Jezequel, D.’s team published research in Canadian Journal of Chemistry in 69 | CAS: 2016-56-0

Canadian Journal of Chemistry published new progress about 2016-56-0. 2016-56-0 belongs to catalysis-chemistry, auxiliary class Active Esterification, name is Dodecylamineacetate, and the molecular formula is C14H31NO2, Category: catalysis-chemistry.

Jezequel, D. published the artcilePotentiometric study of the stability of ¦Â-cyclodextrin surfactant complexes, Category: catalysis-chemistry, the publication is Canadian Journal of Chemistry (1991), 69(12), 1865-71, database is CAplus.

The complexation constants K of ¦Â-cyclodextrin with 13 ammonium surfactants were determined by a potentiometric method using electrodes selective to amphiphilic ions. Especially for C12-16-alkyl groups, a model that provides for the formation of a second complex, with a K1/K2 ratio of ?600, provided a good fit with the exptl. curves. There was a poor influence of the polar group, for example in the case of the dodecyl chain. On the other hand, the pK1 values and the hydrophobic tail length were linked by a linear relation up to C12; beyond pK1 tended to be proportionally smaller and pK2 more important.

Canadian Journal of Chemistry published new progress about 2016-56-0. 2016-56-0 belongs to catalysis-chemistry, auxiliary class Active Esterification, name is Dodecylamineacetate, and the molecular formula is C14H31NO2, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Lopez-Garcia, M. Angeles’s team published research in European Journal of Organic Chemistry in | CAS: 4230-93-7

European Journal of Organic Chemistry published new progress about 4230-93-7. 4230-93-7 belongs to catalysis-chemistry, auxiliary class Alkenyl,Nitro Compound,Benzene,Ether, name is 1,2-Dimethoxy-4-(2-nitrovinyl)benzene, and the molecular formula is C10H11NO4, Application of 1,2-Dimethoxy-4-(2-nitrovinyl)benzene.

Lopez-Garcia, M. Angeles published the artcile1-alkoxyamino-2-nitroalkanes as key building blocks for a chemo- and diastereoselective synthesis of a new type of polyfunctionalized N-alkoxypiperidine, Application of 1,2-Dimethoxy-4-(2-nitrovinyl)benzene, the publication is European Journal of Organic Chemistry (2010), 5482-5488, S5482/1-S5482/13, database is CAplus.

A highly efficient conversion of ¦Â-nitrostyrenes into a new kind of functionalized N-alkoxy-2-hydroxypiperidine, e.g. I, in two steps was developed, giving excellent yields and diastereoselectivity. The prepared compounds are the first examples of N-alkoxy-2-hydroxypiperidines. The synthetic approach involved the conjugate addition of alkoxyamines to ¦Â-nitrostyrenes, followed by Michael addition of the isolated nitro-alkoxyamines to ¦Á,¦Â-unsaturated carbonyl compounds, and intramol. addition of the alkoxyamino group to the carbonyl functionality of the (non-isolated) adducts. Although three stereogenic centers are formed, only one diastereoisomer was detected. This unprecedented sequence of reactions can also be performed in a one-pot fashion.

European Journal of Organic Chemistry published new progress about 4230-93-7. 4230-93-7 belongs to catalysis-chemistry, auxiliary class Alkenyl,Nitro Compound,Benzene,Ether, name is 1,2-Dimethoxy-4-(2-nitrovinyl)benzene, and the molecular formula is C10H11NO4, Application of 1,2-Dimethoxy-4-(2-nitrovinyl)benzene.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Muraoka, Kazuko’s team published research in Ecletica Quimica in 22 | CAS: 6972-05-0

Ecletica Quimica published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, Related Products of catalysis-chemistry.

Muraoka, Kazuko published the artcileHeterometallic compounds. Interaction of the tricarbonyl containing W-Hg bond, [WCl(CO)3(bipy)(HgCl)], with thioureas, Related Products of catalysis-chemistry, the publication is Ecletica Quimica (1997), 75-82, database is CAplus.

Reactions of [WCl(CO)3(bipy)(HgCl)], [bipy = 2,2′-bipyridine], with thioureas were performed giving compounds [WCl(CO)3(bipy)(HgCl)L], [L = thiourea (tu); N-methylthiourea (mtu); N,N-dimethylthiourea (dmtu)] in which the coordination sphere of the W atom remained unchanged. The coordination of the thioureas to Hg atom occurs, according to IR spectra, through the S atom.

Ecletica Quimica published new progress about 6972-05-0. 6972-05-0 belongs to catalysis-chemistry, auxiliary class Thiourea,Amine,Aliphatic hydrocarbon chain,Amide, name is 1,1-Dimethylthiourea, and the molecular formula is C3H8N2S, Related Products of catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Tran, Thi-Nguyet’s team published research in Polymer Chemistry in 11 | CAS: 119-80-2

Polymer Chemistry published new progress about 119-80-2. 119-80-2 belongs to catalysis-chemistry, auxiliary class sulfides,Carboxylic acid,Benzene, name is 2,2′-Dithiodibenzoic acid, and the molecular formula is C20H28B2O4S2, COA of Formula: C14H10O4S2.

Tran, Thi-Nguyet published the artcileMonitoring the structure-reactivity relationship in epoxidized perilla and safflower oil thermosetting resins, COA of Formula: C14H10O4S2, the publication is Polymer Chemistry (2020), 11(31), 5088-5097, database is CAplus.

For the first time, the effect of reactant structure, stoichiometry and heating rate on the reactivity of epoxidized perilla oil (EPLO) and epoxidized safflower oil (ESFO) with dicarboxylic acids (DCAs) was studied using in situ FT-IR. The epoxy content in the monomer structure was found to affect the copolymerization system’s reactivity, with epoxidized linseed oil (ELO) considered as a reference In this study we discuss also the influence of the DCA structure on the copolymerization reactivity. Two aromatic diacids, dithiodibenzoic acid (DTBA) and diphenic acid (DPA), were studied and compared in the copolymerization of the 3 EVOs, in the presence of imidazole (IM) initiator. The kinetics of these reactions were followed by in situ FT-IR. The corresponding activation energies were calculated via different kinetic models. These data highlight the higher reactivity of the EPLO monomer and the DTBA hardener.

Polymer Chemistry published new progress about 119-80-2. 119-80-2 belongs to catalysis-chemistry, auxiliary class sulfides,Carboxylic acid,Benzene, name is 2,2′-Dithiodibenzoic acid, and the molecular formula is C20H28B2O4S2, COA of Formula: C14H10O4S2.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Chardon, Aurelien’s team published research in ChemCatChem in 9 | CAS: 4141-48-4

ChemCatChem published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Category: catalysis-chemistry.

Chardon, Aurelien published the artcileMetal-free reduction of phosphine oxides, sulfoxides, and N-oxides with hydrosilanes using a borinic acid precatalyst, Category: catalysis-chemistry, the publication is ChemCatChem (2017), 9(24), 4460-4464, database is CAplus.

The general reduction of phosphine oxides, sulfoxides, and amine N-oxides was achieved by combining bis(2-chlorophenyl)borinic acid with phenylsilane. The reaction was shown to tolerate a wide range of substrates and could be performed under mild conditions, with only 2.5 mol% of the easily synthesized catalyst. Mechanistic investigations pointed to a key borohydride as the real catalyst and at bis(2-chlorophenyl)borinic acid as a precatalyst.

ChemCatChem published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Category: catalysis-chemistry.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Maemura, Shunichi’s team published research in Yakuri to Chiryo in 26 | CAS: 38260-01-4

Yakuri to Chiryo published new progress about 38260-01-4. 38260-01-4 belongs to catalysis-chemistry, auxiliary class Chelating Agents, name is N1,N1′-(Ethane-1,2-diyl)bis(ethane-1,2-diamine) dihydrochloride, and the molecular formula is C6H20Cl2N4, Application In Synthesis of 38260-01-4.

Maemura, Shunichi published the artcileMaximum tolerated dose and repeated dose toxicity studies of triethylenetetramine dihydrochloride, a copper chelating agent, by oral administration to beagle dogs, Application In Synthesis of 38260-01-4, the publication is Yakuri to Chiryo (1998), 26(5), 745-767, database is CAplus.

Triethylenetetramine dihydrochloride (trientine-2HCl), a copper chelating agent used to treat Wilson’s disease, was tested for maximum tolerated dose and, subacute and chronic toxicity in beagle dogs. Maximum tolerated dose study. One male and one female beagle dogs received trientine-2HCl by oral administration of variable dosages (50 to 2000 mg/kg) or at constant dosages of 200 or 600 mg/kg/day for two weeks. After one administration at 2000 or 1000 mg/kg severe signs (abnormal gait, ataxia, emesis, diarrhea, body tremor) and marked bodyweight loss were evident. In the constant dosage phase similar effects of treatment were apparent in both animals receiving 600 mg/kg/day. The approx. LD was considered to be more than 2000 mg/kg. Four week study. Beagle dogs received trientine-2HCl orally at dosages of 50, 125 or 300 mg/kg/day for 4 wk followed by a 4-wk reversibility phase. There were no deaths. For some animals receiving 300 mg/kg/day, during the last week of treatment underactivity, abnormal gait, ataxia and body tremor were observed In the lungs, interstitial pneumonia was recorded for one control male and four animals that received 300 mg/kg/day with or without recovery. Toxicokinetic anal. revealed that exposure of the animals to trientine-2HCl was dosage-dependent and that no significant accumulation of trientine-2HCl occurred during the dosing period. Twenty-six week study. Beagle dogs were scheduled to receive trientine-2HCl orally at dosages of 50, 100 or 200 mg/kg/day for 26 wk followed by a 13-wk reversibility phase. However, in view of the severe signs which resulted in the sacrifice for humane reasons of two males and one female receiving 200 mg/kg/day during week 9 of treatment, surviving dogs of this group were only treated for 10 wk. Signs before despatch included marked underactivity, body tremors, abnormal gait, limited use of limb and prone posture. The ante mortem neurol. examination generally indicated depressed postural and flexor withdrawal reactions. The signs were rapidly reversible except in the one female which was killed humanely on day 2 of the reversibility period. Abnormal “stiff legged” gait and underactivity were evident, from week 23 of treatment, in two males and one female receiving 100 mg/kg/day. In the absence of any macroscopic or histopathol. findings, even after the examination of addnl. samples of muscle and nerve, the exact nature of this condition could not be elucidated. In all treated groups low copper and zinc concentrations in the livers and high urinary copper and zinc concentrations were found. The no-observed-adverse-effect level was considered to be 50 mg/kg/day.

Yakuri to Chiryo published new progress about 38260-01-4. 38260-01-4 belongs to catalysis-chemistry, auxiliary class Chelating Agents, name is N1,N1′-(Ethane-1,2-diyl)bis(ethane-1,2-diamine) dihydrochloride, and the molecular formula is C6H20Cl2N4, Application In Synthesis of 38260-01-4.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Kawase, Misa’s team published research in Synlett in 33 | CAS: 613-33-2

Synlett published new progress about 613-33-2. 613-33-2 belongs to catalysis-chemistry, auxiliary class Benzene, name is 4,4′-Dimethyldiphenyl, and the molecular formula is C14H14, Product Details of C14H14.

Kawase, Misa published the artcileSuzuki-Miyaura Cross-Coupling Reaction with Potassium Aryltrifluoroborate in Pure Water Using Recyclable Nanoparticle Catalyst, Product Details of C14H14, the publication is Synlett (2022), 33(1), 57-61, database is CAplus.

The Suzuki-Miyaura cross-coupling reaction of aryl bromides with potassium aryltrifluoroborates in water catalyzed by linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) was described to obtain biaryls Ar1Ar2 [Ar1 = Ph, 2-MeC6H4, 3-furyl, etc.; Ar2 = 2-MeC6H4, 4-MeC6H4, 4-MeOC6H4, 4-F3CC6H4, 4-AcC6H4]. The reaction of aryl bromides having electron-withdrawing groups or electron-donating groups took place smoothly to give the corresponding coupling product in high yields. The catalyst recycles five times without significant loss of catalytic activity although a little bit increase in size of PdNPs was observed after the reaction.

Synlett published new progress about 613-33-2. 613-33-2 belongs to catalysis-chemistry, auxiliary class Benzene, name is 4,4′-Dimethyldiphenyl, and the molecular formula is C14H14, Product Details of C14H14.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Komami, Narumi’s team published research in Synthesis in 50 | CAS: 17351-61-0

Synthesis published new progress about 17351-61-0. 17351-61-0 belongs to catalysis-chemistry, auxiliary class Phase Transfer Catalyst, name is Tetraethylammonium hydrogencarbonate, and the molecular formula is C9H21NO3, Recommanded Product: Tetraethylammonium hydrogencarbonate.

Komami, Narumi published the artcilePalladium-Catalyzed Germylation of Aryl Bromides and Aryl Triflates Using Hexamethyldigermane, Recommanded Product: Tetraethylammonium hydrogencarbonate, the publication is Synthesis (2018), 50(10), 2067-2075, database is CAplus.

Pd-catalyzed germylation of aryl bromides and aryl triflates using com. available hexamethyldigermane is described. Optimized reaction conditions afforded various functionalized aryltrimethylgermanes, including drug-like mols., in moderate to good yields, demonstrating the versatility of the presented protocols.

Synthesis published new progress about 17351-61-0. 17351-61-0 belongs to catalysis-chemistry, auxiliary class Phase Transfer Catalyst, name is Tetraethylammonium hydrogencarbonate, and the molecular formula is C9H21NO3, Recommanded Product: Tetraethylammonium hydrogencarbonate.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Mamiya, Mitsuo’s team published research in Nippon Kogyo Kaishi in 98 | CAS: 2016-56-0

Nippon Kogyo Kaishi published new progress about 2016-56-0. 2016-56-0 belongs to catalysis-chemistry, auxiliary class Active Esterification, name is Dodecylamineacetate, and the molecular formula is C14H31NO2, HPLC of Formula: 2016-56-0.

Mamiya, Mitsuo published the artcileFundamental study on the flotation separation of iron hydroxide and gypsum precipitated in the neutralization process. II, HPLC of Formula: 2016-56-0, the publication is Nippon Kogyo Kaishi (1982), 98(1132), 501-5, database is CAplus.

Flotation was applied for the separation of Fe(OH)3 and gypsum formed in neutralizing the acid drain from an Fe sulfide mine by CaCO3 or Ca(OH)2. The flotation of precipitate obtained from the water containing 1 g Fe3+/L and 6 g SO42-/L was by dodecylammonium?acetate??[2016-56-0]. The selectivity was affected by the rate of neutralization. Satisfactory results were obtained only when the aging process was introduced in the neutralization at pH 2.9. Starch acted as a selective flocculant as well as a depressor for Fe(OH)3, and gave satisfactory selectivity even when a rapid neutralization was adopted. These flotation products are upgraded by washing with small volume of water or an acidified saturated solution of gypsum.

Nippon Kogyo Kaishi published new progress about 2016-56-0. 2016-56-0 belongs to catalysis-chemistry, auxiliary class Active Esterification, name is Dodecylamineacetate, and the molecular formula is C14H31NO2, HPLC of Formula: 2016-56-0.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia

Horioka, Masakazu’s team published research in Nippon Kogyo Kaishi in 98 | CAS: 2016-56-0

Nippon Kogyo Kaishi published new progress about 2016-56-0. 2016-56-0 belongs to catalysis-chemistry, auxiliary class Active Esterification, name is Dodecylamineacetate, and the molecular formula is C14H31NO2, Quality Control of 2016-56-0.

Horioka, Masakazu published the artcileFloatability of zeolite with dodecylammonium acetate. Fundamental study on the recovery of cesium from high-level radioactive wastewater by adsorbing particle flotation with zeolite, Quality Control of 2016-56-0, the publication is Nippon Kogyo Kaishi (1982), 98(1132), 507-12, database is CAplus.

The flotation of zeolite in aqueous solutions of dodecylammonium?acetate (I) [2016-56-0] and pine oil was studied for possible application of the process to the removal of 137Cs in waste solutions Almost complete flotation was observed for the zeolite of <74¦Ì size at pH 2-8 in solutions of 50 I and 46 mg/dm3 pine oil. The Cs-type zeolite required higher I concentration than one without Cs, and <0.03% of the Cs adsorbed was eluted from the zeolite during flotation.

Nippon Kogyo Kaishi published new progress about 2016-56-0. 2016-56-0 belongs to catalysis-chemistry, auxiliary class Active Esterification, name is Dodecylamineacetate, and the molecular formula is C14H31NO2, Quality Control of 2016-56-0.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia