Hankin, Danielle M. published the artcile¦Ç2-Sulfenamido and -selenamido complexes of titanium, zirconium, molybdenum and tungsten, Synthetic Route of 19117-31-8, the publication is Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1996), 1309-21, database is CAplus.
The interaction of TiCl4 with LiN(But)SR (R = Ph or C6H2Me3-2,4,6) gave the sulfenamido complexes TiCl2(¦Ç2-ButNSR)2. Interaction of ZrCl4 with 3 equiv of LiN(But)SPh produced ZrCl(¦Ç2-ButNSPh)3 while ZrCl4(tht)2 (tht = tetrahydrothiophene) with 5 equiv gave the homoleptic Zr(¦Ç2-ButNSPh)4. From ZrCl2(¦Ç5-C5H5)2 only ZrCl(¦Ç5-C5H5)2(¦Ç2-ButNSPh) was obtained. Using as starting materials MO2Cl2(dme) (dme = 1,2-dimethoxyethane, M = Mo or W), MoCl2(NBut)2 and WCl2(NBut)2(py)2, interactions with LiNButSPh gave ¦Ç2-sulfenamido compounds such as MoO2(¦Ç2-ButNSPh)2. The Se analog of the W compound, i.e. W(NBut)2(¦Ç2-ButNSePh)2 was made by interaction of Li2W(NBut)4 with PhSeBr. Where study was possible, NMR spectra over a temperature range indicate that invertomers and isomers occur. Six compounds were structurally characterized by x-ray diffraction. In all case the sulfenamido ligands are ¦Ç2 bonded and the geometry about the N atoms is planar.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry published new progress about 19117-31-8. 19117-31-8 belongs to catalysis-chemistry, auxiliary class Oxidant, name is N-(tert-Butyl)-S-phenylthiohydroxylamine, and the molecular formula is C10H15NS, Synthetic Route of 19117-31-8.
Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia