A kinetic study on the activating power of lithium ions on the porphyrin metallation by lanthanides and on a microwave specific effect was written by Faure, Rene;Granet, Robert;Krausz, Pierre. And the article was included in Comptes Rendus Chimie in 2009.Recommanded Product: 57412-08-5 The following contents are mentioned in the article:
A kinetic study of the lithium ion activating effect on porphyrin metalation has been investigated using monohydroxy-tritolyl porphyrin and the lanthanides erbium and gadolinium in dimethylacetamide. The powerful, concentration-dependent, catalytic effect of lithium, observed in both cases with classical heating was considerably enhanced under microwave irradiation at the same temperature thus underscoring a specific microwave effect. This study involved multiple reactions and reactants, such as 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5Recommanded Product: 57412-08-5).
4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5) belongs to catalyst ligands. Ligand design occupies a central place in organic synthesis and catalysis. The ligands are electron-rich and highly tunable to provide catalyst systems with a diverse scope, high stability, and reactivity.Recommanded Product: 57412-08-5
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI