Journal of Carbohydrate Chemistry published new progress about 77189-99-2. 77189-99-2 belongs to catalysis-chemistry, auxiliary class Thiophenol,Benzene,Ether, name is 2,4,6-Trimethoxybenzenethiol, and the molecular formula is C9H12O3S, Related Products of catalysis-chemistry.
Balavoine, Gilbert published the artcileThio glycosides as potential glycosyl donors in electrochemical glycosidation reactions. Part 1. Their preparation and reactivity toward simple alcohols, Related Products of catalysis-chemistry, the publication is Journal of Carbohydrate Chemistry (1995), 14(8), 1217-36, database is CAplus.
Constant potential electrolysis of several glycosyl donors such as substituted Ph 2,3,4,6-tetra-O-acetyl, benzoyl or benzyl-1-thio-β-D-gluco or galactopyranosides in dry acetonitrile in the presence of various primary, secondary or tertiary alcs. performed in an undivided cell, gave preferentially β-linked saccharides in moderate to good yields according to the nature of the protective groups on the sugar moiety. 2-Deoxy-2-phthalimido-1-thio-β-D-gluco derivatives gave the β-glucosides selectively in excellent yields. It was found, as expected, that substitution of the Ph group with methoxy or Me radicals facilitates the electrochem. glycosidation reaction by lowering the oxidation potentials of the corresponding thio glycosides.
Journal of Carbohydrate Chemistry published new progress about 77189-99-2. 77189-99-2 belongs to catalysis-chemistry, auxiliary class Thiophenol,Benzene,Ether, name is 2,4,6-Trimethoxybenzenethiol, and the molecular formula is C9H12O3S, Related Products of catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia