Gonzalez-Nogal, Ana M. published the artcileSome synthetic applications of vinylphosphane oxides, Application In Synthesis of 4141-48-4, the publication is Tetrahedron (2010), 66(50), 9610-9619, database is CAplus.
Vinylphosphine oxides have been used as Michael acceptors for the diastereoselective synthesis of anti ¦Á-functionalized-¦Â-silylated phosphine oxides and ¦Â-stannyl-, ¦Â-phenylthio- or ¦Â-phosphinyl phosphine oxides. Although the utility of these substrates as dipolarophiles was more limited, authors have obtained a mixture of 3- and 4-phosphinylpyrazoles in which the latter is the major regioisomer, by 1,3-cycloaddition with N-phenylsydnone. Moreover, vinylphosphine oxides reacted with aldehydes in the presence of LDA by a Baylis-Hillman type reaction, leading to (E)-¦Â-hydroxyphosphine oxides, which were readily converted in allenes. It is noteworthy that the application of this methodol. to silylated substrates has permitted us to synthesize an interesting and more versatile silylallene.
Tetrahedron published new progress about 4141-48-4. 4141-48-4 belongs to catalysis-chemistry, auxiliary class Aryl phosphine ligand,Mono-phosphine Ligands, name is Allyldiphenylphosphine oxide, and the molecular formula is C15H15OP, Application In Synthesis of 4141-48-4.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia