Excitational energy and photoinduced electron transfer reactions in Ge(IV) corrole-porphyrin hetero dimers was written by Giribabu, Lingamallu;Kandhadi, Jaipal;Kanaparthi, Ravi Kumar;Reeta, P. Silviya. And the article was included in Journal of Luminescence in 2014.Recommanded Product: 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol The following contents are mentioned in the article:
We have constructed hetero dimers by utilizing the axial bonding capabilities as well as known oxophilicity of Germanium(IV) ion of Germanium(IV) corroles as basal scaffolding unit and either free-base or ZnII porphyrin at axial position for the first time. Both the hetero dimers have been completely characterized by elemental anal., UV-visible, proton NMR (1D and 1H-1H COSY) and fluorescence spectroscopies as well as electrochem. methods. The ground state properties indicate that there exists a min. ¦Ð-¦Ð interactions between the macrocyclic units of these dyads. Excited state properties showed that there is an electronic energy transfer competing photoinduced electron transfer from singlet state of basal metalloid corrole to the axial porphyrin and a photoinduced electron transfer from excited state of axial porphyrin to the ground state of central metalloid corrole are possible. This study involved multiple reactions and reactants, such as 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5Recommanded Product: 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol).
4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5) belongs to catalyst ligands. Ligand, in chemistry, any atom or molecule attached to a central atom, usually a metallic element, in a coordination or complex compound. And they often provide a convenient approach to fine-tuning the performance of known catalysts.Recommanded Product: 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI