Wei, Duo published the artcileManganese catalyzed reductive amination of aldehydes using hydrogen as a reductant, Quality Control of 140-28-3, the publication is Chemical Communications (Cambridge, United Kingdom) (2018), 54(34), 4302-4305, database is CAplus and MEDLINE.
A one-pot two-step procedure was developed for the alkylation of amines via reductive amination of aldehydes using mol. dihydrogen as a reductant in the presence of a manganese pyridinyl-phosphine complex as a pre-catalyst. After the initial condensation step, the reduction of imines formed in-situ was performed under mild conditions (50-100¡ã) with 2 mol% of catalyst and 5 mol% of tBuOK under 50 bar of hydrogen. Excellent yields (> 90%) were obtained for a large combination of aldehydes and amines (40 examples), including aliphatic aldehydes and amino-alcs.
Chemical Communications (Cambridge, United Kingdom) published new progress about 140-28-3. 140-28-3 belongs to catalysis-chemistry, auxiliary class Benzenes, name is N1,N2-Dibenzylethane-1,2-diamine, and the molecular formula is C9H17NO, Quality Control of 140-28-3.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia