Modification of electrodes with porphyrin-functionalized conductive polymers was written by Ballarin, B.;Masiero, S.;Seeber, R.;Tonelli, D.. And the article was included in Journal of Electroanalytical Chemistry in 1998.Application In Synthesis of 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol The following contents are mentioned in the article:
A new thiophene derivative was synthesized, in which a porphyrin moiety was inserted in the ¦Â position of the heterocyclic ring. The homopolymer deriving from this monomer was prepared by chem. oxidation and subsequently deposited on a glassy carbon electrode, while the copolymer with dithiophene was generated electrochem. directly on the electrode surface. Both materials were characterized by SEM, and by UV-visible and IR spectroscopies. The electrochem. behavior of the relevant coatings was studied and the complexing ability of the polymer chains was studied with respect to the Ni(II) ion. This study involved multiple reactions and reactants, such as 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5Application In Synthesis of 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol).
4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5) belongs to catalyst ligands. Ligand, in chemistry, any atom or molecule attached to a central atom, usually a metallic element, in a coordination or complex compound. It is clear that future advancements in metal complexes and their applications crucially depend on ligand design, whereas the ligand electronic, steric and topological properties provide numerous improvements to the reactivity and selectivity at the metal centers.Application In Synthesis of 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI