Chen, Zicong published the artcilePalladium-Catalyzed C(sp2)-N Bond Cross-Coupling with Triaryl Phosphates, Safety of 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, the publication is Journal of Organic Chemistry (2019), 84(10), 6366-6376, database is CAplus and MEDLINE.
The first general palladium-catalyzed amination of aryl phosphates is described. The combination of MorDalPhos with [Pd(¦Ð-cinnamyl)Cl]2 enables the amination of electron-rich, electron-neutral, and electron-poor aryl phosphates with a board range of aromatic, aliphatic, and heterocyclic amines. Common functional groups such as ether, keto, ester, and nitrile show an excellent compatibility in this reaction condition. The solvent-free amination reactions are also successful in both solid coupling partners. The gram-scale cross-coupling is achieved by this catalytic system.
Journal of Organic Chemistry published new progress about 1237588-12-3. 1237588-12-3 belongs to catalysis-chemistry, auxiliary class Mono-phosphine Ligands, name is 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine, and the molecular formula is C30H42NOP, Safety of 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia