Rizzo, Giorgio published the artcileSilk-Fibroin-Supported Palladium Catalyst for Suzuki-Miyaura and Ullmann Coupling Reactions of Aryl Chlorides, Related Products of catalysis-chemistry, the publication is European Journal of Organic Chemistry (2022), 2022(16), e202101567, database is CAplus.
Pd/SF was tested as a catalyst for the Suzuki-Miyaura and Ullmann coupling reactions of aryl chlorides, in H2O/EtOH solvent mixture under atm. conditions. Starting from the anal. of the products of the Pd/SF promoted Ullmann reactions of poly-haloarenes, the existence of catalytic pockets where monoat. palladium species could form stable complexes with SF. To shed light on this hypothesis, Pd/SF was characterized by Wide-Angle X-ray Scattering (WAXS) anal., which supported the supposition of catalytic pockets. Finally, using a computational model developed by Mol. Mechanic Energy Minimization was estimated the dimension of the catalytic pocket of Pd/SF (about 15 S), in good agreement with the exptl. results.
European Journal of Organic Chemistry published new progress about 613-33-2. 613-33-2 belongs to catalysis-chemistry, auxiliary class Benzene, name is 4,4′-Dimethyldiphenyl, and the molecular formula is C14H14, Related Products of catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia