Category: catalysis-chemistry

Rao, B. Nageswara published the artcileConvenient preparation of arylacetic acids by tetracarbonylcobaltate anion-catalyzed carbonylation, SDS of cas: 1860-58-8, the publication is Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry (1988), 27B(1), 84-5, database is CAplus.

Tetracarbonylcobaltate catalyst [Co(CO)₄]^–, has been prepared in 6 h by pressure carbonylation of cobalt salt in aqueous alk. solution containing cyanide catalyst. Carbonylation of benzyl chloride derivatives in aqueous methanolic solutions using this catalyst affords arylacetic acids in good yields.

Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry published new progress about 1860-58-8. 1860-58-8 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2-(3-(Benzyloxy)phenyl)acetic acid, and the molecular formula is C15H14O3, SDS of cas: 1860-58-8.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Chakraborty, Amitabha published the artcileMolecular interaction of oxazine dyes in aqueous solution: Temperature dependent molecular disposition of the aggregates, Computed Properties of 10510-54-0, the publication is Journal of Molecular Liquids (2011), 164(3), 250-256, database is CAplus.

Temperature dependent mol. interaction of oxazine dyes, viz., brilliant cresyl blue (C.I. Basic dye), cresyl violet (C.I. Basic violet 3) and nile blue (C.I. Basic blue 12) are studied in aqueous media within a concentration range of 5.0 × 10^-6 M to 8.0 × 10^-4 M by UV-visible absorption spectroscopy. The effect of temperature on the geometrical structure of the dimer in solution along with the dimerization equilibrium is explained in terms of electrostatic and hydrophobic interactions. Modified non-covalent interaction between two monomer mols. in a dimer as a function of temperature affects the extinction coefficient as well as the geometrical disposition of the dimers and this is well manifested in the exciton splitting of the dimer spectra. The angle θ between main oscillators of the two monomer mols. in a dimer increases by 1.94° for brilliant cresyl blue, whereas an increase of 4.32° and 1.73° were observed for cresyl violet and nile blue resp. due to the increase of temperature from 20 °C to 60 °C.

Journal of Molecular Liquids published new progress about 10510-54-0. 10510-54-0 belongs to catalysis-chemistry, auxiliary class Other Aromatic Heterocyclic,Salt,Amine,Inhibitor,Inhibitor, name is 5,9-Diaminobenzo[a]phenoxazin-7-ium acetate, and the molecular formula is C18H15N3O3, Computed Properties of 10510-54-0.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Martinot, Pauline published the artcileLC-PUFA enrichment in infant formula and neurodevelopment up to age 3.5 years in the French nationwide ELFE birth cohort, Category: catalysis-chemistry, the publication is European Journal of Nutrition (2022), 61(6), 2979-2991, database is CAplus and MEDLINE.

For decades, consistent associations between breastfeeding and children′s neurodevelopment have been attributed to breastmilk content in long-chain polyunsaturated fatty acids (LC-PUFAs). However, the beneficial effect of LC-PUFA enrichment of infant formula on neurodevelopment remains controversial. This study examined the association of LC-PUFA enrichment of infant formulas with neurodevelopment up to age 3.5 years. Analyses were based on 9372 children from the French nationwide ELFE birth cohort. Monthly from 2 to 10 mo, parents declared their infant′s feeding mode, including breastfeeding and the name of the infant formula, which allowed for identifying formulas enriched in arachidonic (ARA), eicosapentaenoic (EPA) and/or docosahexaenoic (DHA) acids. Neurodevelopment was assessed at age 1 and 3.5 years with the Child Development Inventory (CDI-1 and CDI-3.5); at 2 years with the MacArthur-Bates Communicative Development Inventories (MB-2); and at 3.5 years with the Picture Similarities subtest of the British Ability Scale (BAS-3.5). Associations were assessed by linear regression adjusted for any breastfeeding duration and main confounding factors, including socioeconomic characteristics. One-third of formula-fed infants consumed LC-PUFA-enriched formulas. Most of these formulas were enriched in both DHA and ARA, and about 10% of infants consumed formula further enriched in EPA. LC-PUFA enrichment of infant formula was not associated with neurodevelopmental scores at age 1 (CDI-1, – 0.16 [- 0.39, 0.07]), age 2 (MB-2, 0.78 [- 0.33, 1.89]), or age 3.5 (CDI-3.5, – 0.05 [- 0.27, 0.17]; BAS-3.5, – 0.93 [- 2.85, 0.98]). In the ELFE study, LC-PUFA enrichment of infant formula was not associated with neurodevelopmental scores up to 3.5 years.

European Journal of Nutrition published new progress about 6217-54-5. 6217-54-5 belongs to catalysis-chemistry, auxiliary class Alkenyl,Carboxylic acid,Aliphatic hydrocarbon chain,Metabolic Enzyme,RAR/RXR,Natural product, name is Docosahexaenoic Acid, and the molecular formula is C22H32O2, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Shkulev, V. A. published the artcileOn the connection between reactivity and charge distribution of the azaadamantane ring, Safety of 1,3,5-Triazaadamantan-7-amine, the publication is Armyanskii Khimicheskii Zhurnal (1989), 42(6), 405-7, database is CAplus.

Charge distributions were calculated for di-, tri-, and tetraazaadamantanes; di- and triazahomoadamantane; and a 3,7-diacetyl-1,3,7-triazabicyclononane. Correlations between charge distribution and reactivity were obtained.

Armyanskii Khimicheskii Zhurnal published new progress about 14707-75-6. 14707-75-6 belongs to catalysis-chemistry, auxiliary class Triazinanes, name is 1,3,5-Triazaadamantan-7-amine, and the molecular formula is C18H34N4O5S, Safety of 1,3,5-Triazaadamantan-7-amine.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia