Wei, Duo’s team published research in ChemCatChem in 11 | CAS: 140-28-3

ChemCatChem published new progress about 140-28-3. 140-28-3 belongs to catalysis-chemistry, auxiliary class Benzenes, name is N1,N2-Dibenzylethane-1,2-diamine, and the molecular formula is C12H12F3N5O2, Synthetic Route of 140-28-3.

Wei, Duo published the artcileManganese-Catalyzed Transfer Hydrogenation of Aldimines, Synthetic Route of 140-28-3, the publication is ChemCatChem (2019), 11(21), 5256-5259, database is CAplus.

The reduction of imines to amines R1CH2NHR2 [R1 = Ph, 2-pyridyl, CH=CHPh, etc.; R2 = Ph, cyclohexyl, Bn, etc.] via transfer hydrogenation was achieved by using a phosphine-free manganese(I) catalyst. Using isopropanol as reductant, in the presence of t-BuOK (4 mol %) and manganese complex [Mn(CO)3Br(¦Ê2N,N-PyCH2NH2)] (2 mol %), a large variety of aldimines (30 examples) were typically reduced in 3 h at 80 ¡ãC with good to excellent yield.

ChemCatChem published new progress about 140-28-3. 140-28-3 belongs to catalysis-chemistry, auxiliary class Benzenes, name is N1,N2-Dibenzylethane-1,2-diamine, and the molecular formula is C12H12F3N5O2, Synthetic Route of 140-28-3.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia