The first synthesis of covalently linked mixed dimer complexes containing phthalocyanine and porphyrin was written by Gaspard, Serge;Giannotti, Charles;Maillard, Philippe;Schaeffer, Corinne;Tran-Thi, Thu Hoa. And the article was included in Journal of the Chemical Society, Chemical Communications in 1986.HPLC of Formula: 57412-08-5 The following contents are mentioned in the article:
The covalently linked mixed phthalocyanine-porphyrin dimers I (M = Zn, 2H) were prepared and studied by spectral methods. I (M = Zn) showed very efficient intramol. energy transfer from the Zn porphyrin to the Zn phthalocyanine moiety under light irradiation This study involved multiple reactions and reactants, such as 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5HPLC of Formula: 57412-08-5).
4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5) belongs to catalyst ligands. The atoms and molecules used as ligands are almost always those that are capable of functioning as the electron-pair donor in the electron-pair bond (a coordinate covalent bond) formed with the metal atom. It is clear that future advancements in metal complexes and their applications crucially depend on ligand design, whereas the ligand electronic, steric and topological properties provide numerous improvements to the reactivity and selectivity at the metal centers.HPLC of Formula: 57412-08-5
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI