl groups located on one side, and further assembled into dimeric units by the disordered Na ions. These are the 1st crystal structures of actinide ion complexes with both H₂PDDA and H₄DCTA.

Crystal Growth & Design published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H13NO2, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Liu, Leifang published the artcileHydrothermal Synthesis, Crystal Structures and Fluorescent Properties of Two Complexes Based on 1,2-Phenylenedioxydiacetic Acid and Polypyridyl Ligands, Application In Synthesis of 5411-14-3, the publication is Journal of Inorganic and Organometallic Polymers and Materials (2012), 22(6), 1308-1313, database is CAplus.

Hydrothermal reactions of flexible 1,2-phenylenedioxydiacetic acid (H₂pda) with zinc nitrate or cadmium nitrate in the presence of auxiliary 4,4′-bipyridine (bpy) or 1,3-bis(4-pyridyl)propane (bpp) ligands gave rise to two coordination polymers, {[Cd₂(pda)₂(bpy)(H₂O)₂]¡¤4H₂O}_n (1) and [Zn(pda)(bpp)]_n (2). The polymers were characterized by elemental anal., IR, TG, and single-crystal x-ray diffraction methods. Compound 1 shows 1D ribbon structure and compound 2 displays twofold parallel interpenetrated 2D ¡ú 2D architecture. The different conformations of pda anions in these two compounds are mainly induced by different metal coordination configurations in compound 1 and 2. In addition, the photoluminescence emission of 1 and 2 was studied in the solid state at room temperature

Journal of Inorganic and Organometallic Polymers and Materials published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, Application In Synthesis of 5411-14-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Zhu, Bao-Yong published the artcileSynthesis and characterization of four coordination polymers constructed with d¹⁰ metals and mixed flexible ligands under solvothermal conditions, Computed Properties of 5411-14-3, the publication is Inorganica Chimica Acta (2012), 58-65, database is CAplus.

Solvothermal reactions of flexible 1,2-phenylenedioxydiacetic acid (H₂PDA) or hydroquinone-O,O’-diacetic acid (H₂QDA) with zinc nitrate or cadmium nitrate in the presence of auxiliary 1,1′-(1,4-butanediyl)bis(imidazole) (BBI) ligand gave rise to four coordination polymers, namely, {[Zn(PDA)(BBI)]¡¤3H₂O}_n (1), {[Zn(PDA)(BBI)]¡¤DMF}_n (2), {[Cd₂(QDA)(BBI)]¡¤4H₂O}_n (3), [Cd(QDA)(BBI)]_n (4). All the compounds were characterized by elemental anal., IR and single-crystal x-ray diffraction methods. Compound 1 exhibits a puckered (2D) (4, 4) grid net with a Schlafli symbol of 4⁴ 6². Compound 2 has the dinuclear Zn₂(PDA)₂ “loops” which are further connected by BBI ligands into 2D sheet along (0 1 -1) plane with a Schlafli symbol of 2.6⁵. Interestingly, the Zn₂(PDA)₂ “loops” are penetrated by BBI ligands of the other equivalent net. Thus an unusual 2D polyrotaxane-like structure is formed containing rotaxane-like motifs. Compound 3 possesses a three-dimensional (3D) diamond-type network with a Schlafli symbol of 6⁶. Compound 4 has the dinuclear cadmium core as the node and shows a 3D threefold interpenetrating 8-connected unimodal network with a Schlafli symbol of 3⁶4¹⁸5³6. The structural differences of these complexes give some insights into the effect of solvent on the construction of coordination polymers with the same components under solvothermal conditions. In addition, the fluorescent properties of 1–4 were also investigated.

Inorganica Chimica Acta published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C42H63O3P, Computed Properties of 5411-14-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Hou, Huan-Fu published the artcilecatena-Poly[[[diaquacadmium]-¦Ì-2,2′-(1,2-phenylenedioxy)diacetato] monohydrate], COA of Formula: C10H10O6, the publication is Acta Crystallographica, Section E: Structure Reports Online (2011), 67(3), m342, Sm342/1-Sm342/10, database is CAplus and MEDLINE.

In the title coordination complex, {[Cd(C₁₀H₈O₆)(H₂O)₂]¡¤H₂O}_n the Cd^II atom is seven-coordinated in a distorted pentagonal-bipyramidal geometry, the pentagonal plane comprising four O-atom donors from the 2,2′-(1,2-phenylenedioxy)diacetate chelate ligand together with a bridging carboxylate O-atom donor, with the axial sites occupied by two H₂O mols. The resulting helical chains extend along the b axis and are interconnected by extensive O-H¡¤¡¤¡¤O H-bonding interactions, which also involve the H₂O mol. of solvation, giving a three-dimensional structure. Crystallog. data and at. coordinates are given.

Acta Crystallographica, Section E: Structure Reports Online published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, COA of Formula: C10H10O6.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Huang, Y. published the artcileHydrothermal synthesis, structure, and properties of a novel 2D stair-like zinc coordination polymer with benzene-1,2-dioxyacetate, Name: 2,2-(1,2-Phenylenebis(oxy))diacetic acid, the publication is Russian Journal of Coordination Chemistry (2010), 36(6), 452-457, database is CAplus.

The hydrothermal reaction of Zn(CH₃COOH)₂¡¤6H₂O with benzene-1,2-di(oxyacetic acid) (H₂BDOA) and 1,4-bis(imidazol-1-yl)butane (Bimb) yields a novel 2D zinc coordination polymer, [Zn(BDOA)(Bimb)]¡¤3H₂O_n, in which the Bimb ligands link the 1D Zn-BDOA chains into two kinds of 1D ladder-like structure to construct a 2D stair-like structure. It exhibits intense blue photoluminescence upon photoexcitation.

Russian Journal of Coordination Chemistry published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, Name: 2,2-(1,2-Phenylenebis(oxy))diacetic acid.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Wang, Guan published the artcileDecorating an individual living cell with a shell of controllable thickness by cytocompatible surface initiated graft polymerization, Quality Control of 5411-14-3, the publication is Chemical Communications (Cambridge, United Kingdom) (2018), 54(37), 4677-4680, database is CAplus and MEDLINE.

Surface engineering of individual living cells is a promising field for cell-based applications. However, engineering individual cells with controllable thickness by chem. methods has been rarely studied. This article describes the development of a new cytocompatible chem. strategy to decorate individual living cells. The thicknesses of the crosslinked shells could be conveniently controlled by the irradiation time, visible light intensity, or monomer concentration Moreover, the lag phase of the yeast cell division was extended and their stability against lysis was improved, which could also be tuned by controlling the shell thickness.

Chemical Communications (Cambridge, United Kingdom) published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C16H12O, Quality Control of 5411-14-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Sharghi, Hashem published the artcileEfficient synthesis of some novel macrocyclic diamides using fast addition method, Category: catalysis-chemistry, the publication is Synthesis (2006), 999-1004, database is CAplus.

Synthesis of some new macrocyclic diamides based on catechol scaffold (I; X = (CH₂)₃, (CH₂)₆, CH₂CH₂NHCH₂CH₂, naphthalene-1,8-diyl, 3-nitro-1,2-phenylene, 3-methoxycarbonyl-1,2-phenylene, 3-pentyloxycarbonyl-1,2-phenylene, 3-octyloxycarbonyl-1,2-phenylene) and (II; X =3-methoxycarbonyl-1,2-phenylene, 3-pentyloxycarbonyl-1,2-phenylene, 3-octyloxycarbonyl-1,2-phenylene) by cyclization reactions between various diamines, i.e. 1,3-propanediamine, 1,6-hexanediamine, 3-aza-1,5-pentanediamine, 3-nitro-1,2-benzenediamine, Et 3,4-diaminobenzoate, pentyl 3,4-diaminobenzoate, or octyl; 3,4-diaminobenzoate, and 2-[2-(2-chloro-2-oxoethoxy)phenoxy]ethanoyl chloride using fast addition method has been described. The reactions were carried out in short reaction times and the expected macrocycles were obtained in good to high yields.

Synthesis published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C14H22O2, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Alizadeh, N. published the artcileSpectroscopic studies of charge-transfer complexation of iodine with a new benzo-substituted macrocyclic diamide in chloroform, dichloromethane and their 1:1 mixture, Application In Synthesis of 5411-14-3, the publication is Journal of the Iranian Chemical Society (2008), 5(4), 610-616, database is CAplus.

Charge-transfer complexation of iodine with a new benzo-substituted macrocyclic diamide 5,6,7,8,9,10-hexahydro-2H-1,13,4,7,10-benzodioxatriazacyclopentadecine-3,11(4H,12H)-dione (L) with iodine was studied spectrophotometrically in chloroform, dichloromethane and their 1:1 (volume/volume) mixture The observed time dependence of the charge-transfer band and subsequent formation of I₃^– ion are related to the slow formation of the initially formed 1:1 L.I₂ outer complex to an inner electron donor-acceptor (EDA) complex, followed by fast reaction of the inner complex with iodine to form a triiodide ion, as follows:. L + I₂ ¡ú L.I₂ (outer complex), fast. L.I₂ (outer complex) ¡ú (L.I⁺)I^– (inner complex), slow. (L.I⁺)I^– (inner complex) + I₂ ¡ú (L.I⁺)I₃^–, fast. The pseudo-first-order rate constants for the transformation process were evaluated in different solvent systems. The stability constants of the resulting EDAr complexes were also evaluated and the solvent effect on their stability is discussed. The resulting complexes were isolated and characterized by FTIR and ¹H NMR spectroscopy.

Journal of the Iranian Chemical Society published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, Application In Synthesis of 5411-14-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Kawakami, Yukio published the artcileSynthesis and complexation of an optically active aza crown ether, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid, the publication is Bulletin of the Institute for Chemical Research, Kyoto University (1983), 61(2), 117-19, database is CAplus.

Ethanolamine I was condensed with o-phenylenedioxyacetic acid or its p-nitrophenyl ester to give diamide II, which was cyclized with o-(BrCH₂)₂C₆H₄ in the presence of NaH to give aza crown ether III. The cation binding of III with Li, Na, and Mg perchlorates was assessed by CD and NMR spectra in MeCN.

Bulletin of the Institute for Chemical Research, Kyoto University published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Xu, Liang published the artcileA novel method for selective recovery of indium from end-of-life liquid crystal displays by 15-crown-5 ether and its derivatives, Formula: C10H10O6, the publication is Hydrometallurgy (2021), 105601, database is CAplus.

The present study has proposed a promising liquid-liquid extraction system using novel extractants of 15-crown-5 (15C5), benzo-15-crown-5 (B15C5), and thia-benzo-15-crown-5 (TB15C5) for selective indium recovery from end-of-life liquid crystal displays (LCDs) leaching solution The focus was placed on the selectivity of the crown ethers toward In³⁺ over the most competing ion of Sn²⁺. The mol. design of the crown ethers and their complexations with In³⁺ were theor. evaluated through d. functional theory (DFT) modeling from the perspectives of geometrical structure, electrostatic potential, independent gradient model, MO and thermodn. anal. The results show that the complexation affinity of the crown ethers toward In³⁺ is in the order of 15C5 > B15C5 > TB15C5. On the basis of the theor. anal., the target crown ethers of 15C5, B15C5, and TB15C5 were synthesized and the corresponding solvent extraction experiments were carried out. The exptl. results are in excellent agreement with the theor. evaluations that 15C5 has the best selectivity to In³⁺ over Sn²⁺ among the three crown ethers with the separation coefficient being 5.5, which is followed by 4.1 for B15C5 and 1.6 for TB15C5.

Hydrometallurgy published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C20H18BrN3, Formula: C10H10O6.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia