Category: 5411-14-3

Boca, R. published the artcileSlow magnetic relaxations in a ladder-type Dy(III) complex and its dinuclear analogue, Application In Synthesis of 5411-14-3, the publication is Dalton Transactions (2017), 46(16), 5344-5351, database is CAplus and MEDLINE.

The complex {[Dy₂(PDOA)₃(H₂O)₆]¡¤2H₂O}_n (1) (H₂PDOA = 1,2-phenylenedioxydiacetic acid) was prepared from aqueous solution Its crystal structure, built up of {-Dy-O-C-O-}_n chains interlinked by PDOA ligands yielding a ladder-like arrangement, was determined at 173 K. 1 Exhibits slow magnetic relaxation under a small magnetic field B_DC = 0.2 T with two (LF and HF) relaxation channels. The LF relaxation time at B_DC = 0.2 T and T = 1.85 K is as slow as ¦Ó(LF) = 46 ms whereas the HF channel is ¦Ó(HF) = 1.4 ms. The mole fraction of the LF species is x_LF = 0.76 at 1.85 K and it escapes progressively on heating. In the dinuclear analog [Dy₂(PDOA)₃(H₂O)₆]¡¤3.5H₂O (2) one PDOA ligand forms a bis(chelate) bridge between the two Dy(III) atoms yielding a local structure analogous to that in 1; however its a.c. susceptibility data show slightly different quant. characteristics of the single-mol. magnetic behavior.

Dalton Transactions published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, Application In Synthesis of 5411-14-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Uhl, Werner published the artcileGa-Ga Bonds as Key Building Blocks for the Formation of Supramolecular Entities – Unusual Macrocyclic Tetra- and Octagallium Compounds, Application of 2,2-(1,2-Phenylenebis(oxy))diacetic acid, the publication is European Journal of Inorganic Chemistry (2017), 2017(15), 2270-2278, database is CAplus.

Treatment of the digallium compound R₂Ga-GaR₂ (1) [R = CH(SiMe₃)₂] with the dicarboxylic acids 1,2- and 1,4-(HO₂CCH₂O)₂C₆H₄ afforded, by the release of H₂C(SiMe₃)₂, macrocyclic compounds 2a and 2c, in which two organic spacer ligands connect two metal-metal bonds. Two CO₂ groups bridge each Ga-Ga bond, and different structures resulted with a parallel or perpendicular arrangement of the bridging ligands. The resorcinol derivative 1,3-(HO₂CCH₂O)₂C₆H₄ yielded the unique compound 2b, in which four Ga-Ga bonds are bridged by four spacer ligands. The organic groups form loops, which are alternately arranged above and below the mol. plane with four saddle points and a structure approaching 4 symmetry. The 1,2- and 1,4-diacids afforded tetrakis(digallium) compounds 3a and 3c in the presence of water. In both cases carboxylate groups and hydroxido ligands bridge two Ga atoms of two different Ga-Ga bonds. The spacer ligands connect two of these fragments and adopt parallel orientations to form mol. boxes. Again, the 1,3-diacid afforded a unique structural motif in which a Ga₄O₆ skeleton (two Ga-Ga bonds) is bridged by a single organic spacer, reminiscent of the handle of a basket.

European Journal of Inorganic Chemistry published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C18H35NO, Application of 2,2-(1,2-Phenylenebis(oxy))diacetic acid.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Yang, Yuqing published the artcileA preliminary theoretical study on T_3,4CPP and its combination with Re=O, Related Products of catalysis-chemistry, the publication is Jisuanji Yu Yingyong Huaxue (2011), 28(2), 143-146, database is CAplus.

The mol. structure of meso-tetrakis 3,4-bis(carboxymethyleneoxy)phenyl porphyrin (T_3,4CPP) and the combination of Re = O with T_3,4CPP are studied using the DFT(d. functional theory) with B3LYP method. Their optimum geometry structures, FMO and combination energy are calculated and analyzed. The porphin ring in T_3,4CPP keeps good planarity and exactly similar geometry with sep. porphin ring. Also the combination energy of Re = O with T_3,4CPP on porphin ring is remarkably higher than that of Re = O with T_3,4CPP on carboxymethyleneoxy group of side chain. And stability of the former complex is much higher than that of the latter one. These imply that ¹⁸⁸Re = O should be labeled with T_3,4CPP on porphin ring while not on carboxymethyleneoxy group of side chain. It still shows that during combination of Re = O with T_3,4CPP on porphin ring, electron shifts from carbon atoms to nitrogen atoms. It still shows that after combination of Re = O with T_3,4CPP on porphin ring, the porphin ring deviates slightly (5.7 degree) from planarity to Re = O, and four nitrogen atoms slightly expand toward Re = O with the ring diameter deduced by 0.15-0.20 ?.

Jisuanji Yu Yingyong Huaxue published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C18H17N5O3, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Niu, Changrong published the artcileSynthesis of bisamide bisester-bis(crown ether) compounds, Application In Synthesis of 5411-14-3, the publication is Wuhan Daxue Xuebao, Ziran Kexueban (1998), 44(6), 711-713, database is CAplus.

Three new bisamides-bis(crown ether) compounds I (ortho, meta, para) are synthesized by the reaction of o, m, p-phenylenedioxydiacetyl dichloride with 4′-aminobenzo-15-crown-5; three new bisesters-bis(crown ether) compounds are synthesized by the condensation of o, m, p-phenylenedioxydiacetyl dichloride with 6-hydroxyldibenzo-16-crown-5.

Wuhan Daxue Xuebao, Ziran Kexueban published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, Application In Synthesis of 5411-14-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Purohit, D. M. published the artcileSynthesis of 1,1,1-trichloro-2,2-bis(carboxymethoxyaryl)ethanes as potential antimicrobial and insecticidal agents, HPLC of Formula: 5411-14-3, the publication is Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry (1999), 38B(5), 618-622, database is CAplus.

Some new 1,1,1-trichloro-2,2-bis(carboxymethoxyaryl)ethanes have been synthesized by treating aryloxyacetic acids (2 mol) with chloral hydrate (1 mol) in the presence of a catalytic amount of concentrated sulfuric acid. The aryloxyacetic acids are prepared by reaction of phenols with chloroacetic acid in the presence of aqueous sodium hydroxide. The antimicrobial activities of these compounds have been assayed against Gram pos. and Gram neg. bacteria and fungi; insecticidal activities have been examined against the rice leaf hopper.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, HPLC of Formula: 5411-14-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Purohit, D. M. published the artcileSynthesis of 1,1,1-trichloro-2-(2′,4′-dichloro-5′-carboxymethoxyphenyl)-2-(carboxyaryl/carboxymethoxyaryl)ethanes as possible antimicrobial agents, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid, the publication is Indian Journal of Heterocyclic Chemistry (1999), 8(3), 209-212, database is CAplus.

The title compounds I (R = HO₂C, HO₂CCH:CH, HO₂CCH₂, HO₂CCH₂O; R¹ = H, HO₂C, Me, Cl, MeO, NO₂, HO₂CCH₂O) were prepared by reaction of 2,4-Cl₂C₆H₃OCH₂CO₂H with chloral hydrate in the presence of concentrated H₂SO₄ to afford the (trichloroethyl)phenoxyacetic acid II. II reacted with RR¹C₆H₄ in the presence of a catalytic amount of concentrated H₂SO₄ to give I. All products were screened for antimicrobial activity. The mol. structures of the products were supported by IR, PMR, and mass spectroscopy and elemental anal.

Indian Journal of Heterocyclic Chemistry published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Metz, Alexander published the artcileFrom Determinants of RUNX1/ETO Tetramerization to Small-Molecule Protein-Protein Interaction Inhibitors Targeting Acute Myeloid Leukemia, Related Products of catalysis-chemistry, the publication is Journal of Chemical Information and Modeling (2013), 53(9), 2197-2202, database is CAplus and MEDLINE.

We identified the first small-mol. protein-protein interaction inhibitors of RUNX1/ETO tetramerization applying structure-based virtual screening guided by predicted hot spots and pockets in the interface. A 3D similarity screening revealed specific hot spot mimetics, one of which prevents the proliferation of RUNX1/ETO-dependent SKNO-1 cells at low micromolar concentration Using solely a protein-protein complex structure to start with, this strategy can be the first step in any comparable structure-based endeavor to identify protein-protein interaction inhibitors.

Journal of Chemical Information and Modeling published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Shamsipur, Mojtaba published the artcileAn efficient and selective fluorescent optode membrane based on 7-[(5-chloro-8-hydroxy-7-quinolinyl)methyl]-5,6,7,8,9,10-hexahydro-2H-1,13,4,7,10-benzodioxatriazacyclopentadecine-3,11(4H,12H)-dione as a novel fluoroionophore for determination of cobalt(II) ions, Formula: C10H10O6, the publication is Analytica Chimica Acta (2008), 630(1), 57-66, database is CAplus and MEDLINE.

A novel fluorescence chem. sensor for the highly sensitive and selective determination of Co²⁺ ions in aqueous solutions is prepared The cobalt sensing system was prepared by incorporating 7-[(5-chloro-8-hydroxy-7-quinolinyl)methyl]-5,6,7,8,9,10-hexahydro-2H-1,13,4,7,10-benzodioxatriazacyclopentadecine-3,11(4H,12H)-dione (L) as a neutral cobalt-selective fluoroionophore in the plasticized PVC membrane containing sodium tetraphenylborate as a liphophilic anionic additive. The response of the sensor is based on the strong selective fluorescence quenching of L by Co²⁺ ions. At a pH 5.0, the proposed sensor displays a calibration curve over a wide concentration range of 5.0 ¡Á 10^-7 to 2.0 ¡Á 10^-2 M with a relatively fast response time of <5 min. In addition to high stability and reproducibility, the sensor shows a unique selectivity towards Co²⁺ ion with respect to common coexisting cations. The proposed fluorescence optode was successfully applied to the determination of cobalt content of vitamin B12 ampul, cobalt cake, cobalt alloy and tap water samples.

Analytica Chimica Acta published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C6H17NO3Si, Formula: C10H10O6.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Shin, Jai Moo published the artcile1-arylsulfonyl-2-(pyridylmethylsulfinyl) benzimidazoles as new proton pump inhibitor prodrugs, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid, the publication is Molecules (2009), 14(12), 5247-5280, database is CAplus and MEDLINE.

New arylsulfonyl proton pump inhibitor (PPI) prodrug forms were synthesized. These prodrugs provided longer residence time of an effective PPI plasma concentration, resulting in better gastric acid inhibition.

Molecules published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C19H21N3O3S, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Gholivand, M. B. published the artcileHighly sensitive and selective measurement of bismuth in seawater and drug with 1,2-phenylenedioxydiacetic acid by cathodic adsorptive stripping voltammetry, Formula: C10H10O6, the publication is Electroanalysis (2006), 18(7), 730-734, database is CAplus.

A new method is presented for determination of Bi based on cathodic adsorptive stripping of complex Bi with 1,2-phenylenedioxydiacetic acid (PDA) at a hanging mercury drop electrode (HMDE). The effect of various parameters such as pH, concentration of ligand, accumulation potential and accumulation time on the selectivity and sensitivity were studied. The optimum conditions for determination of Bi include HNO₃ concentration 0.01 M, 8.0 ¡Á 10^-4 M PDA and accumulation time 120 s, accumulation potential of -200 mV. The limits of detection are 0.25 and 0.05 nM, and responses are linear 1-1000 and 0.1-400 nM at t_acc of 60 and 120 s, resp. Many common anions and cations do not interfere in the determination of Bi. The method was applied to the determination of Bi in some real samples such as sea- and spring water and drug.

Electroanalysis published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, Formula: C10H10O6.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia