Yamaguchi, Shigehiro published the artcileSynthesis, Structures, Photophysical Properties, and Dynamic Stereochemistry of Tri-9-anthrylsilane Derivatives, Product Details of C12H10F2Si, the publication is Organometallics (1998), 17(20), 4347-4352, database is CAplus.
Tri-9-anthrylsilanes having various substituents, such as -F, -H, -OH, -OMe, vinyl, and ethynyl, were prepared, and their UV-visible absorption and fluorescence spectra were determined Chiral propeller-like arrangements of three anthryl groups were confirmed by x-ray structural anal. of the fluoro and vinyl derivatives In solution, however, all the trianthrylsilanes prepared herein undergo enantiomerization at room temperature The free energies of enantiomerization are â?-10 kcal mol-1, determined by variable-temperature 1H NMR. The propeller-like structure significantly reduces the quantum yield of fluorescence of the anthracene chromophore.
Organometallics published new progress about 312-40-3. 312-40-3 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Difluorodiphenylsilane, and the molecular formula is C19H34ClN, Product Details of C12H10F2Si.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia