Dilman, Alexander D. published the artcileTrifluoromethylation of Salicyl Aldimines, Name: Trimethyl(perfluorophenyl)silane, the publication is Journal of Organic Chemistry (2007), 72(22), 8604-8607, database is CAplus and MEDLINE.
A method for the nucleophilic trifluoromethylation of salicyl aldimines, which do not contain an activating group at the nitrogen atom, has been described. The reaction proceeds through the initial generation of an intramol. boron complex followed by interaction with Me3SiCF3 activated by sodium acetate. Thus, BF3.OEt2 was added dropwise to a solution of imine I and EtN(i-Pr)2 in CH2Cl2. After stirring for 2 h at room temperature, the solvent was evaporated in a vacuum followed by successive addition of DMF, Me3SiCF3, and AcONa to give up to 86% trifluoromethylated product II.
Journal of Organic Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Name: Trimethyl(perfluorophenyl)silane.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia