Fenwick, Andrew E. published the artcileSynthesis, Characterization, and Reduction Chemistry of Mixed-Cyclopentadienyl/Arylsulfide Titanium Dichlorides, Quality Control of 22693-41-0, the publication is Organometallics (2003), 22(3), 535-540, database is CAplus.
A series of titanium derivatives [CpTi(SAr)Cl2] containing both cyclopentadienyl and various substituted arylsulfide ligands (SAr = SC6H4Me-4 (1), SC6H2Me3-2,4,6 (2), SC6H2Pri3-2,4,6 (3), SC6H2Ph3-2,4,6 (4)) has been synthesized from the reaction of [CpTiCl3] with 1 equivalent of the lithium salt of the corresponding aryl sulfides in benzene. X-ray diffraction studies show that each metal center possesses a pseudo-tetrahedral geometry. The compounds undergo one-electron reduction to produce sulfur-bridged dimers of the type [CpTiCl(¦Ì-SAr)]2 (SAr = SC6H2Me3-2,4,6 (5), SC6H2Pri3-2,4,6 (6)). The solid-state structures of these dimers show that the cyclopentadienyl rings are arranged in a transoid fashion about the [Ti(¦Ì-SAr)2Ti] core. The Ti-Ti distances, 3.242(1) and 3.225(1) ?, resp., are similar to those found in previously reported Cp/aryloxide dimers with terminal aryloxides and bridging chlorides.
Organometallics published new progress about 22693-41-0. 22693-41-0 belongs to catalysis-chemistry, auxiliary class Other Functionalization Reagent, name is 2,4,6-Triisopropylbenzenethiol, and the molecular formula is C15H24S, Quality Control of 22693-41-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia