Hevesi, L.’s team published research in Tetrahedron Letters in 35 | CAS: 1206-46-8

Tetrahedron Letters published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Application of Trimethyl(perfluorophenyl)silane.

Hevesi, L. published the artcilePeculiarities in the cleavage by methyllithium of unsymmetrical disilanes, Application of Trimethyl(perfluorophenyl)silane, the publication is Tetrahedron Letters (1994), 35(43), 8031-2, database is CAplus.

The title reactions did not produce the more stable silyl anions from the disilanes studied. These reactions either occurred by attack at the more electrophilic Si atom, or led to unexpected products. Three different reaction pathways were observed, depending on the substituents. Thus, treating Me3SiSiMe2C6HnX5-n (X = H; X = 4-Cl, n = 4; X = 3-CF3, 4-Cl, n = 3 1a–c) with MeLi in HMPA gave predominantly Me3SiC6HnX5-n. Similar reaction of 1d (X = 3,5-Cl2, n = 3) gave almost quant. m-Cl2C6H4, whereas 1e (X = F5, n = 0) gave C6HF5 and polymeric -(Me2Si)-n.

Tetrahedron Letters published new progress about 1206-46-8. 1206-46-8 belongs to catalysis-chemistry, auxiliary class Organic Silicones, name is Trimethyl(perfluorophenyl)silane, and the molecular formula is C9H9F5Si, Application of Trimethyl(perfluorophenyl)silane.

Referemce:
https://courses.lumenlearning.com/boundless-chemistry/chapter/catalysis/,
Catalysis – Wikipedia