Gallo, Rafael D. C. published the artcileA Selective C-C Bond Cleavage Strategy Promoted by Visible Light, Computed Properties of 104-03-0, the publication is Organic Letters (2021), 23(22), 8916-8920, database is CAplus and MEDLINE.
A new visible-light-promoted reaction between aryldiazoacetates ArC(=N2)COOR1 (Ar = Ph, 4-chlorophenyl, 3,5-dimethoxypheny, etc.; R1 = Me, Bn, i-Pr, allyl) and 1,3-diketones R2C(O)CH2C(O)R3 (R2 = Me, 4-chlorophenyl, cyclopropyl, etc.; R3 = Me, Ph, 2-methoxyphenyl, etc.) allows good yields and selectivities for C-C bond insertions, leading to the corresponding 1,4-dicarbonyl compounds R2C(O)C(COOR1)(Ar)CH2C(O)R3 . This transformation is straightforward and highly practical. It tolerates air and moisture and does not require the use of any metals. Mechanistic investigations support the involvement of a key cyclopropanol intermediate derived from an intramol. rearrangement.
Organic Letters published new progress about 104-03-0. 104-03-0 belongs to catalysis-chemistry, auxiliary class Nitro Compound,Carboxylic acid,Benzene, name is 4-Nitrophenylacetic acid, and the molecular formula is C8H7NO4, Computed Properties of 104-03-0.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia