Cunningham, Drew W. published the artcileReversible and Selective CO2 to HCO2– Electrocatalysis near the Thermodynamic Potential, Quality Control of 17351-62-1, the publication is Angewandte Chemie, International Edition (2020), 59(11), 4443-4447, database is CAplus and MEDLINE.
Reversible catalysis is a hallmark of energy-efficient chem. transformations, but can only be achieved if the changes in free energy of intermediate steps are minimized and the catalytic cycle is devoid of high transition-state barriers. Using these criteria, the authors demonstrate reversible CO2/HCO2– conversion catalyzed by [Pt(depe)2]2+ (depe = 1,2-bis(diethylphosphino)ethane). Direct measurement of the free energies associated with each catalytic step correctly predicts a slight bias towards CO2 reduction The exptl. measured free energy of each step directly contributes to the <50 mV overpotential. Also for CO2 reduction, H2 evolution is negligible and the faradaic efficiency for HCO2– production is nearly quant. A free-energy anal. reveals H2 evolution is endergonic, providing a thermodn. basis for highly selective CO2 reduction
Angewandte Chemie, International Edition published new progress about 17351-62-1. 17351-62-1 belongs to catalysis-chemistry, auxiliary class Salt,Amine, name is Tetrabutylammonium hydrogencarbonate, and the molecular formula is C17H37NO3, Quality Control of 17351-62-1.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia