Dallemer, F.’s team published research in Applied Organometallic Chemistry in 9 | CAS: 4141-48-4

Applied Organometallic Chemistry published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Formula: C15H15OP.

Dallemer, F. published the artcileSynthesis of tertiary phosphine oxides mediated by SmCp2 or SmI2, Formula: C15H15OP, the publication is Applied Organometallic Chemistry (1995), 9(5 & 6), 431-5, database is CAplus.

Tertiary phosphine oxides are prepared under mild conditions by sequential addition of diphenylphosphinoyl chloride to divalent samarium compounds (SmCp2 and SmI2) followed by reaction with various electrophiles such as organic halides, tosylates, epoxides or ¦Á,¦Â-unsaturated ketones. Biscyclopentadienylsamarium (SmCp2) gives better yields than SmI2. Similar reactions, using phenylphosphonoyl dichloride, SmI2 and subsequent addition of two equivalent of activated halides, yield the corresponding tertiary phosphine oxides.

Applied Organometallic Chemistry published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Formula: C15H15OP.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia