Freidlina, R. Kh.’s team published research in Doklady Akademii Nauk SSSR in 156 | CAS: 3115-28-4

Doklady Akademii Nauk SSSR published new progress about 3115-28-4. 3115-28-4 belongs to catalysis-chemistry, auxiliary class Aliphatic Chain, name is 2-Butylhexanoic acid, and the molecular formula is C10H20O2, COA of Formula: C10H20O2.

Freidlina, R. Kh. published the artcileRearrangement of radicals in the process of telomerization of ethylene with acetic acid, COA of Formula: C10H20O2, the publication is Doklady Akademii Nauk SSSR (1964), 156(5), 1133-6, database is CAplus.

Heating C2H4 at 1540 atm. with AcOH in the presence of a catalytic amount (Me3CO)2 in an autoclave at 140° gave the normally expected telomer acids Et(CH2CH2)nCH2CO2H. However, also isolated were isooctanoic and isodecanoic acids and α-ethylcaproic acid, b13 120°, n20D 1.4290, d20 0.9014 (S-benzylthiuronium salt m. 127-8°), as well as α-butylcaproic acid, b12 137-8°, 1.4459, 0.9216. The higher boiling products were found to consist of C16-18 acids. Formation of the branched acids indicated some isomerization of radicals such as •CH2(CH2)3CH2CO2H.

Doklady Akademii Nauk SSSR published new progress about 3115-28-4. 3115-28-4 belongs to catalysis-chemistry, auxiliary class Aliphatic Chain, name is 2-Butylhexanoic acid, and the molecular formula is C10H20O2, COA of Formula: C10H20O2.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia