Chen, Xiuting’s team published research in Chemical Communications (Cambridge, United Kingdom) in 58 | CAS: 118-90-1

Chemical Communications (Cambridge, United Kingdom) published new progress about 118-90-1. 118-90-1 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Natural product, name is 2-Methylbenzoic acid, and the molecular formula is C8H8O2, Application In Synthesis of 118-90-1.

Chen, Xiuting published the artcileGas-phase synthesis and structure of thorium benzyne complexes, Application In Synthesis of 118-90-1, the publication is Chemical Communications (Cambridge, United Kingdom) (2022), 58(50), 7018-7021, database is CAplus and MEDLINE.

The thorium benzyne complex (¦Ç2-C6H4)ThCl3 was synthesized in the gas phase through consecutive decarboxylation and dehydrochlorination from the (C6H5CO2)ThCl4 precursor upon collision-induced dissociation Theor. calculations suggest that (¦Ç2-C6H4)ThCl3 exhibits a metallacyclopropene structure with two polarized Th-Cbenzyne ¦Ò bonds. This procedure can be generally extended to the synthesis of a wide range of gas-phase thorium benzyne complexes.

Chemical Communications (Cambridge, United Kingdom) published new progress about 118-90-1. 118-90-1 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Natural product, name is 2-Methylbenzoic acid, and the molecular formula is C8H8O2, Application In Synthesis of 118-90-1.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Kim, Won Seob’s team published research in Scientific Reports in 12 | CAS: 63-68-3

Scientific Reports published new progress about 63-68-3. 63-68-3 belongs to catalysis-chemistry, auxiliary class Natural product, name is (S)-2-Amino-4-(methylthio)butanoic acid, and the molecular formula is C5H11NO2S, Synthetic Route of 63-68-3.

Kim, Won Seob published the artcileEffects of different protein levels on growth performance and stress parameters in beef calves under heat stress, Synthetic Route of 63-68-3, the publication is Scientific Reports (2022), 12(1), 8113, database is CAplus and MEDLINE.

This study investigated the effects of dietary protein levels under various heat stress (HS) conditions on the growth performance and stress parameters in Korean native beef calves. Male calves (n = 40; initial BW = 202.2 ¡À 3.31 kg) were randomly assigned to climatic-controlled chambers with 3 x 3 factorial arrangements. Calves were assigned into three dietary protein levels (low protein; LP = 12.5%, medium protein; MP = 15%, and high protein; HP = 17.5%) and three HS levels [mild: temperature-humidity index (THI) = 74 to 76, moderate: THI = 81 to 83, and severe: THI = 89 to 91] with control (threshold: THI = 70 to 73 and dietary protein level 12.5%). The calves were subjected to ambient temperature (22¡ãC) for 7 days and subsequently to the temperature and humidity corresponding to the target THI level for 21 days. The data were analyzed using the repeated-measures anal. by the GLM procedure of SAS. As a result, average daily gain (ADG) was decreased (P < 0.05) under severe HS level compared to the mild and moderate HS stress levels. However, HP increased ADG (P < 0.05) than moderate levels (LP) and severe levels (LP and MP). Under different HS levels (mild, moderate, and severe), HR, RT, and blood cortisol were increased (P < 0.05) compared to a threshold level, but no differences were observed in the parameters among various protein levels. Varied HS levels decreased the levels of blood glucose, NEFA, and amino acids (AAs) (lysine and glutamic acid) compared to a threshold (P < 0.05). But, the HP group resulted in increased (P < 0.05) levels of blood glucose, NEFA, and AAs (lysine and glutamic acid) compared to LP and MP groups under severe HS stress. The expression level of the HSP70 gene in peripheral blood mononuclear cell (PBMC) and hair follicles was increased (P < 0.05) following an increase in moderate and severe HS levels. Also, HSP70 gene expression in the HP group was decreased (P < 0.05) compared with LP and MP groups under intense HS level. Overall, HS in Korean native beef calves exhibited neg. effects on ADG, blood glucose, NEFA, and AA profile. However, 17.5% of dietary protein (HP) could compensate for the growth of heat-exposed Korean native beef calves through the regulation of homeostasis by protein and energy metabolism Also, it was evident that adequate protein (HP) is used as a major nutrient for HSP70 synthesis in PBMC and hair follicles causing, a boost in the immune system of heat-exposed Korean native beef calves.

Scientific Reports published new progress about 63-68-3. 63-68-3 belongs to catalysis-chemistry, auxiliary class Natural product, name is (S)-2-Amino-4-(methylthio)butanoic acid, and the molecular formula is C5H11NO2S, Synthetic Route of 63-68-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Kuroyanagi, Kazuyoshi’s team published research in Japanese Journal of Applied Physics, Part 2: Letters & Express Letters in 45 | CAS: 201157-13-3

Japanese Journal of Applied Physics, Part 2: Letters & Express Letters published new progress about 201157-13-3. 201157-13-3 belongs to catalysis-chemistry, auxiliary class Nitro Compound,Amine,Benzene, name is N-Benzyl-2-methyl-4-nitroaniline, and the molecular formula is C14H14N2O2, Safety of N-Benzyl-2-methyl-4-nitroaniline.

Kuroyanagi, Kazuyoshi published the artcileDetermination of refractive indices and absorption coefficients of highly purified N-benzyl-2-methyl-4-nitroaniline crystal in terahertz frequency regime, Safety of N-Benzyl-2-methyl-4-nitroaniline, the publication is Japanese Journal of Applied Physics, Part 2: Letters & Express Letters (2006), 45(29-32), L761-L764, database is CAplus.

The authors have measured the refractive index and absorption coefficient of the N-benzyl-2-Me-4-nitroaniline crystal using terahertz time-domain spectroscopy. The refractive index had a value between 1.5 and 1.9 in the <100> direction and between 1.9 and 2.3 in the <100> direction. Also there were resonances at 1.6 and 3.2 THz in the <100> direction, and 1.3, 2.2, and 3.6 THz in the <001> direction within the observed spectral range between 0 and 5 THz. A Lorentz-type oscillator model is applicable to explain exptl. observations.

Japanese Journal of Applied Physics, Part 2: Letters & Express Letters published new progress about 201157-13-3. 201157-13-3 belongs to catalysis-chemistry, auxiliary class Nitro Compound,Amine,Benzene, name is N-Benzyl-2-methyl-4-nitroaniline, and the molecular formula is C14H14N2O2, Safety of N-Benzyl-2-methyl-4-nitroaniline.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Keil, D.’s team published research in Liebigs Annalen in | CAS: 6972-05-0

Liebigs Annalen published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, Related Products of catalysis-chemistry.

Keil, D. published the artcileSynthesis and characterization of 1,3-bis-(2-dialkylamino-5-thiazolyl)-substituted squaraines and their 2-(dialkylamino)thiazole precursors, Related Products of catalysis-chemistry, the publication is Liebigs Annalen (1995), 979-84, database is CAplus.

By condensing of squaric acid with 2-(dialkylamino)-substituted thiazoles, a novel type of heterocyclic-substituted squaraines was prepared in moderate yield mostly. The squaraines are sparingly soluble in most organic solvents and exhibit narrow absorption bands in the visible range at ? 620-700 nm in solution. In dispersed form, the absorption bands of the squaraines are, however, broadened and shifted into the near IR region at ? 900 nm. These unique properties of the new squaraines suggest the use of these dyes as spectral sensitizers for laser-driven data recording or data storage media.

Liebigs Annalen published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia