Watile, Rahul A. published the artcileIntramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst, Formula: C10H10O3, the publication is Nature Communications (2019), 10(1), 1-9, database is CAplus and MEDLINE.
A simple, inexpensive, and environmentally benign iron(III) catalyst promotes the direct intramol. substitution of enantiomerically enriched secondary and tertiary alcs. with O-, N-, and S-centered nucleophiles, e.g., (1S)-3-[2-[(4-methoxyphenyl)amino]phenyl]-1-phenylpropan-1-ol to generate valuable 5-membered, 6-membered and aryl-fused 6-membered heterocyclic compounds, e.g., I with chirality transfer and water as the only byproduct has been demonstrated. The power of the methodol. is demonstrated in the total synthesis of (+)-lentiginosine from D-glucose where iron-catalysis is used in a key step. Adoption of this methodol. will contribute towards the transition to sustainable and bio-based processes in the pharmaceutical and agrochem. industries.
Nature Communications published new progress about 2051-95-8. 2051-95-8 belongs to catalysis-chemistry, auxiliary class Carboxylic acid,Benzene,Ketone, name is 3-Benzoylpropionicacid, and the molecular formula is C8H5F3N4, Formula: C10H10O3.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia