Chen, Qin published the artcileSynthesis and characterization of platinum(II)-thiolate complexes. Crystal and molecular structures of cis-Pt(Ph3P)2(SC6H2-2,4,6-iPr3)Cl and cis-Pt(Ph3P)2(SC6H2-2,4,6-iPr3)2, COA of Formula: C15H24S, the publication is Inorganica Chimica Acta (1994), 216(1-2), 83-7, database is CAplus.
The reaction of cis-Pt(Ph3P)2Cl2 with 2,4,6-triisopropylbenzenethiol (HTIPT) in benzene at 65° yields yellow crystals of cis-[Pt(Ph3P)2(TIPT)Cl] (1), while the reaction of cis-Pt(Ph3P)2Cl2 and HTIPT in benzene at room temperature yields cis-[Pt(Ph3P)2(TIPT)2] (2). In contrast to the tendency of solutions of [Pt(R3P)2(SR’)2] with sterically innocent thiolates to rearrange into a complex mixture of cis and trans complexes and polynuclear materials upon exposure to air, solutions of both 1 and 2 are stable with respect to isomerization and oligomerization. Crystal data for 1·2H2O are monoclinic space group P21/c, Z = 4, R = 0.074 and for 2 they are monoclinic space group P21/n, Z = 4, R = 0.049..
Inorganica Chimica Acta published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, COA of Formula: C15H24S.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia