Berry, John F. published the artcileA molecular loop with interstitial channels in a chiral environment: exploration of the chemistry of Mo24+ species with chiral and non-chiral dicarboxylate anions, Category: catalysis-chemistry, the publication is Dalton Transactions (2003), 4297-4302, database is CAplus.
An enantiomerically pure chiral loop containing two units of cis-Mo2(DAniF)22+ (DAniF = di-p-anisylformamidinate) was obtained by reacting cis-[Mo2(DAniF)2(NCMe)4](BF4)2 with a chiral dicarboxylate easily prepared from p-, m-, and o-hydroquinone and Et (S)-lactate (H2L1-H2L3). The compound [cis-Mo2(DAniF)2]2(L1)2¡¤4CH2Cl2 (1) crystallizes in the noncentrosym. I222 space group with mols. stacking so as to form channels capable of hosting guest mols. such as CH2Cl2. These properties of 1, which was synthesized in high yield, makes it promising for applications in stereoselective catalysis. Similar reactions with H2L2-3 and isomeric dicarboxylate linkers and some nonchiral ligands (HO2CC(Me)2O)2-m-C6H4 and (HO2CCH2O)2-o-C6H4 were studied. The nature of the products depends on the bite angle of the ligand.
Dalton Transactions published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H10O6, Category: catalysis-chemistry.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia