Tag: M.W=450-500

Crawford, Sarah M.’s team published research in European Journal of Organic Chemistry in 2012 | CAS: 1237588-12-3

European Journal of Organic Chemistry published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C30H42NOP, Quality Control of 1237588-12-3.

Crawford, Sarah M. published the artcilePalladium-catalyzed mono-α-arylation of carbonyl-containing compounds with aryl halides using DalPhos ligands, Quality Control of 1237588-12-3, the publication is European Journal of Organic Chemistry (2012), 2012(30), 6042-6050, database is CAplus.

The extension and optimization of the [Pd(cinnamyl)Cl]2/DalPhos catalyst system, previously found effective for the α-monoarylation of acetone, to the α-monoarylation of a variety of carbonyl compounds with aryl halides and heteroaryl halides was reported. Aryl Me ketones, heteroaryl Me ketones, propiophenones, malonates, and methoxyacetone can be α-arylated under relatively mild conditions and in good yields. The limitations of the ligand/catalyst system towards other classes of carbonyl compounds are reported also.

European Journal of Organic Chemistry published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C30H42NOP, Quality Control of 1237588-12-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Sismondi, A.’s team published research in Journal of Fluorine Chemistry in 59 | CAS: 30670-30-5

Journal of Fluorine Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C13H10O3, Category: catalysis-chemistry.

Sismondi, A. published the artcileSynthesis of novel intermediate fluoroalkyl precursors to highly fluorinated cationic surfactants, Category: catalysis-chemistry, the publication is Journal of Fluorine Chemistry (1992), 59(1), 127-32, database is CAplus.

The syntheses of F-alkyl compounds such as RFC2H4ZCOCH2Br (RF = C4F9, C6F13, C8F17; Z = S, O, NH) by the reaction of bromoacetyl bromide with an F-alkyl compound such as RFC2H4ZH are reported. These compounds show high reactivity with nucleophilic substrates, e.g., Et3N. They are intended for use as precursors of surfactants or as precursors of monomers for the elaboration of artificial vesicles.

Journal of Fluorine Chemistry published new progress about 30670-30-5. 30670-30-5 belongs to catalysis-chemistry, auxiliary class Polyfluoroalkanes, name is 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecan-1-amine, and the molecular formula is C13H10O3, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia