Stolarova, Monika published the artcile¦Ï-Phenylenedioxydiacetate complexes of Gd(III) and Ce(III): syntheses, crystal structures, and magnetic properties, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid, the publication is Journal of Coordination Chemistry (2014), 67(6), 1046-1060, database is CAplus.
{[Ln2(PDOA)3(H2O)6]?2H2O}n (Ln = Gd, 1; Ln = Ce, 2; H2PDOA = ¦Ï-phenylenedioxydiacetic acid) has been synthesized and characterized by chem. analyses, IR spectroscopy, and thermal analyses. Single-crystal X-ray structure analyses revealed that both 1 and 2 are polymeric and built up of a ladder-like arrangement of Ln(III) ions linked by short syn-anti carboxylate bridges and long bridges (legs of the ladder) formed by a second crystallog. independent PDOA. Ln(III) in both 1 and 2 is nine-coordinate with an O9 donor set formed by one chelating/bridging and one bridging PDOA, and an addnl. three waters. In the asym. unit, there is one crystallog. independent water of crystallization, which is involved in a rich system of hydrogen bonds of the O-H¡¤¡¤¡¤O type. The identities of the bulk and single crystal phases were corroborated by powder X-ray diffraction. Variable temperature (2-300 K) magnetic studies indicate the presence of only weak antiferromagnetic interactions between pairs of paramagnetic Ln(III) ions with J/hc = -0.004 and -0.13 cm-1, for 1 and 2.
Journal of Coordination Chemistry published new progress about 5411-14-3. 5411-14-3 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ether, name is 2,2-(1,2-Phenylenebis(oxy))diacetic acid, and the molecular formula is C10H7NO3, Recommanded Product: 2,2-(1,2-Phenylenebis(oxy))diacetic acid.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia