Bellini, Clement published the artcileBarium-Mediated Cross-Dehydrocoupling of Hydrosilanes with Amines: A Theoretical and Experimental Approach, Application In Synthesis of 140-28-3, the publication is Angewandte Chemie, International Edition (2015), 54(26), 7679-7683, database is CAplus and MEDLINE.
Alk.-earth (most prominently barium) complexes of the type [Ae{N(SiMe3)2}2¡¤(THF)x] and [{NN?}Ae{N(SiMe3)2}¡¤(THF)x] are very active and productive precatalysts (TON = 396, TOF up to 3600 h-1; Ca < Sr < Ba) for N-H/H-Si cross-dehydrocoupling, with excellent chemoselectivity in the reaction of (di)amines with (di)hydrosilanes. Exptl. and DFT investigations revealed that the reactions proceed by nucleophilic attack of a metal amide at the incoming silane and subsequent turnover-limiting hydrogen transfer to the metal center.
Angewandte Chemie, International Edition published new progress about 140-28-3. 140-28-3 belongs to catalysis-chemistry, auxiliary class Benzenes, name is N1,N2-Dibenzylethane-1,2-diamine, and the molecular formula is C16H20N2, Application In Synthesis of 140-28-3.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia