Kandhadi, Jaipal et al. published their research in Journal of Porphyrins and Phthalocyanines in 2012 | CAS: 57412-08-5

4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5) belongs to catalyst ligands. Catalytic transformations have become a mainstay in the toolkit of the synthetic and increasing non-synthetic chemist alike. It is clear that future advancements in metal complexes and their applications crucially depend on ligand design, whereas the ligand electronic, steric and topological properties provide numerous improvements to the reactivity and selectivity at the metal centers.Product Details of 57412-08-5

Germanium(IV) phthalocyanine-porphyrin based hetero trimers:: synthesis, spectroscopy and photochemistry was written by Kandhadi, Jaipal;Kanaparthi, Ravi Kumar;Giribabu, Lingamallu. And the article was included in Journal of Porphyrins and Phthalocyanines in 2012.Product Details of 57412-08-5 The following contents are mentioned in the article:

The known oxophilicity of Germanium(IV) ion of Germanium(IV) phthalocyanine and porphyrins were exploited to synthesize functionally active, “axial-bonding” -type hetero oligomers. These hetero trimers were fully characterized by elemental anal., FAB-MS, UV-visible, proton NMR (1D and 1H-1H COSY) and fluorescence spectroscopies, as well as differential pulse voltammetric method. Comparison of their spectroscopic and electrochem. data with those of the corresponding individual constituents reveals that there is no apparent ¦Ð-¦Ð interactions in these “vertically” linked hetero oligomers. The fluorescence quantum yields are lower of these hetero oligomers in comparison with those of the monomeric chromophores. Electronic energy transfer and photoinduced electron transfer from axial porphyrins to central metalloid phthalocyanine and photoinduced electron transfer from singlet state of axial porphyrins to central metalloid phthalocyanine was detected in these hetero oligomers. This study involved multiple reactions and reactants, such as 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5Product Details of 57412-08-5).

4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5) belongs to catalyst ligands. Catalytic transformations have become a mainstay in the toolkit of the synthetic and increasing non-synthetic chemist alike. It is clear that future advancements in metal complexes and their applications crucially depend on ligand design, whereas the ligand electronic, steric and topological properties provide numerous improvements to the reactivity and selectivity at the metal centers.Product Details of 57412-08-5

Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI