Ohki, Yasuhiro published the artcileSynthesis and Characterization of Bioinspired [Mo2Fe2]-Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2, Product Details of C15H24S, the publication is Chemistry – A European Journal (2017), 23(53), 13240-13248, database is CAplus and MEDLINE.
The hydride-supported [Mo2Fe2] cluster complex {Cp*Mo(PMe3)}2{FeN(SiMe3)2}2(H)8 (2a; Cp*=η5-C5Me5) and its [Mo2Mn2] congener 2b were synthesized from the reactions of Cp*Mo(PMe3)(H)5 (1) with M{N(SiMe3)2}2 (M=Fe, Mn). The amide-to-thiolate ligand-exchange reactions of complex 2a with bulky thiol reagents (HSR; R=2,4,6-iPr3C6H2 (Tip), 2,6-(SiMe3)2C6H3 (Btp)) furnished the corresponding hydride-supported [Mo2Fe2](SR)2 cluster complexes. The [Mo2Fe2] clusters served as catalyst precursors for the reductive silylation of N2 and yielded â?5-69 equiv of N(SiMe3)3 relative to the [Mo2Fe2] clusters. Treatment of complexes 2a and b with an excess of CNtBu resulted in the formation of dinuclear Mo-Fe and Mo-Mn complexes, which indicated that the [Mo2M2] cores (M=Fe, Mn) split into two dinuclear species upon accommodation of substrates.
Chemistry – A European Journal published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Product Details of C15H24S.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia