Blower, Philip J. published the artcileComplexes of molybdenum(II) and -(IV) and tungsten(II) with sterically hindered thiolate ligands. Synthesis, reactivity, and x-ray crystal structures of tetraphenylphosphonium dicarbonyltris(2,4,6-triisopropylbenzenethiolato)molybdenum(II) and (methyl cyanide)(phenyldiazenido)tris(2,4,6-triisopropylbenzenethiolato)molybdenum(IV), Recommanded Product: 2,4,6-Triisopropylbenzenethiol, the publication is Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999) (1985), 2639-45, database is CAplus.
Reaction of [MBr2(CO)4] (M = Mo, W) reacted with SR– to give [M(SR)3(CO)2]– [R = C6H2(CHMe2)3-2,4,6, C6H3(CHMe2)2-2,6, C6H2Br(CHMe2)2-4,2,6, C6H2Me3-2,4,5, C6F5], isolated as their [PPh4]+ salts (I). I reacted with CO to give [PPh4][M(SR)3(CO)3]. Reaction of I [R = C6H2(CHMe2)3-2,4,6] (II) with neutral donors gave [PPh4][Mo[SC6H2(CHMe2)3-2,4,6]3(CO)L] (L = MeCN, Me3CCN, PMe2Ph, Me3CNC) and with [N2Ph][BF4] in MeCN to give [Mo(NNPh)[SC6H2(CHMe2)3-2,4,6]3(NCMe)] (III). The structures of II and III were determined by x-ray crystallog.; results were refined to R values of 0.0755 and 0.075 for 2939 and 1172 reflections, resp., for II and III, resp. The anions in II and III have trigonal-bipyramidal structures with axial coligands.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999) published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Recommanded Product: 2,4,6-Triisopropylbenzenethiol.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia