Stephens, David E. published the artcileSynthetic and mechanistic aspects of the regioselective base-mediated reaction of perfluoroalkyl- and perfluoroarylsilanes with heterocyclic N-oxides, Safety of Trimethyl(perfluorophenyl)silane, the publication is Organic & Biomolecular Chemistry (2014), 12(32), 6190-6199, database is CAplus and MEDLINE.
The scope and mechanistic implications of the direct transformation of heterocyclic N-oxides to 2-trifluoromethyl-, and related perfluoroalkyl- and perfluoroaryl-substituted N-heterocycles has been studied. The reaction is effected by perfluoroalkyl- and perfluorophenyltrimethylsilane in the presence of strong base. In situ displacement of the para-fluoro substituent in the pentafluorophenyl ring and the methoxy group in 8-methoxyquinolines with addnl. nucleophiles allows for further site-selective refunctionalization of the N-heterocyclic products.
Organic & Biomolecular Chemistry published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C15H10O2, Safety of Trimethyl(perfluorophenyl)silane.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia