Sirish, Mallena et al. published their research in Journal of Porphyrins and Phthalocyanines in 1998 | CAS: 57412-08-5

4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5) belongs to catalyst ligands. The atoms and molecules used as ligands are almost always those that are capable of functioning as the electron-pair donor in the electron-pair bond (a coordinate covalent bond) formed with the metal atom. The actual catalysts are metal complexes that are prepared from ligands and appropriate metal precursors.Electric Literature of C47H36N4O

A porphyrin-anthracene supramolecular system assembled via complementary nucleic acid base pairing was written by Sirish, Mallena;Maiya, Bhaskar G.. And the article was included in Journal of Porphyrins and Phthalocyanines in 1998.Electric Literature of C47H36N4O The following contents are mentioned in the article:

Covalently linked porphyrin-adenine [meso-5(4-(9-(2-oxyethyl)adenine)phenyl)-10,15,20-tritolylporphyrin] (1) and anthracene-thymine [1-(9-methylanthracene)thymine] (2) conjugates have been synthesized and fully characterized by elemental anal., FAB mass, UV-vis, 1H NMR, fluorescence and cyclic voltammetric methods. Detailed 1H NMR studies reveal that 1 and 2 self-assemble in CDCl3 solutions at 293 ¡À 3 K to form a two-point hydrogen-bonded, bichromophoric, supramol. system 3 with a binding constant of 47 ¡À 5 M-1 and that both Hoogsteen- and Watson-Crick-type A-T assemblies exist in solution under these exptl. conditions. Spectral and electrochem. data point out the possibility of occurrence of both energy and electron transfer reactions from the singlet excited state of 2 to 1 in the ensemble 3. The singlet state activity of the ensemble 3 has been probed mainly by the time-resolved fluorescence method and the results have been discussed in the light of those obtained earlier on similar “non-covalently” or covalently bound bichromophoric systems. This study involved multiple reactions and reactants, such as 4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5Electric Literature of C47H36N4O).

4-(10,15,20-Tri-p-tolylporphyrin-5-yl)phenol (cas: 57412-08-5) belongs to catalyst ligands. The atoms and molecules used as ligands are almost always those that are capable of functioning as the electron-pair donor in the electron-pair bond (a coordinate covalent bond) formed with the metal atom. The actual catalysts are metal complexes that are prepared from ligands and appropriate metal precursors.Electric Literature of C47H36N4O

Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI