Sensitized photoredox reactions. Photoinduced energy and electron transfer in pyrene-porphyrin, porphyrin-benzoquinone binary systems and the pyrene-porphyrin-benzoquinone ternary system was written by Lin, Zhiming;Feng, Wuzhan;Leung, Hiukwong. And the article was included in Journal of the Chemical Society, Chemical Communications in 1991.Recommanded Product: 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol The following contents are mentioned in the article:
Intramol. energy transfer from singlet excited pyrene to porphyrin and electron transfer from singlet excited porphyrin to benzoquinone and from ground state pyrene to the porphyrin cation radical were observed in a covalently bonded pyrene-porphyrin-benzoquinone ternary system. This study involved multiple reactions and reactants, such as 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5Recommanded Product: 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol).
4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5) belongs to catalyst ligands. Ligands are classified based on the number of lone pair electrons available for the central metal atom, size and charge like anionic, cationic, neutral, monodentate, bidentate, polydentate ligands. Chiral compounds with high purities and ee values are often used as ligands for catalytically active metal complexes. Recommanded Product: 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI